Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application
The primary objective of the present work is to carry out an experimental study into the stability and thermophysical characteristics of cellulose nanocrystal, MXene, and hybrid cellulose nanocrystal-MXene added to engine oil as a lubricant for piston ring-cylinder liner application. There have been...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Elsevier B.V.
2023
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/40831/1/Improvement%20in%20stability%20and%20thermophysical%20properties%20of%20CNC.pdf http://umpir.ump.edu.my/id/eprint/40831/2/Improvement%20in%20stability%20and%20thermophysical%20properties%20of%20CNC-MXene%20nanolubricant%20for%20Tribology%20application_ABS.pdf |
| _version_ | 1825815566573633536 |
|---|---|
| author | Mohd Kamal, Kamarulzaman Sakinah, Muhamad Hisham Kadirgama, Kumaran Ramasamy, Devarajan Samykano, Mahendran Said, Zafar Pandey, Adarsh Kumar |
| author_facet | Mohd Kamal, Kamarulzaman Sakinah, Muhamad Hisham Kadirgama, Kumaran Ramasamy, Devarajan Samykano, Mahendran Said, Zafar Pandey, Adarsh Kumar |
| author_sort | Mohd Kamal, Kamarulzaman |
| collection | UMP |
| description | The primary objective of the present work is to carry out an experimental study into the stability and thermophysical characteristics of cellulose nanocrystal, MXene, and hybrid cellulose nanocrystal-MXene added to engine oil as a lubricant for piston ring-cylinder liner application. There have been experiments with stability techniques like sedimentation observation, UV–visible spectroscopy, and zeta potential. Thermophysical characteristics have been measured using the viscosity index, dynamic viscosity, and thermal conductivity at various concentrations (ranging from 0.01 % to 0.05 %) and temperatures (from 40 °C to 100 °C). Even without any surfactants, the cellulose nanocrystal-MXene nanolubricants showed good dispersion during the first seven days. The results of the ultraviolet–visible spectrophotometer indicate that cellulose nanocrystal nanolubricants exhibit an absorbance ratio that is most similar to one. It can be shown that the zeta potential increases with a concentration in the distribution of cellulose nanocrystal, MXene, and cellulose nanocrystal-MXene nanoparticles. According to the viscosity index results, all nanolubricants reduce the lubricity oil's viscosity by 16.77 % to 20.33 %, with cellulose nanocrystal-MXene showing the greatest improvement at 0.05 %. At solid concentrations of 0.01 % cellulose nanocrystal and 0.05 % cellulose nanocrystal-MXene with temperatures of 40 °C and 90 °C, the dynamic viscosity was enhanced by 0.92 % and 130.87 %, respectively. The solid concentration of 0.05 % cellulose nanocrystal-MXene was determined to have the greatest effect on the thermal conductivity ratio of the chosen nanolubricant at 90 °C. Overall, at an average concentration of 0.05 %, the thermophysical properties' performance was increased by the addition of cellulose nanocrystal-MXene nanoparticle. The study's findings may be useful for applications involving heat transmission, particularly tribological ones. |
| first_indexed | 2024-09-25T03:48:30Z |
| format | Article |
| id | UMPir40831 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-09-25T03:48:30Z |
| publishDate | 2023 |
| publisher | Elsevier B.V. |
| record_format | dspace |
| spelling | UMPir408312024-05-28T08:02:46Z http://umpir.ump.edu.my/id/eprint/40831/ Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application Mohd Kamal, Kamarulzaman Sakinah, Muhamad Hisham Kadirgama, Kumaran Ramasamy, Devarajan Samykano, Mahendran Said, Zafar Pandey, Adarsh Kumar T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TL Motor vehicles. Aeronautics. Astronautics The primary objective of the present work is to carry out an experimental study into the stability and thermophysical characteristics of cellulose nanocrystal, MXene, and hybrid cellulose nanocrystal-MXene added to engine oil as a lubricant for piston ring-cylinder liner application. There have been experiments with stability techniques like sedimentation observation, UV–visible spectroscopy, and zeta potential. Thermophysical characteristics