Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review

5-Hydroxymethylfurfural (5-HMF) as a triply catalytic product is a value-added refining chemical in industry production. 5-HMF as biomass feedstock enables to be transformed into other high-value industrial compounds, such as 2,5-furandicarboxylic acid (FDCA), 5-hydroxymethyl-2-furancarboxylic acid...

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Main Authors: Yuanyong Yao, Shixue Chen, Meng Zhang
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-05-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2022.880603/full
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author Yuanyong Yao
Shixue Chen
Meng Zhang
author_facet Yuanyong Yao
Shixue Chen
Meng Zhang
author_sort Yuanyong Yao
collection DOAJ
description 5-Hydroxymethylfurfural (5-HMF) as a triply catalytic product is a value-added refining chemical in industry production. 5-HMF as biomass feedstock enables to be transformed into other high-value industrial compounds, such as 2,5-furandicarboxylic acid (FDCA), 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA), 2,5-diformylfuran (DFF), 2,5-bis(aminomethyl)furan (BAMF), and 2,5-dimethylfuran (DMF). Hence, catalytic conversion of biomass into 5-HMF has been given much more attention by chemists. In this review, some latest studies about the conversion of cellulose to 5-HMF have been introduced systematically. Solid acids such as heterogeneous catalysts have been widely applied in the conversion of cellulose into 5-HMF. Therefore, some novel solid acids with Brønsted and/or Lewis acidic sites, such as sulfonated solid acids, carbon-based acids, and zeolite particles employed for biomass conversions are listed.
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spelling doaj.art-00489586efe046c1987ceb5363741a102022-12-22T00:40:49ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462022-05-011010.3389/fchem.2022.880603880603Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A ReviewYuanyong YaoShixue ChenMeng Zhang5-Hydroxymethylfurfural (5-HMF) as a triply catalytic product is a value-added refining chemical in industry production. 5-HMF as biomass feedstock enables to be transformed into other high-value industrial compounds, such as 2,5-furandicarboxylic acid (FDCA), 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA), 2,5-diformylfuran (DFF), 2,5-bis(aminomethyl)furan (BAMF), and 2,5-dimethylfuran (DMF). Hence, catalytic conversion of biomass into 5-HMF has been given much more attention by chemists. In this review, some latest studies about the conversion of cellulose to 5-HMF have been introduced systematically. Solid acids such as heterogeneous catalysts have been widely applied in the conversion of cellulose into 5-HMF. Therefore, some novel solid acids with Brønsted and/or Lewis acidic sites, such as sulfonated solid acids, carbon-based acids, and zeolite particles employed for biomass conversions are listed.https://www.frontiersin.org/articles/10.3389/fchem.2022.880603/full5-Hydroxymethylfurfuralcellulosebiomass resourcessolid acidsselective conversionheterogeneous acid catalysis
spellingShingle Yuanyong Yao
Shixue Chen
Meng Zhang
Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
Frontiers in Chemistry
5-Hydroxymethylfurfural
cellulose
biomass resources
solid acids
selective conversion
heterogeneous acid catalysis
title Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
title_full Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
title_fullStr Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
title_full_unstemmed Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
title_short Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
title_sort sustainable approaches to selective conversion of cellulose into 5 hydroxymethylfurfural promoted by heterogeneous acid catalysts a review
topic 5-Hydroxymethylfurfural
cellulose
biomass resources
solid acids
selective conversion
heterogeneous acid catalysis
url https://www.frontiersin.org/articles/10.3389/fchem.2022.880603/full
work_keys_str_mv AT yuanyongyao sustainableapproachestoselectiveconversionofcelluloseinto5hydroxymethylfurfuralpromotedbyheterogeneousacidcatalystsareview
AT shixuechen sustainableapproachestoselectiveconversionofcelluloseinto5hydroxymethylfurfuralpromotedbyheterogeneousacidcatalystsareview
AT mengzhang sustainableapproachestoselectiveconversionofcelluloseinto5hydroxymethylfurfuralpromotedbyheterogeneousacidcatalystsareview