Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and...
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Format: | Article |
Language: | English |
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IOP Publishing Ltd
2015
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Online Access: | http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf |
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author | Irfan, Ahmed Fakharuddin, Azhar Qamar, Wali Ayib Rosdi, Zainun Jamil, Ismail Rajan, Jose |
author_facet | Irfan, Ahmed Fakharuddin, Azhar Qamar, Wali Ayib Rosdi, Zainun Jamil, Ismail Rajan, Jose |
author_sort | Irfan, Ahmed |
collection | UMP |
description | Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and have achieved a high photoconversion efficiency of (η) > 11% with an internal quantum efficiency of ~93% in electrode films of thickness ~7 ± 0.5 μm. Controlling the interface between the vertical nanorods and the mesoporous film is a crucial step in attaining high η. We identify three parameters, viz., large surface area of nanoparticles, increased light scattering of the nanorod�nanoparticle layer, and superior charge transport of nanorods, that simultaneously contribute to the improved photovoltaic performance of the WE developed. |
first_indexed | 2024-03-06T11:52:03Z |
format | Article |
id | UMPir8604 |
institution | Universiti Malaysia Pahang |
language | English |
last_indexed | 2024-03-06T11:52:03Z |
publishDate | 2015 |
publisher | IOP Publishing Ltd |
record_format | dspace |
spelling | UMPir86042018-02-08T03:13:51Z http://umpir.ump.edu.my/id/eprint/8604/ Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells Irfan, Ahmed Fakharuddin, Azhar Qamar, Wali Ayib Rosdi, Zainun Jamil, Ismail Rajan, Jose QC Physics QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and have achieved a high photoconversion efficiency of (η) > 11% with an internal quantum efficiency of ~93% in electrode films of thickness ~7 ± 0.5 μm. Controlling the interface between the vertical nanorods and the mesoporous film is a crucial step in attaining high η. We identify three parameters, viz., large surface area of nanoparticles, increased light scattering of the nanorod�nanoparticle layer, and superior charge transport of nanorods, that simultaneously contribute to the improved photovoltaic performance of the WE developed. IOP Publishing Ltd 2015-03-13 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf Irfan, Ahmed and Fakharuddin, Azhar and Qamar, Wali and Ayib Rosdi, Zainun and Jamil, Ismail and Rajan, Jose (2015) Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells. Nanotechnology, 26 (105401). pp. 1-8. ISSN 0957-4484. (Published) http://dx.doi.org/10.1088/0957-4484/26/10/105401 DOI: 10.1088/0957-4484/26/10/105401 |
spellingShingle | QC Physics QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering Irfan, Ahmed Fakharuddin, Azhar Qamar, Wali Ayib Rosdi, Zainun Jamil, Ismail Rajan, Jose Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells |
title | Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells |
title_full | Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells |
title_fullStr | Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells |
title_full_unstemmed | Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells |
title_short | Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells |
title_sort | mesoporous titania vertical nanorod films with interfacial engineering for high performance dye sensitized solar cells |
topic | QC Physics QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering |
url | http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf |
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