have been measured using the viscosity index, dynamic viscosity, and thermal conductivity at various concentrations (ranging from 0.01 % to 0.05 %) and temperatures (from 40 °C to 100 °C). Even without any surfactants, the cellulose nanocrystal-MXene nanolubricants showed good dispersion during the first seven days. The results of the ultraviolet–visible spectrophotometer indicate that cellulose nanocrystal nanolubricants exhibit an absorbance ratio that is most similar to one. It can be shown that the zeta potential increases with a concentration in the distribution of cellulose nanocrystal, MXene, and cellulose nanocrystal-MXene nanoparticles. According to the viscosity index results, all nanolubricants reduce the lubricity oil's viscosity by 16.77 % to 20.33 %, with cellulose nanocrystal-MXene showing the greatest improvement at 0.05 %. At solid concentrations of 0.01 % cellulose nanocrystal and 0.05 % cellulose nanocrystal-MXene with temperatures of 40 °C and 90 °C, the dynamic viscosity was enhanced by 0.92 % and 130.87 %, respectively. The solid concentration of 0.05 % cellulose nanocrystal-MXene was determined to have the greatest effect on the thermal conductivity ratio of the chosen nanolubricant at 90 °C. Overall, at an average concentration of 0.05 %, the thermophysical properties' performance was increased by the addition of cellulose nanocrystal-MXene nanoparticle. The study's findings may be useful for applications involving heat transmission, particularly tribological ones. Elsevier B.V. 2023-07-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40831/1/Improvement%20in%20stability%20and%20thermophysical%20properties%20of%20CNC.pdf pdf en http://umpir.ump.edu.my/id/eprint/40831/2/Improvement%20in%20stability%20and%20thermophysical%20properties%20of%20CNC-MXene%20nanolubricant%20for%20Tribology%20application_ABS.pdf Mohd Kamal, Kamarulzaman and Sakinah, Muhamad Hisham and Kadirgama, Kumaran and Ramasamy, Devarajan and Samykano, Mahendran and Said, Zafar and Pandey, Adarsh Kumar (2023) Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application. Journal of Molecular Liquids, 381 (121695). pp. 1-16. ISSN 0167-7322. (Published) https://doi.org/10.1016/j.molliq.2023.121695 https://doi.org/10.1016/j.molliq.2023.121695 |
| spellingShingle | T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TL Motor vehicles. Aeronautics. Astronautics Mohd Kamal, Kamarulzaman Sakinah, Muhamad Hisham Kadirgama, Kumaran Ramasamy, Devarajan Samykano, Mahendran Said, Zafar Pandey, Adarsh Kumar Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application |
| title | Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application |
| title_full | Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application |
| title_fullStr | Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application |
| title_full_unstemmed | Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application |
| title_short | Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application |
| title_sort | improvement in stability and thermophysical properties of cnc mxene nanolubricant for tribology application |
| topic | T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TL Motor vehicles. Aeronautics. Astronautics |
| url | http://umpir.ump.edu.my/id/eprint/40831/1/Improvement%20in%20stability%20and%20thermophysical%20properties%20of%20CNC.pdf http://umpir.ump.edu.my/id/eprint/40831/2/Improvement%20in%20stability%20and%20thermophysical%20properties%20of%20CNC-MXene%20nanolubricant%20for%20Tribology%20application_ABS.pdf |
| work_keys_str_mv | AT mohdkamalkamarulzaman improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication AT sakinahmuhamadhisham improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication AT kadirgamakumaran improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication AT ramasamydevarajan improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication AT samykanomahendran improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication AT saidzafar improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication AT pandeyadarshkumar improvementinstabilityandthermophysicalpropertiesofcncmxenenanolubricantfortribologyapplication |