Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
The dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.62...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810046040 |
| _version_ | 1818887069695475712 |
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| author | Zheng-Yu Su Ke-Wei Lei Jie Li Dong-Guo Xia |
| author_facet | Zheng-Yu Su Ke-Wei Lei Jie Li Dong-Guo Xia |
| author_sort | Zheng-Yu Su |
| collection | DOAJ |
| description | The dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.624 (3) Å]. An intermolecular N—H...O hydrogen bond links the dimers together. The two-coordinate CuI atom displays an O—Cu—N bond angle of 176.3 (2)°. The Cu...Cu distance within the dimer is 5.100 (2) Å. |
| first_indexed | 2024-12-19T16:31:22Z |
| format | Article |
| id | doaj.art-00721eb298024274a4d8a512b8fa9a08 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:31:22Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-00721eb298024274a4d8a512b8fa9a082022-12-21T20:14:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1582m158210.1107/S1600536810046040Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)Zheng-Yu SuKe-Wei LeiJie LiDong-Guo XiaThe dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.624 (3) Å]. An intermolecular N—H...O hydrogen bond links the dimers together. The two-coordinate CuI atom displays an O—Cu—N bond angle of 176.3 (2)°. The Cu...Cu distance within the dimer is 5.100 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810046040 |
| spellingShingle | Zheng-Yu Su Ke-Wei Lei Jie Li Dong-Guo Xia Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I) Acta Crystallographica Section E |
| title | Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I) |
| title_full | Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I) |
| title_fullStr | Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I) |
| title_full_unstemmed | Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I) |
| title_short | Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I) |
| title_sort | bis amp 956 3 1h benzimidazol 2 yl benzoato dicopper i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810046040 |
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