Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell

Microbial fuel cells (MFCs) represent a promising technology for simultaneous bioelectricity generation and wastewater treatment. Catalysts are significant portions of the cost of microbial fuel cell cathodes. Many materials have been tested as aqueous cathodes, but air-cathodes are needed to avoid...

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Main Authors: Khan, Maksudur R., Kar, Min Chan, Huei, Ruey Ong, Cheng, C. K., Wasikur, Rahman
Format: Article
Language:English
Published: World Academy of Science, Engineering and Technology 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/9086/1/fkksa-2015-maksudur-Nanostructured%20PtMnO2%20Catalysts.pdf
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author Khan, Maksudur R.
Kar, Min Chan
Huei, Ruey Ong
Cheng, C. K.
Wasikur, Rahman
author_facet Khan, Maksudur R.
Kar, Min Chan
Huei, Ruey Ong
Cheng, C. K.
Wasikur, Rahman
author_sort Khan, Maksudur R.
collection UMP
description Microbial fuel cells (MFCs) represent a promising technology for simultaneous bioelectricity generation and wastewater treatment. Catalysts are significant portions of the cost of microbial fuel cell cathodes. Many materials have been tested as aqueous cathodes, but air-cathodes are needed to avoid energy demands for water aeration. The sluggish oxygen reduction reaction (ORR) rate at air cathode necessitates efficient electrocatalyst such as carbon supported platinum catalyst (Pt/C) which is very costly. Manganese oxide (MnO2) was a representative metal oxide which has been studied as a promising alternative electrocatalyst for ORR and has been tested in air-cathode MFCs. However the single MnO2 has poor electric conductivity and low stability. In the present work, the MnO2 catalyst has been modified by doping Pt nanoparticle. The goal of the work was to improve the performance of the MFC with minimum Pt loading. MnO2 and Pt nanoparticles were prepared by hydrothermal and sol gel methods,respectively. Wet impregnation method was used to synthesize Pt/MnO2 catalyst.
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spelling UMPir90862018-01-11T03:38:35Z http://umpir.ump.edu.my/id/eprint/9086/ Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell Khan, Maksudur R. Kar, Min Chan Huei, Ruey Ong Cheng, C. K. Wasikur, Rahman TP Chemical technology Microbial fuel cells (MFCs) represent a promising technology for simultaneous bioelectricity generation and wastewater treatment. Catalysts are significant portions of the cost of microbial fuel cell cathodes. Many materials have been tested as aqueous cathodes, but air-cathodes are needed to avoid energy demands for water aeration. The sluggish oxygen reduction reaction (ORR) rate at air cathode necessitates efficient electrocatalyst such as carbon supported platinum catalyst (Pt/C) which is very costly. Manganese oxide (MnO2) was a representative metal oxide which has been studied as a promising alternative electrocatalyst for ORR and has been tested in air-cathode MFCs. However the single MnO2 has poor electric conductivity and low stability. In the present work, the MnO2 catalyst has been modified by doping Pt nanoparticle. The goal of the work was to improve the performance of the MFC with minimum Pt loading. MnO2 and Pt nanoparticles were prepared by hydrothermal and sol gel methods,respectively. Wet impregnation method was used to synthesize Pt/MnO2 catalyst. World Academy of Science, Engineering and Technology 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9086/1/fkksa-2015-maksudur-Nanostructured%20PtMnO2%20Catalysts.pdf Khan, Maksudur R. and Kar, Min Chan and Huei, Ruey Ong and Cheng, C. K. and Wasikur, Rahman (2015) Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell. International Journal of Electrical, Computer, Electronics and Communication Engineering, 9 (3). pp. 270-276. (Published) http://www.waset.org/abstracts/19318
spellingShingle TP Chemical technology
Khan, Maksudur R.
Kar, Min Chan
Huei, Ruey Ong
Cheng, C. K.
Wasikur, Rahman
Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell
title Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell
title_full Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell
title_fullStr Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell
title_full_unstemmed Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell
title_short Nanostructured Pt/MnO2 Catalysts and Their Performance for Oxygen Reduction Reaction in Air Cathode Microbial Fuel Cell
title_sort nanostructured pt mno2 catalysts and their performance for oxygen reduction reaction in air cathode microbial fuel cell
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/9086/1/fkksa-2015-maksudur-Nanostructured%20PtMnO2%20Catalysts.pdf
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AT hueirueyong nanostructuredptmno2catalystsandtheirperformanceforoxygenreductionreactioninaircathodemicrobialfuelcell
AT chengck nanostructuredptmno2catalystsandtheirperformanceforoxygenreductionreactioninaircathodemicrobialfuelcell
AT wasikurrahman nanostructuredptmno2catalystsandtheirperformanceforoxygenreductionreactioninaircathodemicrobialfuelcell