Relative Stability of cis- and trans-Hydrindanones
The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, main...
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| Format: | Article |
| Language: | English |
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MDPI AG
2015-01-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/20/1/1509 |
| _version_ | 1830358630931628032 |
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| author | Motoo Tori |
| author_facet | Motoo Tori |
| author_sort | Motoo Tori |
| collection | DOAJ |
| description | The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts. |
| first_indexed | 2024-12-20T02:45:18Z |
| format | Article |
| id | doaj.art-000a35a8d53d4d888fba71fca7e06484 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-20T02:45:18Z |
| publishDate | 2015-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-000a35a8d53d4d888fba71fca7e064842022-12-21T19:56:11ZengMDPI AGMolecules1420-30492015-01-012011509151810.3390/molecules20011509molecules20011509Relative Stability of cis- and trans-HydrindanonesMotoo Tori0Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, JapanThe relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts.http://www.mdpi.com/1420-3049/20/1/1509hydrindanonesisomerizationisomerstereochemistrystabilityMM2 |
| spellingShingle | Motoo Tori Relative Stability of cis- and trans-Hydrindanones Molecules hydrindanones isomerization isomer stereochemistry stability MM2 |
| title | Relative Stability of cis- and trans-Hydrindanones |
| title_full | Relative Stability of cis- and trans-Hydrindanones |
| title_fullStr | Relative Stability of cis- and trans-Hydrindanones |
| title_full_unstemmed | Relative Stability of cis- and trans-Hydrindanones |
| title_short | Relative Stability of cis- and trans-Hydrindanones |
| title_sort | relative stability of cis and trans hydrindanones |
| topic | hydrindanones isomerization isomer stereochemistry stability MM2 |
| url | http://www.mdpi.com/1420-3049/20/1/1509 |
| work_keys_str_mv | AT motootori relativestabilityofcisandtranshydrindanones |