Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing

The aim of this study was to investigate the corrosion resistance of ultrafine-grained (UFG) Ti-6Al-7Nb fabricated by equal channel angular pressing (ECAP) and coarse-grained (CG) Ti- 6Al- 7Nb. The microstructure of each specimen was investigated by the electron backscattered diffraction (EBSD) meth...

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Main Authors: Zequn Yu, Yuecheng Dong, Xin Li, Jingzhe Niu, Igor Alexandrov, Hui Chang
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/7/950
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author Zequn Yu
Yuecheng Dong
Xin Li
Jingzhe Niu
Igor Alexandrov
Hui Chang
author_facet Zequn Yu
Yuecheng Dong
Xin Li
Jingzhe Niu
Igor Alexandrov
Hui Chang
author_sort Zequn Yu
collection DOAJ
description The aim of this study was to investigate the corrosion resistance of ultrafine-grained (UFG) Ti-6Al-7Nb fabricated by equal channel angular pressing (ECAP) and coarse-grained (CG) Ti- 6Al- 7Nb. The microstructure of each specimen was investigated by the electron backscattered diffraction (EBSD) method. The corrosion behavior of each specimen was determined by electrochemical measurement in Ringer’s solution. The surface corroded morphologies and oxide film formed on Ti-6Al-7Nb alloy after electrochemical measurement were investigated by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). EBSD investigation shows that the grain size of UFG Ti-6Al-7Nb decreased to ~0.4 µm, accompanied by low angle grain boundaries (LAGBs) accounting for 39%. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) results indicated that UFG Ti-6Al-7Nb alloy possessed a better corrosion resistance. The surface corroded morphologies revealed many small and shallow corrosion pits, which can be attributed to the good compactness of the oxide film and a rapid self- repairing ability of the UFG Ti-6Al-7Nb alloy.
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spelling doaj.art-00860edd48f94a7898a7ed2caa940aeb2023-11-20T06:46:49ZengMDPI AGMetals2075-47012020-07-0110795010.3390/met10070950Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular PressingZequn Yu0Yuecheng Dong1Xin Li2Jingzhe Niu3Igor Alexandrov4Hui Chang5College of Materials Science and Engineering/Tech Institute for Advanced Materials, Nanjing Tech University, Nanjing 211816, ChinaCollege of Materials Science and Engineering/Tech Institute for Advanced Materials, Nanjing Tech University, Nanjing 211816, ChinaCollege of Materials Science and Engineering/Tech Institute for Advanced Materials, Nanjing Tech University, Nanjing 211816, ChinaState Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, ChinaThe Department of Physics, Ufa State Aviation Technical University, 450008 Ufa, RussiaCollege of Materials Science and Engineering/Tech Institute for Advanced Materials, Nanjing Tech University, Nanjing 211816, ChinaThe aim of this study was to investigate the corrosion resistance of ultrafine-grained (UFG) Ti-6Al-7Nb fabricated by equal channel angular pressing (ECAP) and coarse-grained (CG) Ti- 6Al- 7Nb. The microstructure of each specimen was investigated by the electron backscattered diffraction (EBSD) method. The corrosion behavior of each specimen was determined by electrochemical measurement in Ringer’s solution. The surface corroded morphologies and oxide film formed on Ti-6Al-7Nb alloy after electrochemical measurement were investigated by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). EBSD investigation shows that the grain size of UFG Ti-6Al-7Nb decreased to ~0.4 µm, accompanied by low angle grain boundaries (LAGBs) accounting for 39%. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) results indicated that UFG Ti-6Al-7Nb alloy possessed a better corrosion resistance. The surface corroded morphologies revealed many small and shallow corrosion pits, which can be attributed to the good compactness of the oxide film and a rapid self- repairing ability of the UFG Ti-6Al-7Nb alloy.https://www.mdpi.com/2075-4701/10/7/950corrosion resistanceTi-6Al-7Nb alloyultrafine-grainedequal channel angular pressingoxide film
spellingShingle Zequn Yu
Yuecheng Dong
Xin Li
Jingzhe Niu
Igor Alexandrov
Hui Chang
Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing
Metals
corrosion resistance
Ti-6Al-7Nb alloy
ultrafine-grained
equal channel angular pressing
oxide film
title Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing
title_full Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing
title_fullStr Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing
title_full_unstemmed Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing
title_short Study on Corrosion Behavior of Ultrafine-Grained Ti-6Al-7Nb Fabricated by Equal Channel Angular Pressing
title_sort study on corrosion behavior of ultrafine grained ti 6al 7nb fabricated by equal channel angular pressing
topic corrosion resistance
Ti-6Al-7Nb alloy
ultrafine-grained
equal channel angular pressing
oxide film
url https://www.mdpi.com/2075-4701/10/7/950
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