Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet

This study was initiated to evaluate the performance of asphalt binders and mixtures incorporating linear low-density polyethylene- calcium carbonate (LLDPE-CaCO3) pellet, either with or without titanate coupling agent. The detailed manufacturing process of modifier pellets was displayed. The coupli...

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Main Authors: Mohd Rosli Mohd Hasan, Zhanping You, Mohd Khairul Idham Mohd Satar, Muhammad Naqiuddin Mohd Warid, Nurul Hidayah Mohd Kamaruddin, Dongdong Ge, Ran Zhang
Format: Article
Language:English
Published: MDPI AG 2018-06-01
Series:Applied Sciences
Subjects:
Online Access:http://www.mdpi.com/2076-3417/8/7/1029
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author Mohd Rosli Mohd Hasan
Zhanping You
Mohd Khairul Idham Mohd Satar
Muhammad Naqiuddin Mohd Warid
Nurul Hidayah Mohd Kamaruddin
Dongdong Ge
Ran Zhang
author_facet Mohd Rosli Mohd Hasan
Zhanping You
Mohd Khairul Idham Mohd Satar
Muhammad Naqiuddin Mohd Warid
Nurul Hidayah Mohd Kamaruddin
Dongdong Ge
Ran Zhang
author_sort Mohd Rosli Mohd Hasan
collection DOAJ
description This study was initiated to evaluate the performance of asphalt binders and mixtures incorporating linear low-density polyethylene- calcium carbonate (LLDPE-CaCO3) pellet, either with or without titanate coupling agent. The detailed manufacturing process of modifier pellets was displayed. The coupling agent was used to enhance the cross-linking between materials by means of winding up covalent bonds or molecule chains, thus improving the performance of composites. In the preparation of modified bitumen, the preheated asphalt binder was mixed with the modifiers using a high shear mixer at 5000 rpm rotational speed for 45 min. Experimental works were conducted to evaluate the performance of asphalt binders in terms of volatile loss, viscosity, rutting potential, and low temperature cracking. Meanwhile, the asphalt mixtures were tested using the flow number test and tensile strength ratio (TSR) test. The addition of LLDPE-CaCO3 modifiers and coupling agent does not significantly affect the volatile loss of modified asphalt binders. The addition of modifiers and coupling agent has significantly improved the resistance to permanent deformation of asphalt binders. Even though, the addition of LLDPE-CaCO3 modifier and coupling agent remarkably increased the mixture stiffness that contributed to lower rutting potential, the resistance to low temperature cracking of asphalt binder was not adversely affected. The combination of 1% coupling agent with 3% PECC is optimum dosage for asphalt binder to have satisfactory performance in resistance to moisture damage and rutting.
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spelling doaj.art-004c014a2b664d1081e11fcbcf9835dc2022-12-21T20:37:19ZengMDPI AGApplied Sciences2076-34172018-06-0187102910.3390/app8071029app8071029Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 PelletMohd Rosli Mohd Hasan0Zhanping You1Mohd Khairul Idham Mohd Satar2Muhammad Naqiuddin Mohd Warid3Nurul Hidayah Mohd Kamaruddin4Dongdong Ge5Ran Zhang6School of Civil Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Pulau Pinang, MalaysiaDepartment of Civil and Environmental Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, MI 49931, USADepartment of Geotechnics and Transportation, Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, MalaysiaDepartment of Geotechnics and Transportation, Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, MalaysiaFaculty of Civil and Environmental Engineering, Universiti Tun Hussein Onn Malaysia, 86400 Parit Raja, Johor, MalaysiaDepartment of Civil and Environmental Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, MI 49931, USASchool of Highway, Chang’an University, South Erhuan Middle Section, Xi’an 710064, Shaanxi, ChinaThis study was initiated to evaluate the performance of asphalt binders and mixtures incorporating linear low-density polyethylene- calcium carbonate (LLDPE-CaCO3) pellet, either with or without titanate coupling agent. The detailed manufacturing process of modifier pellets was displayed. The coupling agent was used to enhance the cross-linking between materials by means of winding up covalent bonds or molecule chains, thus improving the performance of composites. In the preparation of modified bitumen, the preheated asphalt binder was mixed with the modifiers using a high shear mixer at 5000 rpm rotational speed for 45 min. Experimental works were conducted to evaluate the performance of asphalt binders in terms of volatile loss, viscosity, rutting potential, and low temperature cracking. Meanwhile, the asphalt mixtures were tested using the flow number test and tensile strength ratio (TSR) test. The addition of LLDPE-CaCO3 modifiers and coupling agent does not significantly affect the volatile loss of modified asphalt binders. The addition of modifiers and coupling agent has significantly improved the resistance to permanent deformation of asphalt binders. Even though, the addition of LLDPE-CaCO3 modifier and coupling agent remarkably increased the mixture stiffness that contributed to lower rutting potential, the resistance to low temperature cracking of asphalt binder was not adversely affected. The combination of 1% coupling agent with 3% PECC is optimum dosage for asphalt binder to have satisfactory performance in resistance to moisture damage and rutting.http://www.mdpi.com/2076-3417/8/7/1029asphalt modificationcoupling agentrheological behaviorplasticcalcium carbonate powder
spellingShingle Mohd Rosli Mohd Hasan
Zhanping You
Mohd Khairul Idham Mohd Satar
Muhammad Naqiuddin Mohd Warid
Nurul Hidayah Mohd Kamaruddin
Dongdong Ge
Ran Zhang
Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet
Applied Sciences
asphalt modification
coupling agent
rheological behavior
plastic
calcium carbonate powder
title Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet
title_full Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet
title_fullStr Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet
title_full_unstemmed Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet
title_short Effects of Titanate Coupling Agent on Engineering Properties of Asphalt Binders and Mixtures Incorporating LLDPE-CaCO3 Pellet
title_sort effects of titanate coupling agent on engineering properties of asphalt binders and mixtures incorporating lldpe caco3 pellet
topic asphalt modification
coupling agent
rheological behavior
plastic
calcium carbonate powder
url http://www.mdpi.com/2076-3417/8/7/1029
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