Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
A solution casting technique was used to fabricate a bio-based polymer electrolytes (BBPEs) system in the form of a solid film that is composed of alginate as the host polymer network, glycolic acid (GA) as the charge carrier, and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid (IL) as...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Elsevier Ltd
2024
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/41368/1/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium.pdf http://umpir.ump.edu.my/id/eprint/41368/2/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium_ABST.pdf |
| _version_ | 1825815671561256960 |
|---|---|
| author | A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin |
| author_facet | A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin |
| author_sort | A. F., Fuzlin |
| collection | UMP |
| description | A solution casting technique was used to fabricate a bio-based polymer electrolytes (BBPEs) system in the form of a solid film that is composed of alginate as the host polymer network, glycolic acid (GA) as the charge carrier, and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid (IL) as an additive. The peak changes in IR spectra revealed the complexation of adding ionic liquids with the enhancement of H+ carriers, while XRD and TGA studies revealed that adding IL suppressed the crystallinity and improved the thermal stability up to ∼100 °C. The free-standing BBPEs sample exhibited the highest ionic conductivity of 2.03 × 10−3 S cm−1 at 6 wt % [Bmim]Cl composition at ambient temperature and achieved an H+ transference number of 0.47. These results suggested that the addition of ILs as an additive into alginate-based BBPEs is a promising strategy for developing proton-conducting solid BBPEs for use in electrochemical devices. |
| first_indexed | 2024-09-25T03:49:45Z |
| format | Article |
| id | UMPir41368 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-09-25T03:49:45Z |
| publishDate | 2024 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | UMPir413682024-05-23T06:44:06Z http://umpir.ump.edu.my/id/eprint/41368/ Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin Q Science (General) QD Chemistry TP Chemical technology A solution casting technique was used to fabricate a bio-based polymer electrolytes (BBPEs) system in the form of a solid film that is composed of alginate as the host polymer network, glycolic acid (GA) as the charge carrier, and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid (IL) as an additive. The peak changes in IR spectra revealed the complexation of adding ionic liquids with the enhancement of H+ carriers, while XRD and TGA studies revealed that adding IL suppressed the crystallinity and improved the thermal stability up to ∼100 °C. The free-standing BBPEs sample exhibited the highest ionic conductivity of 2.03 × 10−3 S cm−1 at 6 wt % [Bmim]Cl composition at ambient temperature and achieved an H+ transference number of 0.47. These results suggested that the addition of ILs as an additive into alginate-based BBPEs is a promising strategy for developing proton-conducting solid BBPEs for use in electrochemical devices. Elsevier Ltd 2024-03-22 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/41368/1/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium.pdf pdf en http://umpir.ump.edu.my/id/eprint/41368/2/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium_ABST.pdf A. F., Fuzlin and N. F., Mazuki and Hasan, Md. Mahmudul and Nagao, Y. and Ahmad Salihin, Samsudin (2024) Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes. International Journal of Hydrogen Energy, 60. 201 -211. ISSN 0360-3199. (Published) https://doi.org/10.1016/j.ijhydene.2024.02.154 https://doi.org/10.1016/j.ijhydene.2024.02.154 |
| spellingShingle | Q Science (General) QD Chemistry TP Chemical technology A. F., Fuzlin N. F., Mazuki Hasan, Md. Mahmudul Nagao, Y. Ahmad Salihin, Samsudin Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes |
| title | Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes |
| title_full | Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes |
| title_fullStr | Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes |
| title_full_unstemmed | Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes |
| title_short | Enhancement on H+ carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes |
| title_sort | enhancement on h carriers in conduction properties with addition of 1 butyl 3 methylimidazolium chloride based alginate polymer electrolytes |
| topic | Q Science (General) QD Chemistry TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/41368/1/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium.pdf http://umpir.ump.edu.my/id/eprint/41368/2/Enhancement%20on%20H%2B%20carriers%20in%20conduction%20properties%20with%20addition%20of%201-butyl-3-Methylimidazolium_ABST.pdf |
| work_keys_str_mv | AT affuzlin enhancementonhcarriersinconductionpropertieswithadditionof1butyl3methylimidazoliumchloridebasedalginatepolymerelectrolytes AT nfmazuki enhancementonhcarriersinconductionpropertieswithadditionof1butyl3methylimidazoliumchloridebasedalginatepolymerelectrolytes AT hasanmdmahmudul enhancementonhcarriersinconductionpropertieswithadditionof1butyl3methylimidazoliumchloridebasedalginatepolymerelectrolytes AT nagaoy enhancementonhcarriersinconductionpropertieswithadditionof1butyl3methylimidazoliumchloridebasedalginatepolymerelectrolytes AT ahmadsalihinsamsudin enhancementonhcarriersinconductionpropertieswithadditionof1butyl3methylimidazoliumchloridebasedalginatepolymerelectrolytes |