Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine

Rising concerns about petrochemical-based materials' sustainability and health risks drive the search for alternatives to natural resources. Polybenzoxazines, known for their exceptional thermal stability, low water absorption, and high glass transition temperature, are promising candidates. Ho...

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Main Authors: Muhammad Nor Arifin, Yaakob, Nurjannah, Salim, Siti Noor Hidayah, Mustapha, Izan Izwan, Misnon, Mohd Hasbi, Ab Rahim, Rasidi, Roslan
Format: Article
Language:English
English
Published: Elsevier Ltd. 2024
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/41456/1/Exploring%20sustainable%20alternatives_Utilizing%20natural%20precursor.pdf
http://umpir.ump.edu.my/id/eprint/41456/2/Exploring%20sustainable%20alternatives_Utilizing%20natural%20precursor_ABST.pdf
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author Muhammad Nor Arifin, Yaakob
Nurjannah, Salim
Siti Noor Hidayah, Mustapha
Izan Izwan, Misnon
Mohd Hasbi, Ab Rahim
Rasidi, Roslan
author_facet Muhammad Nor Arifin, Yaakob
Nurjannah, Salim
Siti Noor Hidayah, Mustapha
Izan Izwan, Misnon
Mohd Hasbi, Ab Rahim
Rasidi, Roslan
author_sort Muhammad Nor Arifin, Yaakob
collection UMP
description Rising concerns about petrochemical-based materials' sustainability and health risks drive the search for alternatives to natural resources. Polybenzoxazines, known for their exceptional thermal stability, low water absorption, and high glass transition temperature, are promising candidates. However, conventional synthesis relies on petroleum-derived monomers like phenol, raising concerns. This review highlights the vast potential of bio-based polybenzoxazines. Biorefinery advancements and new biosynthetic pathways are paving the way for versatile natural monomers like resveratrol and furfurylamine. These alternatives address sustainability and health concerns while offering comparable, and sometimes even superior, material properties. The review delves into the chemistry and structure of polybenzoxazines, tracing their evolution since 1944. It explores the sources and extraction methods of potential bio-based monomers, showcases their application in resin production, and analyzes technical and economic challenges and opportunities. By promoting sustainable materials development and addressing safety considerations, this review paves the way for bio-based polybenzoxazine resins, contributing to a greener and more sustainable future for materials production.
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spelling UMPir414562024-06-04T08:43:16Z http://umpir.ump.edu.my/id/eprint/41456/ Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine Muhammad Nor Arifin, Yaakob Nurjannah, Salim Siti Noor Hidayah, Mustapha Izan Izwan, Misnon Mohd Hasbi, Ab Rahim Rasidi, Roslan Q Science (General) QD Chemistry TP Chemical technology Rising concerns about petrochemical-based materials' sustainability and health risks drive the search for alternatives to natural resources. Polybenzoxazines, known for their exceptional thermal stability, low water absorption, and high glass transition temperature, are promising candidates. However, conventional synthesis relies on petroleum-derived monomers like phenol, raising concerns. This review highlights the vast potential of bio-based polybenzoxazines. Biorefinery advancements and new biosynthetic pathways are paving the way for versatile natural monomers like resveratrol and furfurylamine. These alternatives address sustainability and health concerns while offering comparable, and sometimes even superior, material properties. The review delves into the chemistry and structure of polybenzoxazines, tracing their evolution since 1944. It explores the sources and extraction methods of potential bio-based monomers, showcases their application in resin production, and analyzes technical and economic challenges and opportunities. By promoting sustainable materials development and addressing safety considerations, this review paves the way for bio-based polybenzoxazine resins, contributing to a greener and more sustainable future for materials production. Elsevier Ltd. 2024-05-16 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/41456/1/Exploring%20sustainable%20alternatives_Utilizing%20natural%20precursor.pdf pdf en http://umpir.ump.edu.my/id/eprint/41456/2/Exploring%20sustainable%20alternatives_Utilizing%20natural%20precursor_ABST.pdf Muhammad Nor Arifin, Yaakob and Nurjannah, Salim and Siti Noor Hidayah, Mustapha and Izan Izwan, Misnon and Mohd Hasbi, Ab Rahim and Rasidi, Roslan (2024) Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine. Polymer, 302 (127034). pp. 1-27. ISSN 0032-3861. (Published) https://doi.org/10.1016/j.polymer.2024.127034 https://doi.org/10.1016/j.polymer.2024.127034
spellingShingle Q Science (General)
QD Chemistry
TP Chemical technology
Muhammad Nor Arifin, Yaakob
Nurjannah, Salim
Siti Noor Hidayah, Mustapha
Izan Izwan, Misnon
Mohd Hasbi, Ab Rahim
Rasidi, Roslan
Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine
title Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine
title_full Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine
title_fullStr Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine
title_full_unstemmed Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine
title_short Exploring sustainable alternatives: Utilizing natural precursor for eco-friendly polybenzoxazine
title_sort exploring sustainable alternatives utilizing natural precursor for eco friendly polybenzoxazine
topic Q Science (General)
QD Chemistry
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/41456/1/Exploring%20sustainable%20alternatives_Utilizing%20natural%20precursor.pdf
http://umpir.ump.edu.my/id/eprint/41456/2/Exploring%20sustainable%20alternatives_Utilizing%20natural%20precursor_ABST.pdf
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