Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal

A new type of optical storage device is described employing a material consisting of a host nematic liquid crystal, a photoisomerisable azobenzene component and a photopolymerizable monomer. The principle of image storing involves selectively controlling the birefringence of the medium immediately p...

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Main Authors: Hegde, Gurumurthy, Jayalakshmi, Vallamkondu, Naira, Geetha Gopinathan, Prasad, Subbarao Krishna
Format: Article
Language:English
Published: Royal Society of Chemistry 2009
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/5435/1/PCCP.pdf
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author Hegde, Gurumurthy
Jayalakshmi, Vallamkondu
Naira, Geetha Gopinathan
Prasad, Subbarao Krishna
author_facet Hegde, Gurumurthy
Jayalakshmi, Vallamkondu
Naira, Geetha Gopinathan
Prasad, Subbarao Krishna
author_sort Hegde, Gurumurthy
collection UMP
description A new type of optical storage device is described employing a material consisting of a host nematic liquid crystal, a photoisomerisable azobenzene component and a photopolymerizable monomer. The principle of image storing involves selectively controlling the birefringence of the medium immediately prior to photopolymerization of the monomer. We show that photoisomerisation driven nematic to isotropic transition can be employed to achieve this through proper timing of the reverse isomerization of the azobenzene compound before the nematic director fluctuations get quenched. It is also suggested that grey-shades can be created in this device using the recently discovered phenomenon of electric-field acceleration of reverse isomerisation.
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spelling UMPir54352018-05-18T00:06:23Z http://umpir.ump.edu.my/id/eprint/5435/ Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal Hegde, Gurumurthy Jayalakshmi, Vallamkondu Naira, Geetha Gopinathan Prasad, Subbarao Krishna QC Physics A new type of optical storage device is described employing a material consisting of a host nematic liquid crystal, a photoisomerisable azobenzene component and a photopolymerizable monomer. The principle of image storing involves selectively controlling the birefringence of the medium immediately prior to photopolymerization of the monomer. We show that photoisomerisation driven nematic to isotropic transition can be employed to achieve this through proper timing of the reverse isomerization of the azobenzene compound before the nematic director fluctuations get quenched. It is also suggested that grey-shades can be created in this device using the recently discovered phenomenon of electric-field acceleration of reverse isomerisation. Royal Society of Chemistry 2009-05-28 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/5435/1/PCCP.pdf Hegde, Gurumurthy and Jayalakshmi, Vallamkondu and Naira, Geetha Gopinathan and Prasad, Subbarao Krishna (2009) Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal. Physical Chemistry Chemical Physics, 11 (30). pp. 6450-6454. ISSN 1463-9076 (print); 1463-9084 (online). (Published) http://dx.doi.org/10.1039/B906004A DOI: 10.1039/B906004A
spellingShingle QC Physics
Hegde, Gurumurthy
Jayalakshmi, Vallamkondu
Naira, Geetha Gopinathan
Prasad, Subbarao Krishna
Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal
title Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal
title_full Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal
title_fullStr Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal
title_full_unstemmed Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal
title_short Photo-controlled Conformation-assisted Permanent Optical Storage Device Employing a Polymer Network Liquid Crystal
title_sort photo controlled conformation assisted permanent optical storage device employing a polymer network liquid crystal
topic QC Physics
url http://umpir.ump.edu.my/id/eprint/5435/1/PCCP.pdf
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