Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model

The purpose of this study conducted in this research was to measure thermo physical properties like Viscosities, η, and Densities, ρ, of 1,4 Dioxane with two hydrocarbons like Bromobenzene and Ethylebenzene at different mole fractions and various temperatures in the atmospheric pressure co...

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Main Authors: R., Ramesh, Anwaruddin, Hisyam, K., Ramesh
Format: Article
Language:English
Published: The IJES 2014
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/5939/1/fkksa-2014-ramesh-Measurement_and_Prediction.pdf
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author R., Ramesh
Anwaruddin, Hisyam
K., Ramesh
author_facet R., Ramesh
Anwaruddin, Hisyam
K., Ramesh
author_sort R., Ramesh
collection UMP
description The purpose of this study conducted in this research was to measure thermo physical properties like Viscosities, η, and Densities, ρ, of 1,4 Dioxane with two hydrocarbons like Bromobenzene and Ethylebenzene at different mole fractions and various temperatures in the atmospheric pressure condition. From the experimental data excess volumes, V E , and deviations in viscosities, Δη, of mixtures at infinite dilutions have been obtained. The measured systems exhibited positive values of V E and negative values of Δη. The binary mixture 1, 4 Dioxane + Bromobenzene show positive V E and negative Δη with increasing temperatures. The outcomes clearly indicate that weak interactions present in mixture. It is mainly because of number and position of methyl groups exist in these aromatic hydrocarbons. These measured data tailored to the McAllister model to derive the binary coefficients. Standard deviations obtained from the fitted outcomes and the calculated data is helpful deliberate mixing behavior of the binary mixtures. It can conclude that in our case, the data found with the values correlated by the corresponding model is very well. The molecular interactions existing between the components and comparison of liquid mixtures were also discussed.
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spelling UMPir59392018-01-11T01:43:31Z http://umpir.ump.edu.my/id/eprint/5939/ Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model R., Ramesh Anwaruddin, Hisyam K., Ramesh TP Chemical technology The purpose of this study conducted in this research was to measure thermo physical properties like Viscosities, η, and Densities, ρ, of 1,4 Dioxane with two hydrocarbons like Bromobenzene and Ethylebenzene at different mole fractions and various temperatures in the atmospheric pressure condition. From the experimental data excess volumes, V E , and deviations in viscosities, Δη, of mixtures at infinite dilutions have been obtained. The measured systems exhibited positive values of V E and negative values of Δη. The binary mixture 1, 4 Dioxane + Bromobenzene show positive V E and negative Δη with increasing temperatures. The outcomes clearly indicate that weak interactions present in mixture. It is mainly because of number and position of methyl groups exist in these aromatic hydrocarbons. These measured data tailored to the McAllister model to derive the binary coefficients. Standard deviations obtained from the fitted outcomes and the calculated data is helpful deliberate mixing behavior of the binary mixtures. It can conclude that in our case, the data found with the values correlated by the corresponding model is very well. The molecular interactions existing between the components and comparison of liquid mixtures were also discussed. The IJES 2014 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/5939/1/fkksa-2014-ramesh-Measurement_and_Prediction.pdf R., Ramesh and Anwaruddin, Hisyam and K., Ramesh (2014) Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model. The International Journal Of Engineering And Science (IJES), 3 (3). pp. 68-74. ISSN 2319–1805 (print); 2319–1813 (online). (Published) http://www.theijes.com/papers/v3-i3/Version-3/N0333068074.pdf
spellingShingle TP Chemical technology
R., Ramesh
Anwaruddin, Hisyam
K., Ramesh
Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model
title Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model
title_full Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model
title_fullStr Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model
title_full_unstemmed Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model
title_short Measurement and Prediction of Thermo Physical Properties of Binary Liquid Mixtures at Various Temperatures Using McAllister Model
title_sort measurement and prediction of thermo physical properties of binary liquid mixtures at various temperatures using mcallister model
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/5939/1/fkksa-2014-ramesh-Measurement_and_Prediction.pdf
work_keys_str_mv AT rramesh measurementandpredictionofthermophysicalpropertiesofbinaryliquidmixturesatvarioustemperaturesusingmcallistermodel
AT anwaruddinhisyam measurementandpredictionofthermophysicalpropertiesofbinaryliquidmixturesatvarioustemperaturesusingmcallistermodel
AT kramesh measurementandpredictionofthermophysicalpropertiesofbinaryliquidmixturesatvarioustemperaturesusingmcallistermodel