Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene
Graphene-oxide (GO) is one of the most commonly used carbon nanomaterials in advanced applications such as microwave absorption and EMI shielding, due to various advantages such as ease of synthesis and exfoliation, effective doping capability, and superior composite compatibility. In this study, we...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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World Scientific
2023
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| Online Access: | http://umpir.ump.edu.my/id/eprint/42165/1/Dual%20nitrogen-sulfur-doping%20induce%20microwave%20absorption.pdf |
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| author | Elagib, Tienah H.H. Kabbashi, Nassereldeen A. Alam, Md Zahangir Hassan, Elwathig A.M. Mirghani, Mohamed Elwathig Saeed Azhari, Nour Hamid Abduelraman |
| author_facet | Elagib, Tienah H.H. Kabbashi, Nassereldeen A. Alam, Md Zahangir Hassan, Elwathig A.M. Mirghani, Mohamed Elwathig Saeed Azhari, Nour Hamid Abduelraman |
| author_sort | Elagib, Tienah H.H. |
| collection | UMP |
| description | Graphene-oxide (GO) is one of the most commonly used carbon nanomaterials in advanced applications such as microwave absorption and EMI shielding, due to various advantages such as ease of synthesis and exfoliation, effective doping capability, and superior composite compatibility. In this study, we used the modified Hummer's method to synthesize GO by exfoliating graphite powder, and a simple hydrothermal approach was employed for elemental doping and GO reduction. As nitrogen-sulfur (N, S) dual-doping precursors, thiourea and l-cysteine amino acids were utilized. The structural features and microporous network structure of GO aerogel foams were investigated. The microwave absorption capabilities of polyethersulfone-based nanocomposite films incorporating the as-produced nitrogen-sulfur enrich reduced GO (NS-rGO) are also explored. According to the physicochemical characterization, the existence of remarkable structural defects with a porous three-dimensional (3D) network was discovered due to heteroatom insertion and hydrothermal doping. Additionally, the dual-doped sample exhibited high Nitrogen and sulfur content of 8.93% and 13.19%, respectively. While NS-rGO possesses a higher conductivity of 174.7μS compared to 12.65μS for GO. The nanocomposites filled with NS-rGO foams demonstrated a high shielding efficiency (SE) of 45dB in the X-band with a filler loading of 0.5wt.%. This high SE arises from dopant heteroatoms and the heterogeneous interface, which induce interface polarization, thereby increasing microwave absorption and dielectric constant. It also results from multi-level reflections caused by the 3D porous structures. These findings offer valuable insights into the functionalization of carbon nanostructures and the development of 3D networks in GO-based functional materials, providing further guidance for engineering high-performance electromagnetic interference shielding materials. |
| first_indexed | 2024-12-09T02:29:56Z |
| format | Article |
| id | UMPir42165 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-12-09T02:29:56Z |
| publishDate | 2023 |
| publisher | World Scientific |
| record_format | dspace |
| spelling | UMPir421652024-09-30T04:52:22Z http://umpir.ump.edu.my/id/eprint/42165/ Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene Elagib, Tienah H.H. Kabbashi, Nassereldeen A. Alam, Md Zahangir Hassan, Elwathig A.M. Mirghani, Mohamed Elwathig Saeed Azhari, Nour Hamid Abduelraman QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Graphene-oxide (GO) is one of the most commonly used carbon nanomaterials in advanced applications such as microwave absorption and EMI shielding, due to various advantages such as ease of synthesis and exfoliation, effective doping capability, and superior composite compatibility. In this study, we used the modified Hummer's method to synthesize GO by exfoliating graphite powder, and a simple hydrothermal approach was employed for elemental doping and GO reduction. As nitrogen-sulfur (N, S) dual-doping precursors, thiourea and l-cysteine amino acids were utilized. The structural features and microporous network structure of GO aerogel foams were investigated. The microwave absorption capabilities of polyethersulfone-based nanocomposite films incorporating the as-produced nitrogen-sulfur enrich reduced GO (NS-rGO) are also explored. According to the physicochemical characterization, the existence of remarkable structural defects with a porous three-dimensional (3D) network was discovered due to heteroatom insertion and hydrothermal doping. Additionally, the dual-doped sample exhibited high Nitrogen and sulfur content of 8.93% and 13.19%, respectively. While NS-rGO possesses a higher conductivity of 174.7μS compared to 12.65μS for GO. The nanocomposites filled with NS-rGO foams demonstrated a high shielding efficiency (SE) of 45dB in the X-band with a filler loading of 0.5wt.%. This high SE arises from dopant heteroatoms and the heterogeneous interface, which induce interface polarization, thereby increasing microwave absorption and dielectric constant. It also results from multi-level reflections caused by the 3D porous structures. These findings offer valuable insights into the functionalization of carbon nanostructures and the development of 3D networks in GO-based functional materials, providing further guidance for engineering high-performance electromagnetic interference shielding materials. World Scientific 2023 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/42165/1/Dual%20nitrogen-sulfur-doping%20induce%20microwave%20absorption.pdf Elagib, Tienah H.H. and Kabbashi, Nassereldeen A. and Alam, Md Zahangir and Hassan, Elwathig A.M. and Mirghani, Mohamed Elwathig Saeed and Azhari, Nour Hamid Abduelraman (2023) Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene. Journal of Advanced Dielectrics (2350029). pp. 1-11. ISSN 2010-135X. (In Press / Online First) (In Press / Online First) https://doi.org/10.1142/S2010135X23500297 https://doi.org/10.1142/S2010135X23500297 |
| spellingShingle | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Elagib, Tienah H.H. Kabbashi, Nassereldeen A. Alam, Md Zahangir Hassan, Elwathig A.M. Mirghani, Mohamed Elwathig Saeed Azhari, Nour Hamid Abduelraman Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene |
| title | Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene |
| title_full | Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene |
| title_fullStr | Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene |
| title_full_unstemmed | Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene |
| title_short | Dual nitrogen-sulfur-doping induce microwave absorption and EMI shielding in nanocomposites based on graphene |
| title_sort | dual nitrogen sulfur doping induce microwave absorption and emi shielding in nanocomposites based on graphene |
| topic | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/42165/1/Dual%20nitrogen-sulfur-doping%20induce%20microwave%20absorption.pdf |
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