The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
Considering palm oil as non-drying oil owing to its low iodine value, an attempt was taken to increase the unsaturation in the fatty acid chains of palm oil for the preparation of alkyds. To increase the unsaturation in the palm oil, sulphuric acid (SA) and para-toluene sulphonic acid (PTSA) was us...
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| Format: | Article |
| Language: | English English |
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World Academy of Science, Engineering and Technology
2015
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| Online Access: | http://umpir.ump.edu.my/id/eprint/6165/1/The%20Effects%20of%20Increasing%20Unsaturation%20in%20Palm%20Oil%20and%20Incorporation%20of%20Carbon%20Nanotubes%20on%20Resinous%20Properties.pdf http://umpir.ump.edu.my/id/eprint/6165/7/fkksa-2015-mdh-Effects%20of%20Increasing.pdf |
| _version_ | 1796990055542161408 |
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| author | M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari |
| author_facet | M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari |
| author_sort | M. R., Islam |
| collection | UMP |
| description | Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in the fatty acid chains of palm oil for the preparation of alkyds. To increase the unsaturation in the palm oil, sulphuric acid (SA) and para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for the dehydration process. The iodine number of the oil samples was checked for the unsaturation measurement by Wijs method. Alkyd resin was prepared using the dehydrated palm oil by following alcoholysis and esterification reaction. To improve the film properties 0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to manufacture polymeric film. The properties of the resins were characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural elucidation was confirmed by Fourier transform of infrared spectroscopy and proton nuclear magnetic resonance; surfaces of the films were examined by field-emission scanning electron microscope. In addition, pencil hardness and chemical resistivity was also measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and motivational. The resin prepared with dehydrated palm oil showed improved properties regarding hardness and chemical resistivity testing. The incorporation of MWCNTs enhanced the thermal stability and hardness of the films as well.
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| first_indexed | 2024-03-06T11:46:00Z |
| format | Article |
| id | UMPir6165 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-03-06T11:46:00Z |
| publishDate | 2015 |
| publisher | World Academy of Science, Engineering and Technology |
| record_format | dspace |
| spelling | UMPir61652018-01-10T03:15:34Z http://umpir.ump.edu.my/id/eprint/6165/ The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari TP Chemical technology Considering palm oil as non-drying oil owing to its low iodine value, an attempt was taken to increase the unsaturation in the fatty acid chains of palm oil for the preparation of alkyds. To increase the unsaturation in the palm oil, sulphuric acid (SA) and para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for the dehydration process. The iodine number of the oil samples was checked for the unsaturation measurement by Wijs method. Alkyd resin was prepared using the dehydrated palm oil by following alcoholysis and esterification reaction. To improve the film properties 0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to manufacture polymeric film. The properties of the resins were characterized by various physico-chemical properties such as density, viscosity, iodine value, saponification value, etc. Structural elucidation was confirmed by Fourier transform of infrared spectroscopy and proton nuclear magnetic resonance; surfaces of the films were examined by field-emission scanning electron microscope. In addition, pencil hardness and chemical resistivity was also measured by using standard methods. The effect of enhancement of the unsaturation in the fatty acid chain found significant and motivational. The resin prepared with dehydrated palm oil showed improved properties regarding hardness and chemical resistivity testing. The incorporation of MWCNTs enhanced the thermal stability and hardness of the films as well. World Academy of Science, Engineering and Technology 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6165/1/The%20Effects%20of%20Increasing%20Unsaturation%20in%20Palm%20Oil%20and%20Incorporation%20of%20Carbon%20Nanotubes%20on%20Resinous%20Properties.pdf application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/6165/7/fkksa-2015-mdh-Effects%20of%20Increasing.pdf M. R., Islam and Beg, M. D. H. and Saidatul Shima, Jamari (2015) The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties. International Journal of Chemical, Nuclear, Materials and Metallurgical Engineering, 9 (3). pp. 475-480. (Published) http://waset.org/publications/10001064/the-effects-of-increasing-unsaturation-in-palm-oil-and-incorporation-of-carbon-nanotubes-on-resinous-properties |
| spellingShingle | TP Chemical technology M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties |
| title | The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties |
| title_full | The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties |
| title_fullStr | The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties |
| title_full_unstemmed | The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties |
| title_short | The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties |
| title_sort | effects of increasing unsaturation in palm oil and incorporation of carbon nanotubes on resinous properties |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/6165/1/The%20Effects%20of%20Increasing%20Unsaturation%20in%20Palm%20Oil%20and%20Incorporation%20of%20Carbon%20Nanotubes%20on%20Resinous%20Properties.pdf http://umpir.ump.edu.my/id/eprint/6165/7/fkksa-2015-mdh-Effects%20of%20Increasing.pdf |
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