Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique

In this study, Pb2+ removal from wastewater using multiwall carbon nanotubes (MWCNTs) was investigated. XRD, SEM-EDX, BET, and FTIR were employed for MWCNT characterization. The effects of various parameters, including the solution pH, adsorbent dosage, initial concentration of Pb2+, and contact tim...

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Main Authors: Al Jadir, Thaer, Alardhi, Saja Mohsen, Al-Sheikh, Farooq, Jaber, Alaa Abdulhady, Kadhim, Wafaa Abdul, Mohd Hasbi, Ab. Rahim
Format: Article
Language:English
English
Published: Taylor and Francis Ltd. 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/38612/1/Modeling%20of%20lead%20%28II%29%20ion%20adsorption%20on%20multiwall%20carbon%20nanotubes.pdf
http://umpir.ump.edu.my/id/eprint/38612/2/Modeling%20of%20lead%20%28II%29%20ion%20adsorption%20on%20multiwall%20carbon%20nanotubes%20using%20artificial_ABS.pdf
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author Al Jadir, Thaer
Alardhi, Saja Mohsen
Al-Sheikh, Farooq
Jaber, Alaa Abdulhady
Kadhim, Wafaa Abdul
Mohd Hasbi, Ab. Rahim
author_facet Al Jadir, Thaer
Alardhi, Saja Mohsen
Al-Sheikh, Farooq
Jaber, Alaa Abdulhady
Kadhim, Wafaa Abdul
Mohd Hasbi, Ab. Rahim
author_sort Al Jadir, Thaer
collection UMP
description In this study, Pb2+ removal from wastewater using multiwall carbon nanotubes (MWCNTs) was investigated. XRD, SEM-EDX, BET, and FTIR were employed for MWCNT characterization. The effects of various parameters, including the solution pH, adsorbent dosage, initial concentration of Pb2+, and contact time, on the Pb2+ removal from wastewater were investigated experimentally. Furthermore, the nonlinear relationship among the parameters was predicted using an artificial neural network (ANN) approach. The Levenberg–Marquardt training algorithm showed the best training performance, with a mean-square error of 2.200× 10−5 and an R2 of 0.998. Combining the ANN models and Monte Carlo simulation, Pb2+ removal efficiency of 99.8% was obtained under the optimum conditions (pH of 10, MWCNT dosage of 0.05 g, contact duration of 60 min, and Pb2+ concentration of 100 mg/L). The high removal efficiency can be attributed to the available adsorption sites (active sites). The results of the reusability of MWCNTs showed that the adsorption efficiency was higher than 90%. Thus, MWCNTs have great potential for recycling and managing Pb2+ from wastewater.
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spelling UMPir386122023-09-13T01:58:55Z http://umpir.ump.edu.my/id/eprint/38612/ Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique Al Jadir, Thaer Alardhi, Saja Mohsen Al-Sheikh, Farooq Jaber, Alaa Abdulhady Kadhim, Wafaa Abdul Mohd Hasbi, Ab. Rahim HD28 Management. Industrial Management QD Chemistry In this study, Pb2+ removal from wastewater using multiwall carbon nanotubes (MWCNTs) was investigated. XRD, SEM-EDX, BET, and FTIR were employed for MWCNT characterization. The effects of various parameters, including the solution pH, adsorbent dosage, initial concentration of Pb2+, and contact time, on the Pb2+ removal from wastewater were investigated experimentally. Furthermore, the nonlinear relationship among the parameters was predicted using an artificial neural network (ANN) approach. The Levenberg–Marquardt training algorithm showed the best training performance, with a mean-square error of 2.200× 10−5 and an R2 of 0.998. Combining the ANN models and Monte Carlo simulation, Pb2+ removal efficiency of 99.8% was obtained under the optimum conditions (pH of 10, MWCNT dosage of 0.05 g, contact duration of 60 min, and Pb2+ concentration of 100 mg/L). The high removal efficiency can be attributed to the available adsorption sites (active sites). The results of the reusability of MWCNTs showed that the adsorption efficiency was higher than 90%. Thus, MWCNTs have great potential for recycling and managing Pb2+ from wastewater. Taylor and Francis Ltd. 2023 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/38612/1/Modeling%20of%20lead%20%28II%29%20ion%20adsorption%20on%20multiwall%20carbon%20nanotubes.pdf pdf en http://umpir.ump.edu.my/id/eprint/38612/2/Modeling%20of%20lead%20%28II%29%20ion%20adsorption%20on%20multiwall%20carbon%20nanotubes%20using%20artificial_ABS.pdf Al Jadir, Thaer and Alardhi, Saja Mohsen and Al-Sheikh, Farooq and Jaber, Alaa Abdulhady and Kadhim, Wafaa Abdul and Mohd Hasbi, Ab. Rahim (2023) Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique. Chemical Engineering Communications, 210 (10). pp. 1642-1658. ISSN 0098-6445. (Published) https://doi.org/10.1080/00986445.2022.2129622 https://doi.org/10.1080/00986445.2022.2129622
spellingShingle HD28 Management. Industrial Management
QD Chemistry
Al Jadir, Thaer
Alardhi, Saja Mohsen
Al-Sheikh, Farooq
Jaber, Alaa Abdulhady
Kadhim, Wafaa Abdul
Mohd Hasbi, Ab. Rahim
Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique
title Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique
title_full Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique
title_fullStr Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique
title_full_unstemmed Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique
title_short Modeling of lead (II) ion adsorption on multiwall carbon nanotubes using artificial neural network and Monte Carlo technique
title_sort modeling of lead ii ion adsorption on multiwall carbon nanotubes using artificial neural network and monte carlo technique
topic HD28 Management. Industrial Management
QD Chemistry
url http://umpir.ump.edu.my/id/eprint/38612/1/Modeling%20of%20lead%20%28II%29%20ion%20adsorption%20on%20multiwall%20carbon%20nanotubes.pdf
http://umpir.ump.edu.my/id/eprint/38612/2/Modeling%20of%20lead%20%28II%29%20ion%20adsorption%20on%20multiwall%20carbon%20nanotubes%20using%20artificial_ABS.pdf
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