Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review

Nanocomposite materials have seen increased adoption in a wide range of applications, with toxic gas detection, such as carbon monoxide (CO), being of particular interest for this review. Such sensors are usually characterized by the presence of CO absorption sites in their structures, with the Lang...

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Main Authors: Mihaela Savin, Carmen-Marinela Mihailescu, Carmen Moldovan, Alexandru Grigoroiu, Ion Ion, Alina Catrinel Ion
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/3/821
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author Mihaela Savin
Carmen-Marinela Mihailescu
Carmen Moldovan
Alexandru Grigoroiu
Ion Ion
Alina Catrinel Ion
author_facet Mihaela Savin
Carmen-Marinela Mihailescu
Carmen Moldovan
Alexandru Grigoroiu
Ion Ion
Alina Catrinel Ion
author_sort Mihaela Savin
collection DOAJ
description Nanocomposite materials have seen increased adoption in a wide range of applications, with toxic gas detection, such as carbon monoxide (CO), being of particular interest for this review. Such sensors are usually characterized by the presence of CO absorption sites in their structures, with the Langmuir reaction model offering a good description of the reaction mechanism involved in capturing the gas. Among the reviewed sensors, those that combined polymers with carbonaceous materials showed improvements in their analytical parameters such as increased sensitivities, wider dynamic ranges, and faster response times. Moreover, it was observed that the CO reaction mechanism can differ when measured in mixtures with other gases as opposed to when it is detected in isolation, which leads to lower sensitivities to the target gas. To better understand such changes, we offer a complete description of carbon nanostructure-based chemosensors for the detection of CO from the sensing mechanism of each material to the water solution strategies for the composite nanomaterials and the choice of morphology for enhancing a layers’ conductivity. Then, a series of state-of-the-art resistive chemosensors that make use of nanocomposite materials is analyzed, with performance being assessed based on their detection range and sensitivity.
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spelling doaj.art-00a1814acd3140a197416b55927215762023-11-23T17:12:59ZengMDPI AGMolecules1420-30492022-01-0127382110.3390/molecules27030821Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A ReviewMihaela Savin0Carmen-Marinela Mihailescu1Carmen Moldovan2Alexandru Grigoroiu3Ion Ion4Alina Catrinel Ion5Department of Microsystems in Biomedical and Enviromental Applications, National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest, RomaniaDepartment of Microsystems in Biomedical and Enviromental Applications, National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest, RomaniaDepartment of Microsystems in Biomedical and Enviromental Applications, National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest, RomaniaDepartment of Microsystems in Biomedical and Enviromental Applications, National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest, RomaniaDepartment of Microsystems in Biomedical and Enviromental Applications, National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest, RomaniaDepartment of Applied Chemistry and Materials Science, University Politehnica of Bucharest, 1-7 Polizu, 011061 Bucharest, RomaniaNanocomposite materials have seen increased adoption in a wide range of applications, with toxic gas detection, such as carbon monoxide (CO), being of particular interest for this review. Such sensors are usually characterized by the presence of CO absorption sites in their structures, with the Langmuir reaction model offering a good description of the reaction mechanism involved in capturing the gas. Among the reviewed sensors, those that combined polymers with carbonaceous materials showed improvements in their analytical parameters such as increased sensitivities, wider dynamic ranges, and faster response times. Moreover, it was observed that the CO reaction mechanism can differ when measured in mixtures with other gases as opposed to when it is detected in isolation, which leads to lower sensitivities to the target gas. To better understand such changes, we offer a complete description of carbon nanostructure-based chemosensors for the detection of CO from the sensing mechanism of each material to the water solution strategies for the composite nanomaterials and the choice of morphology for enhancing a layers’ conductivity. Then, a series of state-of-the-art resistive chemosensors that make use of nanocomposite materials is analyzed, with performance being assessed based on their detection range and sensitivity.https://www.mdpi.com/1420-3049/27/3/821chemosensorcarbon monoxidenanocomposite carbon materialsensing mechanismelectrodepositionconducting polymers
spellingShingle Mihaela Savin
Carmen-Marinela Mihailescu
Carmen Moldovan
Alexandru Grigoroiu
Ion Ion
Alina Catrinel Ion
Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review
Molecules
chemosensor
carbon monoxide
nanocomposite carbon material
sensing mechanism
electrodeposition
conducting polymers
title Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review
title_full Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review
title_fullStr Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review
title_full_unstemmed Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review
title_short Resistive Chemosensors for the Detection of CO Based on Conducting Polymers and Carbon Nanocomposites: A Review
title_sort resistive chemosensors for the detection of co based on conducting polymers and carbon nanocomposites a review
topic chemosensor
carbon monoxide
nanocomposite carbon material
sensing mechanism
electrodeposition
conducting polymers
url https://www.mdpi.com/1420-3049/27/3/821
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AT carmenmoldovan resistivechemosensorsforthedetectionofcobasedonconductingpolymersandcarbonnanocompositesareview
AT alexandrugrigoroiu resistivechemosensorsforthedetectionofcobasedonconductingpolymersandcarbonnanocompositesareview
AT ionion resistivechemosensorsforthedetectionofcobasedonconductingpolymersandcarbonnanocompositesareview
AT alinacatrinelion resistivechemosensorsforthedetectionofcobasedonconductingpolymersandcarbonnanocompositesareview