Catalytic evaluation of citrate-stabilized palladium nanoparticles in the Sonogashira reaction for the synthesis of 1,4-Bis[(trimethylsilyl)ethynyl]benzene

Catalytic evaluation of citrate-stabilized palladium nanoparticles in the Sonogashira reaction for the synthesis of 1,4-Bis[(trimethylsilyl)ethynyl]benzene

Citrate-stabilized palladium nanoparticles were synthesized and supported on silica spheres. Conditions affecting particle size, stability and adsorption on silica particles are explored. The catalytic activity of nanoparticles in suspension as well as on silica support was evaluated in the Sonogash...

Full description

Bibliographic Details
Main Authors:	Erick Gálvez-Martínez, Andrés Aguilar-Granda, Braulio Rodríguez-Molina, Catalina Haro-Pérez, Anna Kozina
Format:	Article
Language:	English
Published:	Elsevier 2021-05-01
Series:	Catalysis Communications
Subjects:	Palladium nanoparticles Silica Sonogashira reaction Catalysis
Online Access:	http://www.sciencedirect.com/science/article/pii/S1566736720303459

Similar Items

Solid-Supported Heterogenized Palladium Nanoparticles: Propitious Vehicles for Sonogashira Cross-Coupling Reaction
by: Abhay Srivastava, et al.
Published: (2023-01-01)

Sonogashira Reaction of Aryl and Heteroaryl Halides with Terminal Alkynes Catalyzed by a Highly Efficient and Recyclable Nanosized MCM-41 Anchored Palladium Bipyridyl Complex
by: Chung-Yuan Mou, et al.
Published: (2010-12-01)

Catalytic Studies Featuring Palladium(II) Benzoylthiourea Derivative as Catalyst in Sonogashira Reaction
by: Wan M. Khairul, et al.
Published: (2014-12-01)

Palladium and Copper Catalyzed Sonogashira cross Coupling an Excellent Methodology for C-C Bond Formation over 17 Years: A Review
by: Iram Kanwal, et al.
Published: (2020-04-01)

Polymer-supported Pd(0) catalyst for copper- and ligand-free Sonogashira reactions in aqueous media
by: Yi Wen-Bin, et al.
Published: (2012-04-01)

Biogenic palladium nanostructures for Suzuki-Miyaura and Sonogashira cross-coupling reaction under mild reaction conditions
by: Sameeran Kumar Das, et al.
Published: (2022-01-01)

Synthesis of Alkynyl Ketones by Sonogashira Cross-Coupling of Acyl Chlorides with Terminal Alkynes Mediated by Palladium Catalysts Deposited over Donor-Functionalized Silica Gel
by: Miloslav Semler, et al.
Published: (2020-10-01)

DNA‐Encoded Libraries: Aryl Fluorosulfonates as Versatile Electrophiles Enabling Facile On‐DNA Suzuki, Sonogashira, and Buchwald Reactions
by: Hongtao Xu, et al.
Published: (2019-12-01)

Au(I)/Au(III)-catalyzed Sonogashira-type reactions of functionalized terminal alkynes with arylboronic acids under mild conditions
by: Deyun Qian, et al.
Published: (2011-06-01)

Palladium Nanoparticles Incorporated Fumed Silica as an Efficient Catalyst for Nitroarenes Reduction via Thermal and Microwave Heating
by: Afaf Y. Khormi, et al.
Published: (2023-02-01)

Magnetically Recoverable Nanoparticulate Catalysts for Cross-Coupling Reactions: The Dendritic Support Influences the Catalytic Performance
by: Nina V. Kuchkina, et al.
Published: (2021-12-01)

Facile synthesis of palladium nanoparticles on hierarchical hollow silica spheres and its catalytic properties in Suzuki-reaction
by: Mao Liu, et al.
Published: (2018-01-01)

Novel Highly Efficient Green and Reusable Cu(II)/Chitosan-Based Catalysts for the Sonogashira, Buchwald, Aldol, and Dipolar Cycloaddition Reactions
by: Artem P. Dysin, et al.
Published: (2023-01-01)

TiO<sub>2</sub>-Modified Montmorillonite-Supported Porous Carbon-Immobilized Pd Species Nanocomposite as an Efficient Catalyst for Sonogashira Reactions
by: Yuli Chen, et al.
Published: (2023-03-01)

An unprecedented palladium-arsenic catalytic cycle for nitriles hydration
by: Damiano Cirri, et al.
Published: (2023-08-01)

Palladium Nanoparticles Supported on Smopex-234<sup>®</sup> as Valuable Catalysts for the Synthesis of Heterocycles
by: Gianluigi Albano, et al.
Published: (2021-06-01)

Heterogeneous catalytic hydrogenation of canola oil using palladium /
by: Diosady, L. L., et al.

