Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review
5-Hydroxymethylfurfural (5-HMF) as a triply catalytic product is a value-added refining chemical in industry production. 5-HMF as biomass feedstock enables to be transformed into other high-value industrial compounds, such as 2,5-furandicarboxylic acid (FDCA), 5-hydroxymethyl-2-furancarboxylic acid...
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Frontiers Media S.A.
2022-05-01
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Series: | Frontiers in Chemistry |
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Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2022.880603/full |
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author | Yuanyong Yao Shixue Chen Meng Zhang |
author_facet | Yuanyong Yao Shixue Chen Meng Zhang |
author_sort | Yuanyong Yao |
collection | DOAJ |
description | 5-Hydroxymethylfurfural (5-HMF) as a triply catalytic product is a value-added refining chemical in industry production. 5-HMF as biomass feedstock enables to be transformed into other high-value industrial compounds, such as 2,5-furandicarboxylic acid (FDCA), 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA), 2,5-diformylfuran (DFF), 2,5-bis(aminomethyl)furan (BAMF), and 2,5-dimethylfuran (DMF). Hence, catalytic conversion of biomass into 5-HMF has been given much more attention by chemists. In this review, some latest studies about the conversion of cellulose to 5-HMF have been introduced systematically. Solid acids such as heterogeneous catalysts have been widely applied in the conversion of cellulose into 5-HMF. Therefore, some novel solid acids with Brønsted and/or Lewis acidic sites, such as sulfonated solid acids, carbon-based acids, and zeolite particles employed for biomass conversions are listed. |
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issn | 2296-2646 |
language | English |
last_indexed | 2024-12-12T02:54:05Z |
publishDate | 2022-05-01 |
publisher | Frontiers Media S.A. |
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spelling | doaj.art-00489586efe046c1987ceb5363741a102022-12-22T00:40:49ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462022-05-011010.3389/fchem.2022.880603880603Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A ReviewYuanyong YaoShixue ChenMeng Zhang5-Hydroxymethylfurfural (5-HMF) as a triply catalytic product is a value-added refining chemical in industry production. 5-HMF as biomass feedstock enables to be transformed into other high-value industrial compounds, such as 2,5-furandicarboxylic acid (FDCA), 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA), 2,5-diformylfuran (DFF), 2,5-bis(aminomethyl)furan (BAMF), and 2,5-dimethylfuran (DMF). Hence, catalytic conversion of biomass into 5-HMF has been given much more attention by chemists. In this review, some latest studies about the conversion of cellulose to 5-HMF have been introduced systematically. Solid acids such as heterogeneous catalysts have been widely applied in the conversion of cellulose into 5-HMF. Therefore, some novel solid acids with Brønsted and/or Lewis acidic sites, such as sulfonated solid acids, carbon-based acids, and zeolite particles employed for biomass conversions are listed.https://www.frontiersin.org/articles/10.3389/fchem.2022.880603/full5-Hydroxymethylfurfuralcellulosebiomass resourcessolid acidsselective conversionheterogeneous acid catalysis |
spellingShingle | Yuanyong Yao Shixue Chen Meng Zhang Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review Frontiers in Chemistry 5-Hydroxymethylfurfural cellulose biomass resources solid acids selective conversion heterogeneous acid catalysis |
title | Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review |
title_full | Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review |
title_fullStr | Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review |
title_full_unstemmed | Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review |
title_short | Sustainable Approaches to Selective Conversion of Cellulose Into 5-Hydroxymethylfurfural Promoted by Heterogeneous Acid Catalysts: A Review |
title_sort | sustainable approaches to selective conversion of cellulose into 5 hydroxymethylfurfural promoted by heterogeneous acid catalysts a review |
topic | 5-Hydroxymethylfurfural cellulose biomass resources solid acids selective conversion heterogeneous acid catalysis |
url | https://www.frontiersin.org/articles/10.3389/fchem.2022.880603/full |
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