Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology

Abstract Scale precipitation is one of the major problems in the petroleum industry during waterflooding. The possibility of salt formation and precipitation should be monitored and analyzed under dynamic conditions to improve production performance. Scale precipitation and its dependence on product...

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Main Authors: Azizollah Khormali, Soroush Ahmadi
Format: Article
Language:English
Published: SpringerOpen 2023-07-01
Series:Journal of Petroleum Exploration and Production Technology
Subjects:
Online Access:https://doi.org/10.1007/s13202-023-01679-2
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author Azizollah Khormali
Soroush Ahmadi
author_facet Azizollah Khormali
Soroush Ahmadi
author_sort Azizollah Khormali
collection DOAJ
description Abstract Scale precipitation is one of the major problems in the petroleum industry during waterflooding. The possibility of salt formation and precipitation should be monitored and analyzed under dynamic conditions to improve production performance. Scale precipitation and its dependence on production parameters should be investigated before using scale inhibitors. In this study, the precipitation of barium sulfate salt was investigated through dynamic tube blocking tests at different injection rates and times. For this purpose, the pressure drop caused by salt deposition was evaluated at injection rates of 1, 2, 3, 4, and 5 mL/min. The software determined the worst conditions (temperature, pressure, and water mixing ratio) for barium sulfate precipitation. Moreover, during the experiments, the pressure drop caused by barium sulfate precipitation was measured without using scale inhibitors. The pressure drop data were evaluated by the response surface method and analysis of variance to develop a new model for predicting the pressure drop depending on the injection rate and time. The novelty of this study lies in the development of a new high-precision correlation to predict barium sulfate precipitation under dynamic conditions using the response surface methodology that evaluates the effect of injection rate and time on the possibility of salt precipitation. The accuracy and adequacy of the obtained model were confirmed by using R2 statistics (including R2-coefficient of determination, adjusted R2, and predicted R2), adequate precision, and diagnostic charts. The results showed that the proposed model could fully and accurately predict the pressure drop. Increasing the time and decreasing the injection rate caused an increase in pressure drop and precipitation of barium sulfate salt, which was related to the formation of more salt due to the contact of ions. In addition, in a short period of the injection process, the pressure drop due to salt deposition increased sharply, which confirms the need to use a suitable scale inhibitor to control salt deposition. Finally, the dynamic tube blocking tests were repeated in the presence of two well-known scale inhibitors, which prevented salt deposition in the tubes. At the same time, no pressure drop was observed in the presence of scale inhibitors at all injection rates during a long period of injection. The obtained results can be used for the evaluation of salt precipitation during oil production in the reservoirs, in which barium sulfate is precipitated during waterflooding. For this purpose, knowing the flow rate and injection time, it is possible to determine the amount of pressure drop caused by salt deposition.
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spelling doaj.art-00b4b623b5e7499a972bc69840a7a2892023-09-17T11:07:31ZengSpringerOpenJournal of Petroleum Exploration and Production Technology2190-05582190-05662023-07-0113112267228110.1007/s13202-023-01679-2Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodologyAzizollah Khormali0Soroush Ahmadi1Department of Chemistry, Faculty of Basic Sciences and Engineering, Gonbad Kavous UniversityDepartment of Chemical Engineering, Faculty of Engineering, Payame Noor University (PNU)Abstract Scale precipitation is one of the major problems in the petroleum industry during waterflooding. The possibility of salt formation and precipitation should be monitored and analyzed under dynamic conditions to improve production performance. Scale precipitation and its dependence on production parameters should be investigated before using scale inhibitors. In this study, the precipitation of barium sulfate salt was investigated through dynamic tube blocking tests at different injection rates and times. For this purpose, the pressure drop caused by salt deposition was evaluated at injection rates of 1, 2, 3, 4, and 5 mL/min. The software determined the worst conditions (temperature, pressure, and water mixing ratio) for barium sulfate precipitation. Moreover, during the experiments, the pressure drop caused by barium sulfate precipitation was measured without using scale inhibitors. The pressure drop data were evaluated by the response surface method and analysis of variance to develop a new model for predicting the pressure drop depending on the injection rate and time. The novelty of this study lies in the development of a new high-precision correlation to predict barium sulfate precipitation under dynamic conditions using the response surface methodology that evaluates the effect of injection rate and time on the possibility of salt precipitation. The accuracy and adequacy of the obtained model were confirmed by using R2 statistics (including R2-coefficient of determination, adjusted R2, and predicted R2), adequate precision, and diagnostic charts. The results showed that the proposed model could fully and accurately predict the pressure drop. Increasing the time and decreasing the injection rate caused an increase in pressure drop and precipitation of barium sulfate salt, which was related to the formation of more salt due to the contact of ions. In addition, in a short period of the injection process, the pressure drop due to salt deposition increased sharply, which confirms the need to use a suitable scale inhibitor to control salt deposition. Finally, the dynamic tube blocking tests were repeated in the presence of two well-known scale inhibitors, which prevented salt deposition in the tubes. At the same time, no pressure drop was observed in the presence of scale inhibitors at all injection rates during a long period of injection. The obtained results can be used for the evaluation of salt precipitation during oil production in the reservoirs, in which barium sulfate is precipitated during waterflooding. For this purpose, knowing the flow rate and injection time, it is possible to determine the amount of pressure drop caused by salt deposition.https://doi.org/10.1007/s13202-023-01679-2ScalingPressure dropBarium sulfateRSMDynamic tube blocking testWaterflooding
spellingShingle Azizollah Khormali
Soroush Ahmadi
Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
Journal of Petroleum Exploration and Production Technology
Scaling
Pressure drop
Barium sulfate
RSM
Dynamic tube blocking test
Waterflooding
title Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
title_full Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
title_fullStr Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
title_full_unstemmed Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
title_short Prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
title_sort prediction of barium sulfate precipitation in dynamic tube blocking tests and its inhibition for waterflooding application using response surface methodology
topic Scaling
Pressure drop
Barium sulfate
RSM
Dynamic tube blocking test
Waterflooding
url https://doi.org/10.1007/s13202-023-01679-2
work_keys_str_mv AT azizollahkhormali predictionofbariumsulfateprecipitationindynamictubeblockingtestsanditsinhibitionforwaterfloodingapplicationusingresponsesurfacemethodology
AT soroushahmadi predictionofbariumsulfateprecipitationindynamictubeblockingtestsanditsinhibitionforwaterfloodingapplicationusingresponsesurfacemethodology