Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in mic...
| Main Authors: | , |
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| Format: | Article |
| Language: | English English |
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Trans Tech Publications, Switzerland
2016
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/8742/1/Non-Aqueous%20Dispersion%20%28NAD%29%20Polymerisation-Based%20Synthetic%20Route%20to%20Hypercrosslinked%20Polymer%20With%20High%20Specific%20Surface%20Areas.pdf http://umpir.ump.edu.my/id/eprint/8742/7/fkksa-2016-hayati-Non-Aqueous%20Dispersion.pdf |
| _version_ | 1825822160269082624 |
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| author | Norhayati, Abdullah Cormack, Peter A. G. |
| author_facet | Norhayati, Abdullah Cormack, Peter A. G. |
| author_sort | Norhayati, Abdullah |
| collection | UMP |
| description | Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in microsphere form, and were used subsequently in hypercrosslinking reactions. Extensive microporosity was generated in the products, leading to remarkably high inner specific surface areas of up to ~1,500 m2/g. SEM and BET spectroscopy were used to monitor the course of the hypercrosslinking reactions. |
| first_indexed | 2024-03-06T11:52:25Z |
| format | Article |
| id | UMPir8742 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-03-06T11:52:25Z |
| publishDate | 2016 |
| publisher | Trans Tech Publications, Switzerland |
| record_format | dspace |
| spelling | UMPir87422018-05-14T07:12:53Z http://umpir.ump.edu.my/id/eprint/8742/ Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas Norhayati, Abdullah Cormack, Peter A. G. TP Chemical technology Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in microsphere form, and were used subsequently in hypercrosslinking reactions. Extensive microporosity was generated in the products, leading to remarkably high inner specific surface areas of up to ~1,500 m2/g. SEM and BET spectroscopy were used to monitor the course of the hypercrosslinking reactions. Trans Tech Publications, Switzerland 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8742/1/Non-Aqueous%20Dispersion%20%28NAD%29%20Polymerisation-Based%20Synthetic%20Route%20to%20Hypercrosslinked%20Polymer%20With%20High%20Specific%20Surface%20Areas.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/8742/7/fkksa-2016-hayati-Non-Aqueous%20Dispersion.pdf Norhayati, Abdullah and Cormack, Peter A. G. (2016) Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas. Advanced Materials Research, 1134. pp. 198-202. ISSN 1022-6680 (print), 1662-8985 (online). (Published) http://www.scientific.net/AMR.1134.198 doi: 10.4028/www.scientific.net/AMR.1134.198 |
| spellingShingle | TP Chemical technology Norhayati, Abdullah Cormack, Peter A. G. Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas |
| title | Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas |
| title_full | Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas |
| title_fullStr | Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas |
| title_full_unstemmed | Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas |
| title_short | Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas |
| title_sort | non aqueous dispersion nad polymerisation based synthetic route to hypercrosslinked polymer with high specific surface areas |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/8742/1/Non-Aqueous%20Dispersion%20%28NAD%29%20Polymerisation-Based%20Synthetic%20Route%20to%20Hypercrosslinked%20Polymer%20With%20High%20Specific%20Surface%20Areas.pdf http://umpir.ump.edu.my/id/eprint/8742/7/fkksa-2016-hayati-Non-Aqueous%20Dispersion.pdf |
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