Electrospun Hematite Nanowires for Photoelectrochemical Cell

Solar energy is an efficient source that provides enough power for all global energy demands if it can efficiently harvested. The more elegant, practical and potentially more efficient way to store this huge energy is fix this electromagnetic energy to molecular bonds in the form of chemical ener...

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Main Authors: Ahmed, Irfan, Fakharuddin, Azhar, Mohd Hasbi, Ab. Rahim, Rajan, Jose
Format: Conference or Workshop Item
Language:English
Published: 2013
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/5722/1/EE-002.pdf
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author Ahmed, Irfan
Fakharuddin, Azhar
Mohd Hasbi, Ab. Rahim
Rajan, Jose
author_facet Ahmed, Irfan
Fakharuddin, Azhar
Mohd Hasbi, Ab. Rahim
Rajan, Jose
author_sort Ahmed, Irfan
collection UMP
description Solar energy is an efficient source that provides enough power for all global energy demands if it can efficiently harvested. The more elegant, practical and potentially more efficient way to store this huge energy is fix this electromagnetic energy to molecular bonds in the form of chemical energy as analogous to photosynthesis process exploit by nature[Allen J bard, 1995]. In the view of simplicity and ecology, Photoelectrolysis is very promising technique for photoelectrochemical conversion of solar energy. Hematite (α-Fe2O), a binary metal oxide material, is n type in its pure form crystallizes in corundum structure. Due to its significant light absorption, abundance, chemical stability in an aqueous environment and low cost, it emerged as a model material for water splitting electrode and received considerable attention during last few years. Unfortunately this material produces low photocurrent due to its short exciton life time (~10ps), poor charge carrier mobility and slow water oxidation kinetics [Osterloh, 2013]. To overcome these limitations and improves solar conversion efficiency intense effort has been done as development of such nanostructure that facilitate electron transport and reduce charge recombination[Kay et al., 2006][Ling et al., 2011], modification of electronic structure by elemental doping [Liao et al., 2011] and use of oxygen evolution catalyst[Krengvirat et al., 2012]. One dimensional nanostructure typically nanowires are promising as this morphology reduces charge transport resistance and has high surface area. Electrospinning is one of the bottom up approach which is simple, cost effective and can be scale up this technique works on the principle of liquid injection and jet formation that travels through an electric field and formation of Nanofibers on a substrate.[Bhardwaj et al.,2010] The diameter of nanofibers can be tuned by liquid injection rate, distance form collector and Variation of potential difference.[Archana et al., 2009].
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spelling UMPir57222018-11-22T08:12:32Z http://umpir.ump.edu.my/id/eprint/5722/ Electrospun Hematite Nanowires for Photoelectrochemical Cell Ahmed, Irfan Fakharuddin, Azhar Mohd Hasbi, Ab. Rahim Rajan, Jose TK Electrical engineering. Electronics Nuclear engineering Solar energy is an efficient source that provides enough power for all global energy demands if it can efficiently harvested. The more elegant, practical and potentially more efficient way to store this huge energy is fix this electromagnetic energy to molecular bonds in the form of chemical energy as analogous to photosynthesis process exploit by nature[Allen J bard, 1995]. In the view of simplicity and ecology, Photoelectrolysis is very promising technique for photoelectrochemical conversion of solar energy. Hematite (α-Fe2O), a binary metal oxide material, is n type in its pure form crystallizes in corundum structure. Due to its significant light absorption, abundance, chemical stability in an aqueous environment and low cost, it emerged as a model material for water splitting electrode and received considerable attention during last few years. Unfortunately this material produces low photocurrent due to its short exciton life time (~10ps), poor charge carrier mobility and slow water oxidation kinetics [Osterloh, 2013]. To overcome these limitations and improves solar conversion efficiency intense effort has been done as development of such nanostructure that facilitate electron transport and reduce charge recombination[Kay et al., 2006][Ling et al., 2011], modification of electronic structure by elemental doping [Liao et al., 2011] and use of oxygen evolution catalyst[Krengvirat et al., 2012]. One dimensional nanostructure typically nanowires are promising as this morphology reduces charge transport resistance and has high surface area. Electrospinning is one of the bottom up approach which is simple, cost effective and can be scale up this technique works on the principle of liquid injection and jet formation that travels through an electric field and formation of Nanofibers on a substrate.[Bhardwaj et al.,2010] The diameter of nanofibers can be tuned by liquid injection rate, distance form collector and Variation of potential difference.[Archana et al., 2009]. 2013 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/5722/1/EE-002.pdf Ahmed, Irfan and Fakharuddin, Azhar and Mohd Hasbi, Ab. Rahim and Rajan, Jose (2013) Electrospun Hematite Nanowires for Photoelectrochemical Cell. In: Malaysian Technical Universities Conference on Engineering and Technology (MUCET) , 3-4 December 2013 , MS Garden Hotel, Kuantan. pp. 1-2..
spellingShingle TK Electrical engineering. Electronics Nuclear engineering
Ahmed, Irfan
Fakharuddin, Azhar
Mohd Hasbi, Ab. Rahim
Rajan, Jose
Electrospun Hematite Nanowires for Photoelectrochemical Cell
title Electrospun Hematite Nanowires for Photoelectrochemical Cell
title_full Electrospun Hematite Nanowires for Photoelectrochemical Cell
title_fullStr Electrospun Hematite Nanowires for Photoelectrochemical Cell
title_full_unstemmed Electrospun Hematite Nanowires for Photoelectrochemical Cell
title_short Electrospun Hematite Nanowires for Photoelectrochemical Cell
title_sort electrospun hematite nanowires for photoelectrochemical cell
topic TK Electrical engineering. Electronics Nuclear engineering
url http://umpir.ump.edu.my/id/eprint/5722/1/EE-002.pdf
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AT fakharuddinazhar electrospunhematitenanowiresforphotoelectrochemicalcell
AT mohdhasbiabrahim electrospunhematitenanowiresforphotoelectrochemicalcell
AT rajanjose electrospunhematitenanowiresforphotoelectrochemicalcell