The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas
Catalytic methane (CH4) dry reforming (MDR) reaction proceeds with the formation of carbon; hence the effects of the catalyst preparation method on the type of carbon are worth investigating. This study investigated the performance of 20 wt% nickel praseodymium (III) oxide (20 wt% Ni/Pr2O3) catalyst...
| Κύριοι συγγραφείς: | , , , , , , |
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| Μορφή: | Άρθρο |
| Γλώσσα: | English English |
| Έκδοση: |
Springer Science and Business Media Deutschland GmbH
2023
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| Διαθέσιμο Online: | http://umpir.ump.edu.my/id/eprint/40827/1/The%20role%20of%20catalyst%20synthesis%20on%20the%20enhancement%20of%20nickel.pdf http://umpir.ump.edu.my/id/eprint/40827/2/The%20role%20of%20catalyst%20synthesis%20on%20the%20enhancement%20of%20nickel%20praseodymium%20%28III%29%20oxide%20for%20the%20conversion%20of%20greenhouse%20gases%20to%20syngas_ABS.pdf |
| _version_ | 1825815565790347264 |
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| author | Osazuwa, Osarieme Uyi Sumaiya, Zainal Abidin Nurul Asmawati, Roslan Fan, Xiaolei Herma Dina, Setiabudi Vo, Dai Viet N. Onwudili, Jude Azubuike |
| author_facet | Osazuwa, Osarieme Uyi Sumaiya, Zainal Abidin Nurul Asmawati, Roslan Fan, Xiaolei Herma Dina, Setiabudi Vo, Dai Viet N. Onwudili, Jude Azubuike |
| author_sort | Osazuwa, Osarieme Uyi |
| collection | UMP |
| description | Catalytic methane (CH4) dry reforming (MDR) reaction proceeds with the formation of carbon; hence the effects of the catalyst preparation method on the type of carbon are worth investigating. This study investigated the performance of 20 wt% nickel praseodymium (III) oxide (20 wt% Ni/Pr2O3) catalysts prepared by incipient wetness impregnation (IWI), ultrasonic wet impregnation (US-WI), and Pechini sol–gel (PSG) methods. The catalysts crystallite size was approximately 21.3 nm, 21.3 nm, and 10.6 nm, for IWI, US-WI, and PSG catalysts, respectively. Study of the temperature effecton the MDR system showed that higher temperatures favored the MDR reaction with the side reaction playing vital roles. The catalyst synthesized by the PSG method showd higher carbon gasification rate with the stability up to 24 h, whereas catalysts from other synthesis methods were only active for less than 2 h, which could be due to the formation of higher amount of filamentous carbon, balance in oxygen species, and the smaller crystallite size of the PSG-20 wt% Ni/Pr2O3. The PSG-20 wt% Ni/Pr2O3 catalyst accumulated more filamentous carbon than graphitic carbon. In contrast, the IWI and US-WI catalysts accumulated mainly graphitic carbon which encapsulated the Ni0 sites, resulting in excess carbon deposition and reactor clogging within 2 h on stream. |
| first_indexed | 2024-09-25T03:48:30Z |
| format | Article |
| id | UMPir40827 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-09-25T03:48:30Z |
| publishDate | 2023 |
| publisher | Springer Science and Business Media Deutschland GmbH |
| record_format | dspace |
| spelling | UMPir408272024-05-28T08:02:07Z http://umpir.ump.edu.my/id/eprint/40827/ The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas Osazuwa, Osarieme Uyi Sumaiya, Zainal Abidin Nurul Asmawati, Roslan Fan, Xiaolei Herma Dina, Setiabudi Vo, Dai Viet N. Onwudili, Jude Azubuike QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Catalytic methane (CH4) dry reforming (MDR) reaction proceeds with the formation of carbon; hence the effects of the catalyst preparation method on the type of carbon are worth investigating. This study investigated the performance of 20 wt% nickel praseodymium (III) oxide (20 wt% Ni/Pr2O3) catalysts prepared by incipient wetness impregnation (IWI), ultrasonic wet impregnation (US-WI), and Pechini sol–gel (PSG) methods. The catalysts crystallite size was approximately 21.3 nm, 21.3 nm, and 10.6 nm, for IWI, US-WI, and PSG catalysts, respectively. Study of the temperature effecton the MDR system showed that higher temperatures favored the MDR reaction with the side reaction playing vital roles. The catalyst synthesized by the PSG method showd higher carbon gasification rate with the stability up to 24 h, whereas catalysts from other synthesis methods were only active for less than 2 h, which could be due to the formation of higher amount of filamentous carbon, balance in oxygen species, and the smaller crystallite size of the PSG-20 wt% Ni/Pr2O3. The PSG-20 wt% Ni/Pr2O3 catalyst accumulated more filamentous carbon than graphitic carbon. In contrast, the IWI and US-WI catalysts accumulated mainly graphitic carbon which encapsulated the Ni0 sites, resulting in excess carbon deposition and reactor clogging within 2 h on stream. Springer Science and Business Media Deutschland GmbH 2023-07 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40827/1/The%20role%20of%20catalyst%20synthesis%20on%20the%20enhancement%20of%20nickel.pdf pdf en http://umpir.ump.edu.my/id/eprint/40827/2/The%20role%20of%20catalyst%20synthesis%20on%20the%20enhancement%20of%20nickel%20praseodymium%20%28III%29%20oxide%20for%20the%20conversion%20of%20greenhouse%20gases%20to%20syngas_ABS.pdf Osazuwa, Osarieme Uyi and Sumaiya, Zainal Abidin and Nurul Asmawati, Roslan and Fan, Xiaolei and Herma Dina, Setiabudi and Vo, Dai Viet N. and Onwudili, Jude Azubuike (2023) The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas. Clean Technologies and Environmental Policy, 25 (5). pp. 1569-1587. ISSN 1618-954X. (Published) https://doi.org/10.1007/s10098-022-02455-2 https://doi.org/10.1007/s10098-022-02455-2 |
| spellingShingle | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Osazuwa, Osarieme Uyi Sumaiya, Zainal Abidin Nurul Asmawati, Roslan Fan, Xiaolei Herma Dina, Setiabudi Vo, Dai Viet N. Onwudili, Jude Azubuike The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas |
| title | The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas |
| title_full | The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas |
| title_fullStr | The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas |
| title_full_unstemmed | The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas |
| title_short | The role of catalyst synthesis on the enhancement of nickel praseodymium (III) oxide for the conversion of greenhouse gases to syngas |
| title_sort | role of catalyst synthesis on the enhancement of nickel praseodymium iii oxide for the conversion of greenhouse gases to syngas |
| topic | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/40827/1/The%20role%20of%20catalyst%20synthesis%20on%20the%20enhancement%20of%20nickel.pdf http://umpir.ump.edu.my/id/eprint/40827/2/The%20role%20of%20catalyst%20synthesis%20on%20the%20enhancement%20of%20nickel%20praseodymium%20%28III%29%20oxide%20for%20the%20conversion%20of%20greenhouse%20gases%20to%20syngas_ABS.pdf |
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