Improving the Electrochemical Performance of LiNi0.80Co0.15Al0.05O2 in Lithium Ion Batteries by LiAlO2 Surface Modification

LiNi0.80Co0.15Al0.05O2 (NCA) as a lithium ion battery cathode material has received attention for its highly specific capacity and excellent low temperature performance. However, the disadvantages of its high surface lithium compound residues and high pH value have influenced its processing performa...

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Bibliographic Details
Main Authors: Chunhua Song, Wenge Wang, Huili Peng, Ying Wang, Chenglong Zhao, Huibin Zhang, Qiwei Tang, Jinzhao Lv, Xianjun Du, Yanmeng Dou
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Applied Sciences
Subjects:
Online Access:http://www.mdpi.com/2076-3417/8/3/378
Description
Summary:LiNi0.80Co0.15Al0.05O2 (NCA) as a lithium ion battery cathode material has received attention for its highly specific capacity and excellent low temperature performance. However, the disadvantages of its high surface lithium compound residues and high pH value have influenced its processing performance and limited its application. This paper uses a facile method to modify NCA through LiAlO2 coating. The results showed that when the molar ratio of Al(NO3)3·9H2O and lithium compound residues at the surface of NCA cathode material was 0.25:1, the pH of the cathode material decreased from 12.70 to 11.80 and the surface lithium compound residues decreased from 3.99% to 1.48%. The NCA cell was charged and discharged for 100 cycles at 1 C in the voltage range of 3.0–4.3 V, to test the capacity retention of NCA. It was found to be as high as 94.67%, which was 5.36% higher than the control NCA cell. The discharge capacity of NCA-0.25-500 °C was 139.8 mAh/g even at 8 C rate, which was 15% higher than the raw NCA. Further research indicated that Al(NO3)3·9H2O reacted with the surface lithium compound residues of NCA and generated LiAlO2, which improved the NCA electrochemical performance.
ISSN:2076-3417