Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
ZSM-5 zeolite is one type of heterogeneous catalyst which obtained in the solid form. There are several advantages of heterogeneous catalyst in the chemical reaction compared to homogeneous such cost reduction, environmental friendly and easy to separate. In this study, ZSM-5 zeolite was synthesiz...
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| Materiálatiipa: | Undergraduates Project Papers |
| Giella: | English |
| Almmustuhtton: |
2012
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| Liŋkkat: | http://umpir.ump.edu.my/id/eprint/7816/1/NIK_ROHANI_BT._NIK_MUSTAPA.PDF |
| _version_ | 1825822004225245184 |
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| author | Nik Rohani, Nik Mustapa |
| author_facet | Nik Rohani, Nik Mustapa |
| author_sort | Nik Rohani, Nik Mustapa |
| collection | UMP |
| description | ZSM-5 zeolite is one type of heterogeneous catalyst which obtained in the solid form. There are several advantages of heterogeneous catalyst in the chemical reaction
compared to homogeneous such cost reduction, environmental friendly and easy to separate. In this study, ZSM-5 zeolite was synthesized using hydrothermal method utilising rice husk ash (RHA) which is agriculture waste of silica source. Then, the prepared ZSM-5 zeolite with different ratios of Si0 2/Al2 0 3 was characterized by means of Fourier Transformed-Infrared Spectroscopy (FT-IR), Surface Area Analyzer (BET), X-Ray Diffraction (XRD) and Thermogravimetric Analysis (TGA). The catalytic activity of ZSM-5 zeolite was tested by the reaction of acetophenone and benzaldehyde
to chalcone at 150 °C and 6 hours. The conversion of the reaction was evaluated using Gas Chromatography-Flame Ion Detector (GC-FID). The conversion to chalcone by HZSM-5(30) give yield up to 82.44 %, Na-ZSM-5(60) give 82.72 %, H-ZSM-5(60) give 82.86 % and Na-ZSM-5(30) give the highest yield of 91.95 %.
Keywords: heterogeneous catalyst, ZSM-5, zeolite, chalcone, acidic properties |
| first_indexed | 2024-03-06T11:50:05Z |
| format | Undergraduates Project Papers |
| id | UMPir7816 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T11:50:05Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | UMPir78162021-06-09T03:33:42Z http://umpir.ump.edu.my/id/eprint/7816/ Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction Nik Rohani, Nik Mustapa TP Chemical technology ZSM-5 zeolite is one type of heterogeneous catalyst which obtained in the solid form. There are several advantages of heterogeneous catalyst in the chemical reaction compared to homogeneous such cost reduction, environmental friendly and easy to separate. In this study, ZSM-5 zeolite was synthesized using hydrothermal method utilising rice husk ash (RHA) which is agriculture waste of silica source. Then, the prepared ZSM-5 zeolite with different ratios of Si0 2/Al2 0 3 was characterized by means of Fourier Transformed-Infrared Spectroscopy (FT-IR), Surface Area Analyzer (BET), X-Ray Diffraction (XRD) and Thermogravimetric Analysis (TGA). The catalytic activity of ZSM-5 zeolite was tested by the reaction of acetophenone and benzaldehyde to chalcone at 150 °C and 6 hours. The conversion of the reaction was evaluated using Gas Chromatography-Flame Ion Detector (GC-FID). The conversion to chalcone by HZSM-5(30) give yield up to 82.44 %, Na-ZSM-5(60) give 82.72 %, H-ZSM-5(60) give 82.86 % and Na-ZSM-5(30) give the highest yield of 91.95 %. Keywords: heterogeneous catalyst, ZSM-5, zeolite, chalcone, acidic properties 2012 Undergraduates Project Papers NonPeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/7816/1/NIK_ROHANI_BT._NIK_MUSTAPA.PDF Nik Rohani, Nik Mustapa (2012) Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction. Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang. |
| spellingShingle | TP Chemical technology Nik Rohani, Nik Mustapa Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction |
| title | Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction |
| title_full | Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction |
| title_fullStr | Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction |
| title_full_unstemmed | Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction |
| title_short | Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction |
| title_sort | synthesis and characterization of zsm 5 zeolite as catalyst in claisen schmidt condensation reaction |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/7816/1/NIK_ROHANI_BT._NIK_MUSTAPA.PDF |
| work_keys_str_mv | AT nikrohaninikmustapa synthesisandcharacterizationofzsm5zeoliteascatalystinclaisenschmidtcondensationreaction |