Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode

A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural b-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of b-carotene successfully removes oxygen functionalities on GO nanosheets...

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Main Authors: K. F., Chong, M. Zaid, Rubaiyi, Teo, Ellie Yi Lih, Chong, Fui Chin, Ng, Eng Poh
Format: Article
Language:English
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8003/1/Rubaiyi_et_al_2014_BRGO.pdf
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author K. F., Chong
M. Zaid, Rubaiyi
Teo, Ellie Yi Lih
Chong, Fui Chin
Ng, Eng Poh
author_facet K. F., Chong
M. Zaid, Rubaiyi
Teo, Ellie Yi Lih
Chong, Fui Chin
Ng, Eng Poh
author_sort K. F., Chong
collection UMP
description A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural b-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of b-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM b-carotene as confirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore, the mechanism of GO reduction by b-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of b-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction of GO nanosheets by b-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode.
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spelling UMPir80032018-03-26T07:37:31Z http://umpir.ump.edu.my/id/eprint/8003/ Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode K. F., Chong M. Zaid, Rubaiyi Teo, Ellie Yi Lih Chong, Fui Chin Ng, Eng Poh TP Chemical technology A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural b-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of b-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM b-carotene as confirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore, the mechanism of GO reduction by b-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of b-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction of GO nanosheets by b-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode. Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8003/1/Rubaiyi_et_al_2014_BRGO.pdf K. F., Chong and M. Zaid, Rubaiyi and Teo, Ellie Yi Lih and Chong, Fui Chin and Ng, Eng Poh Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode. Arabian Journal of Chemistry. (In Press / Online First) (In Press / Online First) http://dx.doi.org/10.1016/j.arabjc.2014.11.036
spellingShingle TP Chemical technology
K. F., Chong
M. Zaid, Rubaiyi
Teo, Ellie Yi Lih
Chong, Fui Chin
Ng, Eng Poh
Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode
title Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode
title_full Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode
title_fullStr Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode
title_full_unstemmed Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode
title_short Reduction Of Graphene Oxide Nanosheets By Natural Beta Carotene And Its Potential Use As Supercapacitor Electrode
title_sort reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/8003/1/Rubaiyi_et_al_2014_BRGO.pdf
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