Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics

Increasing industry in Malaysia produce high amount of wastewater, thus increase the heavy metal contaminants that become global concern of environment. Adsorption of heavy metals by activated carbon will need higher cost compare to the other adsorbents. Thus, an alternative way of waste utilization...

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Main Author: Hajar Athirah, Mohd Sukri
Format: Undergraduates Project Papers
Language:English
Published: 2013
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/7211/1/Reduction%20of%20Cd%28II%29%2C%20Ag%28II%29%20AND%20Cu%28II%29%20using%20rubber%20seed%20shell%20-%20adsorption%20isotherm%20and%20kinetics.pdf
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author Hajar Athirah, Mohd Sukri
author_facet Hajar Athirah, Mohd Sukri
author_sort Hajar Athirah, Mohd Sukri
collection UMP
description Increasing industry in Malaysia produce high amount of wastewater, thus increase the heavy metal contaminants that become global concern of environment. Adsorption of heavy metals by activated carbon will need higher cost compare to the other adsorbents. Thus, an alternative way of waste utilization is initializing by researcher to reduce wastewater management cost. The objective of this research is to investigate the potential of rubber seed shell as alternative adsorbent to reduce Cd(II), Ag(II) and Cu(II) ions from aqueous solution by find its kinetic and adsorption isotherm using batch techniques. The adsorbent and adsorbate prepared is used for testing the effect of removal of the ions by the variation parameters of solution pH (pH2, Ph4,pH6 pH8,pH10), contact time (40min, 60min, 80min, 100min, 120min), adsorbent dosage (0.1g, 0.2g, 0.3g, 0.4g, 0.5g) and initial concentration (20ppm, 40ppm, 60ppm, 80ppm, 100ppm). The optimum ph=6, effective time and dosage of 120min and 0.3g is use through all parameters variation. All the experiments are using batch adsorption process and finalize by shake using rotary shaker and analyze using Atomic Absorption Spectroscopy (AAS). This adsorption case fit Langmuir isotherm with correlation coefficient of 0.9991 and satisfactory Pseudo-second order kinetic with correlation coefficient of 1 for all metal and adsorption constant range 0.0662 to 0.1873 g/mg.min. This research approved that rubber seed shell can be used as an alternative adsorbent to reduce Cd (II), Ag (II) and Cu (II) ions from aqueous solution.
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spelling UMPir72112023-11-23T01:32:31Z http://umpir.ump.edu.my/id/eprint/7211/ Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics Hajar Athirah, Mohd Sukri TP Chemical technology Increasing industry in Malaysia produce high amount of wastewater, thus increase the heavy metal contaminants that become global concern of environment. Adsorption of heavy metals by activated carbon will need higher cost compare to the other adsorbents. Thus, an alternative way of waste utilization is initializing by researcher to reduce wastewater management cost. The objective of this research is to investigate the potential of rubber seed shell as alternative adsorbent to reduce Cd(II), Ag(II) and Cu(II) ions from aqueous solution by find its kinetic and adsorption isotherm using batch techniques. The adsorbent and adsorbate prepared is used for testing the effect of removal of the ions by the variation parameters of solution pH (pH2, Ph4,pH6 pH8,pH10), contact time (40min, 60min, 80min, 100min, 120min), adsorbent dosage (0.1g, 0.2g, 0.3g, 0.4g, 0.5g) and initial concentration (20ppm, 40ppm, 60ppm, 80ppm, 100ppm). The optimum ph=6, effective time and dosage of 120min and 0.3g is use through all parameters variation. All the experiments are using batch adsorption process and finalize by shake using rotary shaker and analyze using Atomic Absorption Spectroscopy (AAS). This adsorption case fit Langmuir isotherm with correlation coefficient of 0.9991 and satisfactory Pseudo-second order kinetic with correlation coefficient of 1 for all metal and adsorption constant range 0.0662 to 0.1873 g/mg.min. This research approved that rubber seed shell can be used as an alternative adsorbent to reduce Cd (II), Ag (II) and Cu (II) ions from aqueous solution. 2013-02 Undergraduates Project Papers NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/7211/1/Reduction%20of%20Cd%28II%29%2C%20Ag%28II%29%20AND%20Cu%28II%29%20using%20rubber%20seed%20shell%20-%20adsorption%20isotherm%20and%20kinetics.pdf Hajar Athirah, Mohd Sukri (2013) Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics. Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang.
spellingShingle TP Chemical technology
Hajar Athirah, Mohd Sukri
Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics
title Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics
title_full Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics
title_fullStr Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics
title_full_unstemmed Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics
title_short Reduction of Cd(II), Ag(II) AND Cu(II) Using Rubber Seed Shell : Adsorption Isotherm and Kinetics
title_sort reduction of cd ii ag ii and cu ii using rubber seed shell adsorption isotherm and kinetics
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/7211/1/Reduction%20of%20Cd%28II%29%2C%20Ag%28II%29%20AND%20Cu%28II%29%20using%20rubber%20seed%20shell%20-%20adsorption%20isotherm%20and%20kinetics.pdf
work_keys_str_mv AT hajarathirahmohdsukri reductionofcdiiagiiandcuiiusingrubberseedshelladsorptionisothermandkinetics