Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
The dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.62...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810046040 |
| Summary: | The dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.624 (3) Å]. An intermolecular N—H...O hydrogen bond links the dimers together. The two-coordinate CuI atom displays an O—Cu—N bond angle of 176.3 (2)°. The Cu...Cu distance within the dimer is 5.100 (2) Å. |
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| ISSN: | 1600-5368 |