Synthesis and catalytic activity of polyvinylpyridine supported palladium nanoparticles in sonogashira coupling reaction /
by: Nurul Sahida Hassan, 1988-, et al.
Published: (2012)

A New Heterogeneous Catalyst Obtained via Supramolecular Decoration of Graphene with a Pd<sup>2+</sup> Azamacrocyclic Complex
by: Matteo Savastano, et al.
Published: (2019-07-01)

Catalytic properties of monometallic and bimetallic palladium and rhodium nanoparticles obtained in reverse micellar systems
by: Sergeev Mihail O., et al.
Published: (2014-10-01)

Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
by: Jiao, Zhiwei, et al.
Published: (2017)

EFFECTS OF SOLVENT, BASE, AND TEMPERATURE IN THE OPTIMISATION OF A NEW CATALYTIC SYSTEM FOR SONOGASHIRA CROSS-COUPLING USING NCP PINCER PALLADACYCLE
by: Diego S. Rosa, et al.
Published: (2015-05-01)

Palladium-Catalyzed Mizoroki–Heck and Copper-Free Sonogashira Coupling Reactions in Water Using Thermoresponsive Polymer Micelles
by: Noriyuki Suzuki, et al.
Published: (2021-08-01)

Synthesis and catalytic activity of polyvinylpyridine supported palladium nanoparticles in sonogashira coupling reaction [electronic resource] /
by: Nurul Sahida Hassan, 1988-
Published: (2012)

Palladium Supported on Bioinspired Materials as Catalysts for C–C Coupling Reactions
by: Gianluigi Albano, et al.
Published: (2023-01-01)

Sonogashira–Hagihara reactions of halogenated glycals
by: Dennis C. Koester, et al.
Published: (2012-05-01)

Palladium-Catalyzed Arylation of Ketones and Acetonitrile with Ortho Alkylation of Aryl Rings: De Novo Synthesis of Tetralines and Benzocycloheptenes
by: Lei, Chuanhu, et al.
Published: (2017)

Catalysis of a Bis-Caffeine Palladium(II) NHC-Pincer Complex
by: Oliver Bysewski, et al.
Published: (2023-04-01)

Cellulose Nanofiber Biotemplated Palladium Composite Aerogels
by: Fred J. Burpo, et al.
Published: (2018-06-01)

Nanostructuring of Palladium with Low-Temperature Helium Plasma
by: P. Fiflis, et al.
Published: (2015-11-01)

Crystal structures of three 4-substituted-2,2′-bipyridines synthesized by Sonogashira and Suzuki–Miyaura cross-coupling reactions
by: Thuy Luong Thi Thu, et al.
Published: (2017-04-01)

Palladium(0) Deposited on PAMAM Dendrimers as a Catalyst for C–C Cross Coupling Reactions
by: Tomasz Borkowski, et al.
Published: (2011-01-01)

Recent developments and trends in the iron- and cobalt-catalyzed Sonogashira reactions
by: Surendran Amrutha, et al.
Published: (2022-03-01)

Palladium(0) Nanoparticles Immobilized onto Silica/Starch Composite: Sustainable Catalyst for Hydrogenations and Suzuki Coupling
by: Ravinderpal Kour Sodhi, et al.
Published: (2019-12-01)

Palladium-Catalyzed Cross-Coupling Reaction of Bis(cyclopentadienyl)diaryltitaniums with Terminal Alkynes
by: Yuki Murata, et al.
Published: (2023-10-01)

Thermal, dielectric and catalytic behavior of palladium doped PVC films
by: Ganesh Shimoga, et al.

Advances in Palladium-Catalyzed Carboxylation Reactions
by: Lucia Veltri, et al.
Published: (2022-01-01)

A Mild Aqueous Sonogashira Reaction as a Fluorescent Labeling Strategy for 5-Bromide-2′-Deoxyuridine
by: Shufang Wang, et al.
Published: (2018-01-01)

Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation
by: Kirsty L. Wilson, et al.
Published: (2016-09-01)

A General Synthesis of Cross-Conjugated Enynones through Pd Catalyzed Sonogashira Coupling with Triazine Esters
by: Dezhi Lin, et al.
Published: (2023-05-01)