Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells

Molybdenum disulphide (MoS2) nanotube and tungsten oxide (W18O49) nanowire were coated with poly(3-hexylthiophene) (P3HT) and poly(3,4-ethylenedioxythiophene) (PEDOT) by a radio frequency (RF: 13.56 MHz)-rotating plasma-modification method as alternative counter electrodes for dye-sensitised solar c...

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Main Authors: Sule Erten-Ela, Melek Kiristi, Ana Varlec, Ferhat Bozduman, Maja Remskar, Lutfi Oksuz, Aysegul Uygun Oksuz
Format: Article
Language:English
Published: Taylor & Francis Group 2018-08-01
Series:International Journal of Sustainable Energy
Subjects:
Online Access:http://dx.doi.org/10.1080/14786451.2017.1333995
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author Sule Erten-Ela
Melek Kiristi
Ana Varlec
Ferhat Bozduman
Maja Remskar
Lutfi Oksuz
Aysegul Uygun Oksuz
author_facet Sule Erten-Ela
Melek Kiristi
Ana Varlec
Ferhat Bozduman
Maja Remskar
Lutfi Oksuz
Aysegul Uygun Oksuz
author_sort Sule Erten-Ela
collection DOAJ
description Molybdenum disulphide (MoS2) nanotube and tungsten oxide (W18O49) nanowire were coated with poly(3-hexylthiophene) (P3HT) and poly(3,4-ethylenedioxythiophene) (PEDOT) by a radio frequency (RF: 13.56 MHz)-rotating plasma-modification method as alternative counter electrodes for dye-sensitised solar cells (DSSCs). Surface analysis showed the homogenous plasma nanocoating of inorganic nanostructures by P3HT and PEDOT. It was demonstrated that the plasma-modified hybrid platinum-free counter electrodes increased the efficiencies of the DSSCs. The DSSCs based on hybrid nanostructure materials showed a short circuit current density of 9.49, 7.95, 2.59 and 2.57 mAcm−2 for MoS2/P3HT, MoS2/PEDOT, W18O49/PEDOT and W18O49/P3HT samples, respectively. The plasma nanocoating with the nanostructured materials approach for obtaining hybrid counter electrodes in the photovoltaic action shows an alternative route towards cost-effective, green energy conversion.
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spelling doaj.art-000c67905333498d9b1e37ee4b6bfb462023-09-20T10:33:45ZengTaylor & Francis GroupInternational Journal of Sustainable Energy1478-64511478-646X2018-08-0137764065310.1080/14786451.2017.13339951333995Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cellsSule Erten-Ela0Melek Kiristi1Ana Varlec2Ferhat Bozduman3Maja Remskar4Lutfi Oksuz5Aysegul Uygun Oksuz6Solar Energy Institute, Ege UniversitySuleyman Demirel UniversityJozef Stefan InstituteSuleyman Demirel UniversityJozef Stefan InstituteSuleyman Demirel UniversitySuleyman Demirel UniversityMolybdenum disulphide (MoS2) nanotube and tungsten oxide (W18O49) nanowire were coated with poly(3-hexylthiophene) (P3HT) and poly(3,4-ethylenedioxythiophene) (PEDOT) by a radio frequency (RF: 13.56 MHz)-rotating plasma-modification method as alternative counter electrodes for dye-sensitised solar cells (DSSCs). Surface analysis showed the homogenous plasma nanocoating of inorganic nanostructures by P3HT and PEDOT. It was demonstrated that the plasma-modified hybrid platinum-free counter electrodes increased the efficiencies of the DSSCs. The DSSCs based on hybrid nanostructure materials showed a short circuit current density of 9.49, 7.95, 2.59 and 2.57 mAcm−2 for MoS2/P3HT, MoS2/PEDOT, W18O49/PEDOT and W18O49/P3HT samples, respectively. The plasma nanocoating with the nanostructured materials approach for obtaining hybrid counter electrodes in the photovoltaic action shows an alternative route towards cost-effective, green energy conversion.http://dx.doi.org/10.1080/14786451.2017.1333995molybdenum sulphidetungsten oxidehybridrf-plasma modificationdye-sensitised solar cells
spellingShingle Sule Erten-Ela
Melek Kiristi
Ana Varlec
Ferhat Bozduman
Maja Remskar
Lutfi Oksuz
Aysegul Uygun Oksuz
Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells
International Journal of Sustainable Energy
molybdenum sulphide
tungsten oxide
hybrid
rf-plasma modification
dye-sensitised solar cells
title Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells
title_full Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells
title_fullStr Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells
title_full_unstemmed Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells
title_short Platinum-free counter electrodes of plasma-modified hybrid nanomaterials for dye-sensitised solar cells
title_sort platinum free counter electrodes of plasma modified hybrid nanomaterials for dye sensitised solar cells
topic molybdenum sulphide
tungsten oxide
hybrid
rf-plasma modification
dye-sensitised solar cells
url http://dx.doi.org/10.1080/14786451.2017.1333995
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