Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses
Three novel polyacetylenes : Polyacetylene PAs, 1-ether- benzoic acid-2- ene - propylene (A) . Polydiacetylene (PDAs), hexa -1,6 diphthalmide - 2- ene – 4 –yne ( B ) ,and Polyacetylene PAs , 1- phenyl - 3- butyne -1 -ol ( C) . were prepared through polymerization of three Acetylinic monomers. They w...
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| Format: | Article |
| Language: | English |
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University of Anbar
2012-06-01
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| Series: | مجلة جامعة الانبار للعلوم الصرفة |
| Subjects: | |
| Online Access: | https://juaps.uoanbar.edu.iq/article_44111_ea1557f6eaa5b7a59ca54a775d6cba38.pdf |
| _version_ | 1797373312668532736 |
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| author | Tariq Abdul-Jalil Mandeel |
| author_facet | Tariq Abdul-Jalil Mandeel |
| author_sort | Tariq Abdul-Jalil Mandeel |
| collection | DOAJ |
| description | Three novel polyacetylenes : Polyacetylene PAs, 1-ether- benzoic acid-2- ene - propylene (A) . Polydiacetylene (PDAs), hexa -1,6 diphthalmide - 2- ene – 4 –yne ( B ) ,and Polyacetylene PAs , 1- phenyl - 3- butyne -1 -ol ( C) . were prepared through polymerization of three Acetylinic monomers. They were prepared byby reaction of propargyl bromide, unsaturated alkyl halide RX and With, other various reagents)) Polymerization was carried out by using selective catalyst such as CuCl, PdCl2 complexed of transition metals with dry and pure oxygen . polymers were extracted , purified and identified by FTIR, HNMR Spectroscopy and melting points . Electrical conductivity of polymers was studied after doping with iodine (I2) to increase their conductivities . Composite plastic was prepared from polymethyl metha acrylate PMMA as the matrix with Polyacetylene as the filler by cast molding the solution of plastic and polyacetylene was prepared by mixing with THF as solvent. The conductivities of the composite seem to be close to semiconductors and the results are in agreement with the literature |
| first_indexed | 2024-03-08T18:48:37Z |
| format | Article |
| id | doaj.art-0014d2bf6c9b415d90eed136f8133922 |
| institution | Directory Open Access Journal |
| issn | 1991-8941 2706-6703 |
| language | English |
| last_indexed | 2024-03-08T18:48:37Z |
| publishDate | 2012-06-01 |
| publisher | University of Anbar |
| record_format | Article |
| series | مجلة جامعة الانبار للعلوم الصرفة |
| spelling | doaj.art-0014d2bf6c9b415d90eed136f81339222023-12-28T21:55:38ZengUniversity of Anbarمجلة جامعة الانبار للعلوم الصرفة1991-89412706-67032012-06-0152304010.37652/juaps.2011.4411144111Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical UsesTariq Abdul-Jalil Mandeel0AL-Anbar University- College of scienceThree novel polyacetylenes : Polyacetylene PAs, 1-ether- benzoic acid-2- ene - propylene (A) . Polydiacetylene (PDAs), hexa -1,6 diphthalmide - 2- ene – 4 –yne ( B ) ,and Polyacetylene PAs , 1- phenyl - 3- butyne -1 -ol ( C) . were prepared through polymerization of three Acetylinic monomers. They were prepared byby reaction of propargyl bromide, unsaturated alkyl halide RX and With, other various reagents)) Polymerization was carried out by using selective catalyst such as CuCl, PdCl2 complexed of transition metals with dry and pure oxygen . polymers were extracted , purified and identified by FTIR, HNMR Spectroscopy and melting points . Electrical conductivity of polymers was studied after doping with iodine (I2) to increase their conductivities . Composite plastic was prepared from polymethyl metha acrylate PMMA as the matrix with Polyacetylene as the filler by cast molding the solution of plastic and polyacetylene was prepared by mixing with THF as solvent. The conductivities of the composite seem to be close to semiconductors and the results are in agreement with the literaturehttps://juaps.uoanbar.edu.iq/article_44111_ea1557f6eaa5b7a59ca54a775d6cba38.pdfpolyacetyleneconductive polymerscompositedoping |
| spellingShingle | Tariq Abdul-Jalil Mandeel Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses مجلة جامعة الانبار للعلوم الصرفة polyacetylene conductive polymers composite doping |
| title | Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses |
| title_full | Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses |
| title_fullStr | Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses |
| title_full_unstemmed | Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses |
| title_short | Preparation of Polyacetylene Composite with some Plastic and Semiconductor for Electrical Uses |
| title_sort | preparation of polyacetylene composite with some plastic and semiconductor for electrical uses |
| topic | polyacetylene conductive polymers composite doping |
| url | https://juaps.uoanbar.edu.iq/article_44111_ea1557f6eaa5b7a59ca54a775d6cba38.pdf |
| work_keys_str_mv | AT tariqabduljalilmandeel preparationofpolyacetylenecompositewithsomeplasticandsemiconductorforelectricaluses |