Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process

The Ebolowa Municipal Lake (EML) (South Cameroon) in order to identify the early diagenesis processes taking place in the lake and the factors influencing them. To this end, 21 samples were collected. In situ, hydrogen potential, redox potential, conductivity, dissolved oxygen content, and turbidity...

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Main Authors: Akono Daniel Florent, Bokanda Ekoko Eric, Bisse Salomon Bertrant, Belinga Belinga Cedric, Menanga Tokouet Renaud, Tonye Marie-Diane, Nzesseu Nandjou Valentino, Biani Nya Estelle Diane, Kouakam Cedric, Ngono Anaba Leon Vital, Mouhamed Amin Nsangou, Ekomane Emile
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Heliyon
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Online Access:http://www.sciencedirect.com/science/article/pii/S2405844023048259
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author Akono Daniel Florent
Bokanda Ekoko Eric
Bisse Salomon Bertrant
Belinga Belinga Cedric
Menanga Tokouet Renaud
Tonye Marie-Diane
Nzesseu Nandjou Valentino
Biani Nya Estelle Diane
Kouakam Cedric
Ngono Anaba Leon Vital
Mouhamed Amin Nsangou
Ekomane Emile
author_facet Akono Daniel Florent
Bokanda Ekoko Eric
Bisse Salomon Bertrant
Belinga Belinga Cedric
Menanga Tokouet Renaud
Tonye Marie-Diane
Nzesseu Nandjou Valentino
Biani Nya Estelle Diane
Kouakam Cedric
Ngono Anaba Leon Vital
Mouhamed Amin Nsangou
Ekomane Emile
author_sort Akono Daniel Florent
collection DOAJ
description The Ebolowa Municipal Lake (EML) (South Cameroon) in order to identify the early diagenesis processes taking place in the lake and the factors influencing them. To this end, 21 samples were collected. In situ, hydrogen potential, redox potential, conductivity, dissolved oxygen content, and turbidity were measured. In the laboratory, the samples were subjected to mineralogical analysis by X-ray diffraction, geochemical analysis by X-ray fluorescence and ICP-MS, and statistical analysis. The coefficient of variation (Qi) was calculated from the geochemical data. In the water column, OD > 2 mg/L, pH > 7 and Eh < 0 mV. In sediments: pH < 7, Eh values are lower. The contents of 2.08 ≤ TOC ≤ 12.65%. The mineralogical procession consists of quartz, kaolinite, gibbsite, goethite, and siderite. The latter is only present in the EML. The sediments are dominated by SiO2 (60.44–89.47%), Al2O3 (6.55–18.17%), and Fe2O3 (1.15–6.21%). The Qi values range from 0.73 to 2.31. The Mn/Fe ratio values are below 0.40. Qi > 1 for Al, Fe, Mn, Mg, K, Na, P, Ni, Co, Zn, Pb, Cd, Cu, Ba, and V, and Qi < 1 for Si; Qi = 1 for Ca. The hierarchical cluster analysis shows two groups: the first one includes the samples from the central and western parts, while the second one includes those from the eastern and southern parts of the lake. The water column is subject to oxic conditions, while the sediments are anoxic. The rapid consumption of oxygen is due to organic mineralization, which is the main diagenesis observed in the lake. This phenomenon is more accentuated in the western part of the lake.
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spelling doaj.art-00138e5bba6143ca9236b1e3a7a031eb2023-07-27T05:56:50ZengElsevierHeliyon2405-84402023-07-0197e17617Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis processAkono Daniel Florent0Bokanda Ekoko Eric1Bisse Salomon Bertrant2Belinga Belinga Cedric3Menanga Tokouet Renaud4Tonye Marie-Diane5Nzesseu Nandjou Valentino6Biani Nya Estelle Diane7Kouakam Cedric8Ngono Anaba Leon Vital9Mouhamed Amin Nsangou10Ekomane Emile11Department of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, Cameroon; Corresponding author.Department of Geology, University of Buea, PO Box 63, Buea, CameroonSchool of Geology and Mining Engineering, PO Box 115, Meiganga, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonDepartment of Earth Sciences, University of Yaounde I, PO Box 812, Yaounde, CameroonThe Ebolowa Municipal Lake (EML) (South Cameroon) in order to identify the early diagenesis processes taking place in the lake and the factors influencing them. To this end, 21 samples were collected. In situ, hydrogen potential, redox potential, conductivity, dissolved oxygen content, and turbidity were measured. In the laboratory, the samples were subjected to mineralogical analysis by X-ray diffraction, geochemical analysis by X-ray fluorescence and ICP-MS, and statistical analysis. The coefficient of variation (Qi) was calculated from the geochemical data. In the water column, OD > 2 mg/L, pH > 7 and Eh < 0 mV. In sediments: pH < 7, Eh values are lower. The contents of 2.08 ≤ TOC ≤ 12.65%. The mineralogical procession consists of quartz, kaolinite, gibbsite, goethite, and siderite. The latter is only present in the EML. The sediments are dominated by SiO2 (60.44–89.47%), Al2O3 (6.55–18.17%), and Fe2O3 (1.15–6.21%). The Qi values range from 0.73 to 2.31. The Mn/Fe ratio values are below 0.40. Qi > 1 for Al, Fe, Mn, Mg, K, Na, P, Ni, Co, Zn, Pb, Cd, Cu, Ba, and V, and Qi < 1 for Si; Qi = 1 for Ca. The hierarchical cluster analysis shows two groups: the first one includes the samples from the central and western parts, while the second one includes those from the eastern and southern parts of the lake. The water column is subject to oxic conditions, while the sediments are anoxic. The rapid consumption of oxygen is due to organic mineralization, which is the main diagenesis observed in the lake. This phenomenon is more accentuated in the western part of the lake.http://www.sciencedirect.com/science/article/pii/S2405844023048259Geochemical balanceEarly-diagenesisLakeEbolowa
spellingShingle Akono Daniel Florent
Bokanda Ekoko Eric
Bisse Salomon Bertrant
Belinga Belinga Cedric
Menanga Tokouet Renaud
Tonye Marie-Diane
Nzesseu Nandjou Valentino
Biani Nya Estelle Diane
Kouakam Cedric
Ngono Anaba Leon Vital
Mouhamed Amin Nsangou
Ekomane Emile
Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process
Heliyon
Geochemical balance
Early-diagenesis
Lake
Ebolowa
title Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process
title_full Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process
title_fullStr Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process
title_full_unstemmed Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process
title_short Geochemical balance of the mineral fraction and statistical analyzes of the Ebolowa municipal lake’s sediments (central Africa): Implication for early diagenesis process
title_sort geochemical balance of the mineral fraction and statistical analyzes of the ebolowa municipal lake s sediments central africa implication for early diagenesis process
topic Geochemical balance
Early-diagenesis
Lake
Ebolowa
url http://www.sciencedirect.com/science/article/pii/S2405844023048259
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