Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil

Agarwood (Aquilaria malaccensis) is very well known as the most expensive wood in the world due to its wide applications in perfumery, cosmetic traditional medicine, and religious ceremonies. The study aimed to give an in-depth characterisation focusing on marker compounds in A. malaccensis from dif...

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Main Authors: Erny Haslina, Abd Latib, Huq, A. K. M. Moyeenul, Zareen, Seema, Saiful Nizam, Tajuddin
Format: Article
Language:English
Published: Elsevier B.V. 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/41652/1/Gas%20chromatography%20mass%20spectrometry%20couple%20with%20quadrupole%20time-of-flight.pdf
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author Erny Haslina, Abd Latib
Huq, A. K. M. Moyeenul
Zareen, Seema
Saiful Nizam, Tajuddin
author_facet Erny Haslina, Abd Latib
Huq, A. K. M. Moyeenul
Zareen, Seema
Saiful Nizam, Tajuddin
author_sort Erny Haslina, Abd Latib
collection UMP
description Agarwood (Aquilaria malaccensis) is very well known as the most expensive wood in the world due to its wide applications in perfumery, cosmetic traditional medicine, and religious ceremonies. The study aimed to give an in-depth characterisation focusing on marker compounds in A. malaccensis from different places in Malaysia. The establishment of an oxygenated sesquiterpenes chemical profile of the fungus-infected agarwood oil was achieved by gas chromatography mass spectrometry (GC–MS) coupled with quadrupole time (QTOF) technique. Aroma compounds were identified as sesquiterpenes and oxygenated sesquiterpenes where agarospirol was found in samples of all locations (3.12%, 3.54%, 3.36% and 2.26% from Melaka, Pahang, Kelantan A and Kelantan B respectively) and also N-hexadecanoic acid as one of the major compounds. Both compounds were further isolated by Prep-GC and confirmed by NMR. This study provides a reference for agarwood oil analysis from different origins in Malaysia.
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spelling UMPir416522024-06-24T02:07:41Z http://umpir.ump.edu.my/id/eprint/41652/ Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil Erny Haslina, Abd Latib Huq, A. K. M. Moyeenul Zareen, Seema Saiful Nizam, Tajuddin Q Science (General) QH Natural history TP Chemical technology Agarwood (Aquilaria malaccensis) is very well known as the most expensive wood in the world due to its wide applications in perfumery, cosmetic traditional medicine, and religious ceremonies. The study aimed to give an in-depth characterisation focusing on marker compounds in A. malaccensis from different places in Malaysia. The establishment of an oxygenated sesquiterpenes chemical profile of the fungus-infected agarwood oil was achieved by gas chromatography mass spectrometry (GC–MS) coupled with quadrupole time (QTOF) technique. Aroma compounds were identified as sesquiterpenes and oxygenated sesquiterpenes where agarospirol was found in samples of all locations (3.12%, 3.54%, 3.36% and 2.26% from Melaka, Pahang, Kelantan A and Kelantan B respectively) and also N-hexadecanoic acid as one of the major compounds. Both compounds were further isolated by Prep-GC and confirmed by NMR. This study provides a reference for agarwood oil analysis from different origins in Malaysia. Elsevier B.V. 2023-09 Article PeerReviewed pdf en cc_by_nc_nd_4 http://umpir.ump.edu.my/id/eprint/41652/1/Gas%20chromatography%20mass%20spectrometry%20couple%20with%20quadrupole%20time-of-flight.pdf Erny Haslina, Abd Latib and Huq, A. K. M. Moyeenul and Zareen, Seema and Saiful Nizam, Tajuddin (2023) Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil. Arabian Journal of Chemistry, 16 (9). pp. 1-9. ISSN 1878-5352. (Published) https://doi.org/10.1016/j.arabjc.2023.105025 https://doi.org/10.1016/j.arabjc.2023.105025
spellingShingle Q Science (General)
QH Natural history
TP Chemical technology
Erny Haslina, Abd Latib
Huq, A. K. M. Moyeenul
Zareen, Seema
Saiful Nizam, Tajuddin
Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
title Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
title_full Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
title_fullStr Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
title_full_unstemmed Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
title_short Gas chromatography mass spectrometry couple with quadrupole time-of-flight (GC-QTOF MS) as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
title_sort gas chromatography mass spectrometry couple with quadrupole time of flight gc qtof ms as a powerful tool for profiling of oxygenated sesquiterpenes in agarwood oil
topic Q Science (General)
QH Natural history
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/41652/1/Gas%20chromatography%20mass%20spectrometry%20couple%20with%20quadrupole%20time-of-flight.pdf
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