Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites

In the aerospace sector, structural and non-structural composite components are usually subjected to a wide range of environmental conditions. Among all, moisture can seriously damage these materials’ performance, reducing their mechanical, thermal, electrical, and physical properties as well as the...

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Main Authors: Fabrizia Cilento, Barbara Palmieri, Giovangiuseppe Giusto, Ruggiero Volponi, Giovanni Bruno, Carmine Carandente Tartaglia, Cinzia Toscano, Michele Giordano, Alfonso Martone
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/13/23/12812
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author Fabrizia Cilento
Barbara Palmieri
Giovangiuseppe Giusto
Ruggiero Volponi
Giovanni Bruno
Carmine Carandente Tartaglia
Cinzia Toscano
Michele Giordano
Alfonso Martone
author_facet Fabrizia Cilento
Barbara Palmieri
Giovangiuseppe Giusto
Ruggiero Volponi
Giovanni Bruno
Carmine Carandente Tartaglia
Cinzia Toscano
Michele Giordano
Alfonso Martone
author_sort Fabrizia Cilento
collection DOAJ
description In the aerospace sector, structural and non-structural composite components are usually subjected to a wide range of environmental conditions. Among all, moisture can seriously damage these materials’ performance, reducing their mechanical, thermal, electrical, and physical properties as well as their service time. Lightweight protective barrier coatings capable of reducing the diffusion of gases and/or liquids in a material can improve the material’s resistance in humid environments. In this work, nanolamellar nanocomposites characterized by a high in-plane orientation of nanoplatelets have been employed as protective coatings for Kevlar sandwich panels, reproducing the construction of a nacelle engine. The effectiveness of the protection against water uptake of nanocomposites reinforced with graphite nanoplatelets (GNPs) at high filler contents (70, 80 and 90 wt%) has been investigated using moisture uptake and Ground-Air-Ground (GAG) tests in an environmental chamber. GNP coatings effectively work as barrier by generating highly tortuous paths for molecule diffusion. Results showed a dependence of the absorption on the coating composition and inner structure. Films @70 wt% GNPs showed the best protection against moisture uptake by delaying the phenomenon and reducing the absorption by −80% after 3 days and −35% after 41 days.
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spelling doaj.art-0053e87db9d04809956e3fac16f54ee92023-12-08T15:11:47ZengMDPI AGApplied Sciences2076-34172023-11-0113231281210.3390/app132312812Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich CompositesFabrizia Cilento0Barbara Palmieri1Giovangiuseppe Giusto2Ruggiero Volponi3Giovanni Bruno4Carmine Carandente Tartaglia5Cinzia Toscano6Michele Giordano7Alfonso Martone8Institute of Polymers, Composite and Biomaterials (IPCB), National Research Council of Italy, 80055 Portici, ItalyInstitute of Polymers, Composite and Biomaterials (IPCB), National Research Council of Italy, 80055 Portici, ItalyCIRA, Italian Aerospace Research Centre, 81043 Capua, ItalyCIRA, Italian Aerospace Research Centre, 81043 Capua, ItalyCIRA, Italian Aerospace Research Centre, 81043 Capua, ItalyCIRA, Italian Aerospace Research Centre, 81043 Capua, ItalyCIRA, Italian Aerospace Research Centre, 81043 Capua, ItalyInstitute of Polymers, Composite and Biomaterials (IPCB), National Research Council of Italy, 80055 Portici, ItalyInstitute of Polymers, Composite and Biomaterials (IPCB), National Research Council of Italy, 80055 Portici, ItalyIn the aerospace sector, structural and non-structural composite components are usually subjected to a wide range of environmental conditions. Among all, moisture can seriously damage these materials’ performance, reducing their mechanical, thermal, electrical, and physical properties as well as their service time. Lightweight protective barrier coatings capable of reducing the diffusion of gases and/or liquids in a material can improve the material’s resistance in humid environments. In this work, nanolamellar nanocomposites characterized by a high in-plane orientation of nanoplatelets have been employed as protective coatings for Kevlar sandwich panels, reproducing the construction of a nacelle engine. The effectiveness of the protection against water uptake of nanocomposites reinforced with graphite nanoplatelets (GNPs) at high filler contents (70, 80 and 90 wt%) has been investigated using moisture uptake and Ground-Air-Ground (GAG) tests in an environmental chamber. GNP coatings effectively work as barrier by generating highly tortuous paths for molecule diffusion. Results showed a dependence of the absorption on the coating composition and inner structure. Films @70 wt% GNPs showed the best protection against moisture uptake by delaying the phenomenon and reducing the absorption by −80% after 3 days and −35% after 41 days.https://www.mdpi.com/2076-3417/13/23/12812graphite nanoplateletsmoisture uptakebarrier properties
spellingShingle Fabrizia Cilento
Barbara Palmieri
Giovangiuseppe Giusto
Ruggiero Volponi
Giovanni Bruno
Carmine Carandente Tartaglia
Cinzia Toscano
Michele Giordano
Alfonso Martone
Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites
Applied Sciences
graphite nanoplatelets
moisture uptake
barrier properties
title Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites
title_full Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites
title_fullStr Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites
title_full_unstemmed Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites
title_short Graphite Nanoplatelets Nanostructured Films as Multifunctional Protective Layer in Kevlar/Nomex Sandwich Composites
title_sort graphite nanoplatelets nanostructured films as multifunctional protective layer in kevlar nomex sandwich composites
topic graphite nanoplatelets
moisture uptake
barrier properties
url https://www.mdpi.com/2076-3417/13/23/12812
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