Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier
SBA-15 mesoporous silica was directly synthesised under difference acidic conditions by a “pH modification method” using hexamethylenetetramine (HMTA) as an internal pH-modifier. The synthesised material has been characterised by XRD, Nitrogen adsorption–desorption, and TEM. The characterisation res...
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| Format: | Article |
| Language: | English |
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Trans Tech Publications, Switzerland
2015
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| Online Access: | http://umpir.ump.edu.my/id/eprint/9541/1/fist-2015-ridzuan-Synthesis%20and%20Characteristics.pdf |
| _version_ | 1796990633807708160 |
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| author | Mohd Haizal, Mohd Husin Mohd Ridzuan, Nordin Imran Syakir, Mohamad Jin Lin, Li |
| author_facet | Mohd Haizal, Mohd Husin Mohd Ridzuan, Nordin Imran Syakir, Mohamad Jin Lin, Li |
| author_sort | Mohd Haizal, Mohd Husin |
| collection | UMP |
| description | SBA-15 mesoporous silica was directly synthesised under difference acidic conditions by a “pH modification method” using hexamethylenetetramine (HMTA) as an internal pH-modifier. The synthesised material has been characterised by XRD, Nitrogen adsorption–desorption, and TEM. The characterisation results showed that mesoporous silica lead to high-ordered hexagonal mesoporous morphology by TEM at high acidity compared to low acidity condition. In addition, the physical properties of SBA-15 showed a decrease of surface area and pore size due to the increase in the pH. Use of HMTA as pH modifier is suitable, due to pH value increases occurred in the hydrothermal processes only. This is because during the hydrothermal process at a temperature of 100°C, HMTA decomposes to NH3 which in turn increase of the pH value in the silica gel. It can be concluded that the formation of mesoporous silica SBA-15 to some extent been influenced by the pH value. This can be seen from the results of the study show that mesoporous silica type SBA-15 lead to well-ordered hexagonal mesoporous at high acidity and poor order hexagonal pore structure was formed in low acidity condition. |
| first_indexed | 2024-03-06T11:54:27Z |
| format | Article |
| id | UMPir9541 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T11:54:27Z |
| publishDate | 2015 |
| publisher | Trans Tech Publications, Switzerland |
| record_format | dspace |
| spelling | UMPir95412018-11-29T09:17:04Z http://umpir.ump.edu.my/id/eprint/9541/ Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier Mohd Haizal, Mohd Husin Mohd Ridzuan, Nordin Imran Syakir, Mohamad Jin Lin, Li Q Science (General) SBA-15 mesoporous silica was directly synthesised under difference acidic conditions by a “pH modification method” using hexamethylenetetramine (HMTA) as an internal pH-modifier. The synthesised material has been characterised by XRD, Nitrogen adsorption–desorption, and TEM. The characterisation results showed that mesoporous silica lead to high-ordered hexagonal mesoporous morphology by TEM at high acidity compared to low acidity condition. In addition, the physical properties of SBA-15 showed a decrease of surface area and pore size due to the increase in the pH. Use of HMTA as pH modifier is suitable, due to pH value increases occurred in the hydrothermal processes only. This is because during the hydrothermal process at a temperature of 100°C, HMTA decomposes to NH3 which in turn increase of the pH value in the silica gel. It can be concluded that the formation of mesoporous silica SBA-15 to some extent been influenced by the pH value. This can be seen from the results of the study show that mesoporous silica type SBA-15 lead to well-ordered hexagonal mesoporous at high acidity and poor order hexagonal pore structure was formed in low acidity condition. Trans Tech Publications, Switzerland 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9541/1/fist-2015-ridzuan-Synthesis%20and%20Characteristics.pdf Mohd Haizal, Mohd Husin and Mohd Ridzuan, Nordin and Imran Syakir, Mohamad and Jin Lin, Li (2015) Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier. Applied Mechanics and Materials, 761. pp. 473-478. ISSN 1662-7482. (Published) http://www.scientific.net/AMM.761.473 DOI: 10.4028/www.scientific.net/AMM.761.473 |
| spellingShingle | Q Science (General) Mohd Haizal, Mohd Husin Mohd Ridzuan, Nordin Imran Syakir, Mohamad Jin Lin, Li Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier |
| title | Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier |
| title_full | Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier |
| title_fullStr | Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier |
| title_full_unstemmed | Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier |
| title_short | Synthesis and Characteristics of Mesoporous SBA-15 Influence by HMTA as an Internal pH Modifier |
| title_sort | synthesis and characteristics of mesoporous sba 15 influence by hmta as an internal ph modifier |
| topic | Q Science (General) |
| url | http://umpir.ump.edu.my/id/eprint/9541/1/fist-2015-ridzuan-Synthesis%20and%20Characteristics.pdf |
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