Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles

Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the prese...

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Main Authors: Mohd Hasbi, Ab. Rahim, Forde, Michael M., Jenkins, Robert L., Hammond, Ceri, He, Qian, Dimitratos, Nikolaos, Lopez-Sanchez, Jose Antonio, Carley, Albert F., Taylor, Stuart H., Willock, David J., Murphy, Damien M., Kiely, Christopher J., Hutchings, Graham J.
Format: Article
Published: Wiley Online Library 2012
Subjects:
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author Mohd Hasbi, Ab. Rahim
Forde, Michael M.
Jenkins, Robert L.
Hammond, Ceri
He, Qian
Dimitratos, Nikolaos
Lopez-Sanchez, Jose Antonio
Carley, Albert F.
Taylor, Stuart H.
Willock, David J.
Murphy, Damien M.
Kiely, Christopher J.
Hutchings, Graham J.
author_facet Mohd Hasbi, Ab. Rahim
Forde, Michael M.
Jenkins, Robert L.
Hammond, Ceri
He, Qian
Dimitratos, Nikolaos
Lopez-Sanchez, Jose Antonio
Carley, Albert F.
Taylor, Stuart H.
Willock, David J.
Murphy, Damien M.
Kiely, Christopher J.
Hutchings, Graham J.
author_sort Mohd Hasbi, Ab. Rahim
collection UMP
description Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen.
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institution Universiti Malaysia Pahang
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spelling UMPir94702018-11-22T07:41:49Z http://umpir.ump.edu.my/id/eprint/9470/ Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles Mohd Hasbi, Ab. Rahim Forde, Michael M. Jenkins, Robert L. Hammond, Ceri He, Qian Dimitratos, Nikolaos Lopez-Sanchez, Jose Antonio Carley, Albert F. Taylor, Stuart H. Willock, David J. Murphy, Damien M. Kiely, Christopher J. Hutchings, Graham J. QD Chemistry TP Chemical technology Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen. Wiley Online Library 2012-12-11 Article PeerReviewed Mohd Hasbi, Ab. Rahim and Forde, Michael M. and Jenkins, Robert L. and Hammond, Ceri and He, Qian and Dimitratos, Nikolaos and Lopez-Sanchez, Jose Antonio and Carley, Albert F. and Taylor, Stuart H. and Willock, David J. and Murphy, Damien M. and Kiely, Christopher J. and Hutchings, Graham J. (2012) Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles. Angewandte Chemie International Edition, 52 (4). pp. 1280-1284. ISSN 1521-3773. (Published) http://onlinelibrary.wiley.com/doi/10.1002/anie.201207717/abstract DOI: 10.1002/anie.201207717
spellingShingle QD Chemistry
TP Chemical technology
Mohd Hasbi, Ab. Rahim
Forde, Michael M.
Jenkins, Robert L.
Hammond, Ceri
He, Qian
Dimitratos, Nikolaos
Lopez-Sanchez, Jose Antonio
Carley, Albert F.
Taylor, Stuart H.
Willock, David J.
Murphy, Damien M.
Kiely, Christopher J.
Hutchings, Graham J.
Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles
title Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles
title_full Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles
title_fullStr Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles
title_full_unstemmed Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles
title_short Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold–Palladium Alloy Nanoparticles
title_sort oxidation of methane to methanol with hydrogen peroxide using supported gold palladium alloy nanoparticles
topic QD Chemistry
TP Chemical technology
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