Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs
Abstract: Photocatalytic CO2 reduction into hydrocarbon fuels is one of the most efficient processes since it serves as a renewable energy source while also lowering atmospheric CO2 levels. The development of appropriate materials and technology to attain greater yield in CO2 photoreduction is one o...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/38080/1/Enhanced%20Photocatalytic%20CO2%20Reduction%20to%20CH4%20Using%20Novel.pdf |
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| author | Md. Arif, Hossen Fatema, Khatun Riyadh Ramadhan, Ikreedeegh Aamina Din, Muhammad Azrina, Abd Aziz Kah, Hon Leong Lan, Ching Sim Wu, Lihua Minhaj, Uddin Monir |
| author_facet | Md. Arif, Hossen Fatema, Khatun Riyadh Ramadhan, Ikreedeegh Aamina Din, Muhammad Azrina, Abd Aziz Kah, Hon Leong Lan, Ching Sim Wu, Lihua Minhaj, Uddin Monir |
| author_sort | Md. Arif, Hossen |
| collection | UMP |
| description | Abstract: Photocatalytic CO2 reduction into hydrocarbon fuels is one of the most efficient processes since it serves as a renewable energy source while also lowering atmospheric CO2 levels. The development of appropriate materials and technology to attain greater yield in CO2 photoreduction is one of the key issues facing the 21st century. This study successfully fabricated novel ternary reduced graphene oxide (RGO)/Au-TiO2 nanotube arrays (TNTAs) photocatalysts to promote CO2 photoreduction to CH4. Visible light-responsive RGO/Au-TNTAs composite was synthesized by facile electrochemical deposition of Au nanoparticles (NPs) and immersion of RGO nanosheets onto TNTAs. The synthesized composite has been thoroughly investigated by FESEM, HR-TEM, XRD, XPS, FT-IR, UV-Vis DRS, and PL analyzer to explain structural and functional performance. Under the source of visible light, the maximum yield of CH4 was attained at 35.13 ppm/cm2 for the RGO/Au-TNTAs composite photocatalyst after 4 h, which was considerably higher by a wide margin than that of pure TNTAs, Au-TNTAs and RGO-TNTAs. The CO2 photoreduction of the RGO/Au-TNTAs composite has been improved due to the combined effects of Au NPs and RGO. Due to its surface plasmonic resonance (SPR) mechanism, Au NPs play a crucial role in the absorption of visible light. Additionally, the middle RGO layers serve as effective electron transporters, facilitating better separation of electron-hole pairs. The newly constructed composite would be a promising photocatalyst for future photocatalytic applications in other fields. |
| first_indexed | 2024-03-06T13:07:37Z |
| format | Article |
| id | UMPir38080 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T13:07:37Z |
| publishDate | 2023 |
| publisher | MDPI AG |
| record_format | dspace |
| spelling | UMPir380802023-07-20T01:40:08Z http://umpir.ump.edu.my/id/eprint/38080/ Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs Md. Arif, Hossen Fatema, Khatun Riyadh Ramadhan, Ikreedeegh Aamina Din, Muhammad Azrina, Abd Aziz Kah, Hon Leong Lan, Ching Sim Wu, Lihua Minhaj, Uddin Monir TA Engineering (General). Civil engineering (General) Abstract: Photocatalytic CO2 reduction into hydrocarbon fuels is one of the most efficient processes since it serves as a renewable energy source while also lowering atmospheric CO2 levels. The development of appropriate materials and technology to attain greater yield in CO2 photoreduction is one of the key issues facing the 21st century. This study successfully fabricated novel ternary reduced graphene oxide (RGO)/Au-TiO2 nanotube arrays (TNTAs) photocatalysts to promote CO2 photoreduction to CH4. Visible light-responsive RGO/Au-TNTAs composite was synthesized by facile electrochemical deposition of Au nanoparticles (NPs) and immersion of RGO nanosheets onto TNTAs. The synthesized composite has been thoroughly investigated by FESEM, HR-TEM, XRD, XPS, FT-IR, UV-Vis DRS, and PL analyzer to explain structural and functional performance. Under the source of visible light, the maximum yield of CH4 was attained at 35.13 ppm/cm2 for the RGO/Au-TNTAs composite photocatalyst after 4 h, which was considerably higher by a wide margin than that of pure TNTAs, Au-TNTAs and RGO-TNTAs. The CO2 photoreduction of the RGO/Au-TNTAs composite has been improved due to the combined effects of Au NPs and RGO. Due to its surface plasmonic resonance (SPR) mechanism, Au NPs play a crucial role in the absorption of visible light. Additionally, the middle RGO layers serve as effective electron transporters, facilitating better separation of electron-hole pairs. The newly constructed composite would be a promising photocatalyst for future photocatalytic applications in other fields. MDPI AG 2023 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/38080/1/Enhanced%20Photocatalytic%20CO2%20Reduction%20to%20CH4%20Using%20Novel.pdf Md. Arif, Hossen and Fatema, Khatun and Riyadh Ramadhan, Ikreedeegh and Aamina Din, Muhammad and Azrina, Abd Aziz and Kah, Hon Leong and Lan, Ching Sim and Wu, Lihua and Minhaj, Uddin Monir (2023) Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs. Energies, 16 (4). p. 5404. ISSN 1996-1073. (Published) https://doi.org/10.3390/en16145404 10.3390/en16145404 |
| spellingShingle | TA Engineering (General). Civil engineering (General) Md. Arif, Hossen Fatema, Khatun Riyadh Ramadhan, Ikreedeegh Aamina Din, Muhammad Azrina, Abd Aziz Kah, Hon Leong Lan, Ching Sim Wu, Lihua Minhaj, Uddin Monir Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs |
| title | Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs |
| title_full | Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs |
| title_fullStr | Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs |
| title_full_unstemmed | Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs |
| title_short | Enhanced Photocatalytic CO2 Reduction to CH4 Using Novel Ternary Photocatalyst RGO/Au-TNTAs |
| title_sort | enhanced photocatalytic co2 reduction to ch4 using novel ternary photocatalyst rgo au tntas |
| topic | TA Engineering (General). Civil engineering (General) |
| url | http://umpir.ump.edu.my/id/eprint/38080/1/Enhanced%20Photocatalytic%20CO2%20Reduction%20to%20CH4%20Using%20Novel.pdf |
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