Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells

Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and...

Full description

Bibliographic Details
Main Authors: Irfan, Ahmed, Fakharuddin, Azhar, Qamar, Wali, Ayib Rosdi, Zainun, Jamil, Ismail, Rajan, Jose
Format: Article
Language:English
Published: IOP Publishing Ltd 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf
_version_ 1825822135432511488
author Irfan, Ahmed
Fakharuddin, Azhar
Qamar, Wali
Ayib Rosdi, Zainun
Jamil, Ismail
Rajan, Jose
author_facet Irfan, Ahmed
Fakharuddin, Azhar
Qamar, Wali
Ayib Rosdi, Zainun
Jamil, Ismail
Rajan, Jose
author_sort Irfan, Ahmed
collection UMP
description Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and have achieved a high photoconversion efficiency of (η) > 11% with an internal quantum efficiency of ~93% in electrode films of thickness ~7 ± 0.5 μm. Controlling the interface between the vertical nanorods and the mesoporous film is a crucial step in attaining high η. We identify three parameters, viz., large surface area of nanoparticles, increased light scattering of the nanorod�nanoparticle layer, and superior charge transport of nanorods, that simultaneously contribute to the improved photovoltaic performance of the WE developed.
first_indexed 2024-03-06T11:52:03Z
format Article
id UMPir8604
institution Universiti Malaysia Pahang
language English
last_indexed 2024-03-06T11:52:03Z
publishDate 2015
publisher IOP Publishing Ltd
record_format dspace
spelling UMPir86042018-02-08T03:13:51Z http://umpir.ump.edu.my/id/eprint/8604/ Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells Irfan, Ahmed Fakharuddin, Azhar Qamar, Wali Ayib Rosdi, Zainun Jamil, Ismail Rajan, Jose QC Physics QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and have achieved a high photoconversion efficiency of (η) > 11% with an internal quantum efficiency of ~93% in electrode films of thickness ~7 ± 0.5 μm. Controlling the interface between the vertical nanorods and the mesoporous film is a crucial step in attaining high η. We identify three parameters, viz., large surface area of nanoparticles, increased light scattering of the nanorod�nanoparticle layer, and superior charge transport of nanorods, that simultaneously contribute to the improved photovoltaic performance of the WE developed. IOP Publishing Ltd 2015-03-13 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf Irfan, Ahmed and Fakharuddin, Azhar and Qamar, Wali and Ayib Rosdi, Zainun and Jamil, Ismail and Rajan, Jose (2015) Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells. Nanotechnology, 26 (105401). pp. 1-8. ISSN 0957-4484. (Published) http://dx.doi.org/10.1088/0957-4484/26/10/105401 DOI: 10.1088/0957-4484/26/10/105401
spellingShingle QC Physics
QD Chemistry
T Technology (General)
TK Electrical engineering. Electronics Nuclear engineering
Irfan, Ahmed
Fakharuddin, Azhar
Qamar, Wali
Ayib Rosdi, Zainun
Jamil, Ismail
Rajan, Jose
Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_full Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_fullStr Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_full_unstemmed Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_short Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_sort mesoporous titania vertical nanorod films with interfacial engineering for high performance dye sensitized solar cells
topic QC Physics
QD Chemistry
T Technology (General)
TK Electrical engineering. Electronics Nuclear engineering
url http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf
work_keys_str_mv AT irfanahmed mesoporoustitaniaverticalnanorodfilmswithinterfacialengineeringforhighperformancedyesensitizedsolarcells
AT fakharuddinazhar mesoporoustitaniaverticalnanorodfilmswithinterfacialengineeringforhighperformancedyesensitizedsolarcells
AT qamarwali mesoporoustitaniaverticalnanorodfilmswithinterfacialengineeringforhighperformancedyesensitizedsolarcells
AT ayibrosdizainun mesoporoustitaniaverticalnanorodfilmswithinterfacialengineeringforhighperformancedyesensitizedsolarcells
AT jamilismail mesoporoustitaniaverticalnanorodfilmswithinterfacialengineeringforhighperformancedyesensitizedsolarcells
AT rajanjose mesoporoustitaniaverticalnanorodfilmswithinterfacialengineeringforhighperformancedyesensitizedsolarcells