6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid
The asymmetric unit of the title compound, C17H18O3, comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)� and 1.5 (2)�. The butene group in all three molecul...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/8120/1/Paper_8.pdf |
| _version_ | 1796990390065168384 |
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| author | Lutfor, M. R. M. M., Yusoff |
| author_facet | Lutfor, M. R. M. M., Yusoff |
| author_sort | Lutfor, M. R. |
| collection | UMP |
| description | The asymmetric unit of the title compound, C17H18O3,
comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)� and 1.5 (2)�. The butene group in all three molecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664 (6):0.336 (6). In the crystal, molecules
are oriented with respect to their carbonyl groups, forming head-to-head dimers via O—H� � �O hydrogen bonds. Adjacent dimers are further interconnected by C—H� � �O
hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C—H� � ��
interactions. |
| first_indexed | 2024-03-06T11:50:51Z |
| format | Article |
| id | UMPir8120 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T11:50:51Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | UMPir81202018-02-06T07:49:01Z http://umpir.ump.edu.my/id/eprint/8120/ 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid Lutfor, M. R. M. M., Yusoff QD Chemistry The asymmetric unit of the title compound, C17H18O3, comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)� and 1.5 (2)�. The butene group in all three molecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664 (6):0.336 (6). In the crystal, molecules are oriented with respect to their carbonyl groups, forming head-to-head dimers via O—H� � �O hydrogen bonds. Adjacent dimers are further interconnected by C—H� � �O hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C—H� � �� interactions. International Union of Crystallography 2014-05-09 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/8120/1/Paper_8.pdf Lutfor, M. R. and M. M., Yusoff (2014) 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid. Acta Crystallographica Section E, E70. 0696-0697. (Published) http://journals.iucr.org/e/journalhomepage.html doi:10.1107/S1600536814010642 |
| spellingShingle | QD Chemistry Lutfor, M. R. M. M., Yusoff 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_full | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_fullStr | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_full_unstemmed | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_short | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_sort | 6 hex 5 enyloxy naphthalene 2 carboxylic acid |
| topic | QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/8120/1/Paper_8.pdf |
| work_keys_str_mv | AT lutformr 6hex5enyloxynaphthalene2carboxylicacid AT mmyusoff 6hex5enyloxynaphthalene2carboxylicacid |