Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)

Abstract—The Paphia undulata shell, which is available in abundance, has no any further processing for value-added materials and is commonly discarded as solid waste, was used as solid catalyst in a transesterification reaction to synthesize biodiesel from Rubber and Jatropha curcas seeds oil (RSO...

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Main Authors: Said, N., Fatimah A., Misebah, Siti F., Haron, Nur S., Ghazali, R. M., Yunus, Jolius, Gimbun
Format: Article
Language:English
Published: IACSIT Press 2014
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/7540/1/fkksa-2014-said_nurdin-Activated_Paphia_undulate.pdf
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author Said, N.
Fatimah A., Misebah
Siti F., Haron
Nur S., Ghazali
R. M., Yunus
Jolius, Gimbun
author_facet Said, N.
Fatimah A., Misebah
Siti F., Haron
Nur S., Ghazali
R. M., Yunus
Jolius, Gimbun
author_sort Said, N.
collection UMP
description Abstract—The Paphia undulata shell, which is available in abundance, has no any further processing for value-added materials and is commonly discarded as solid waste, was used as solid catalyst in a transesterification reaction to synthesize biodiesel from Rubber and Jatropha curcas seeds oil (RSOME and JSOME). The biodiesel non-vegetable oil feedstock and catalyst were prepared, characterized, activated and analyzed using GC, FESEM, BET, DTA-TGA, XRF and FTIR analysis. The activated Paphia undulata shells waste (APSW) had a maximum surface area of 2.1290 m 2/g, diameters of 17- 3000 Å, pores adsorption and desorption cumulative volume were 0.006841cm 3/g and 0.006928cm 3/g with the pores size of 312.527 Å, and it reflected the composition of 83.99 – 86.25 % calcium oxide, etc. The resulted Rubber and Jatropha seeds oil biodiesel yields of 75.93% and 93.33% were found by the methanol/oil ratio of 6:1, catalyst amount of 4 wt.%, temperature of 60oC and reaction time of 3 hours. The synthesized biodiesels were approved by GC-MS, and its properties fulfills the limitation of specification described by ASTM D6751.
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spelling UMPir75402018-01-15T02:35:54Z http://umpir.ump.edu.my/id/eprint/7540/ Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME) Said, N. Fatimah A., Misebah Siti F., Haron Nur S., Ghazali R. M., Yunus Jolius, Gimbun TP Chemical technology Abstract—The Paphia undulata shell, which is available in abundance, has no any further processing for value-added materials and is commonly discarded as solid waste, was used as solid catalyst in a transesterification reaction to synthesize biodiesel from Rubber and Jatropha curcas seeds oil (RSOME and JSOME). The biodiesel non-vegetable oil feedstock and catalyst were prepared, characterized, activated and analyzed using GC, FESEM, BET, DTA-TGA, XRF and FTIR analysis. The activated Paphia undulata shells waste (APSW) had a maximum surface area of 2.1290 m 2/g, diameters of 17- 3000 Å, pores adsorption and desorption cumulative volume were 0.006841cm 3/g and 0.006928cm 3/g with the pores size of 312.527 Å, and it reflected the composition of 83.99 – 86.25 % calcium oxide, etc. The resulted Rubber and Jatropha seeds oil biodiesel yields of 75.93% and 93.33% were found by the methanol/oil ratio of 6:1, catalyst amount of 4 wt.%, temperature of 60oC and reaction time of 3 hours. The synthesized biodiesels were approved by GC-MS, and its properties fulfills the limitation of specification described by ASTM D6751. IACSIT Press 2014 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/7540/1/fkksa-2014-said_nurdin-Activated_Paphia_undulate.pdf Said, N. and Fatimah A., Misebah and Siti F., Haron and Nur S., Ghazali and R. M., Yunus and Jolius, Gimbun (2014) Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME). International Journal of Chemical Engineering and Applications (IJCEA), 5 (6). pp. 483-488. ISSN 2010-0221. (Published) http://dx.doi.org/10.7763/IJCEA.2014.V5.433 DOI: 10.7763/IJCEA.2014.V5.433
spellingShingle TP Chemical technology
Said, N.
Fatimah A., Misebah
Siti F., Haron
Nur S., Ghazali
R. M., Yunus
Jolius, Gimbun
Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)
title Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)
title_full Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)
title_fullStr Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)
title_full_unstemmed Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)
title_short Activated Paphia undulate Shells Waste (APSW): A Cost-Effective Catalyst for Biodiesel Synthesis from Rubber and Jatropha curcas Seeds Oil (RSOME & JSOME)
title_sort activated paphia undulate shells waste apsw a cost effective catalyst for biodiesel synthesis from rubber and jatropha curcas seeds oil rsome jsome
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/7540/1/fkksa-2014-said_nurdin-Activated_Paphia_undulate.pdf
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