Silver nanoparticles passivated with aniline and their subsequent polymerization using hematin as a catalyst

In this work, silver nanoparticles (AgNPs) were synthesized via two different routes. The first route was based on the Creighton method (chemical reduction), used aniline as a passivating agent and NaBH4 as a reducing agent, and led to a green nanoparticle solution with an average particle size of 2...

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Bibliographic Details
Main Authors: Tiffany Ledesma-González, Román Torres-Lubian, Carmen Alvarado-Canché, Eduardo Cardozo-Villalba, Agustín L. Herrera-May, Enrique Díaz Barriga-Castro, Carlos Gallardo-Vega, Antonio Ledezma-Pérez, Arxel de León
Format: Article
Language:English
Published: Elsevier 2023-08-01
Series:Hybrid Advances
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Online Access:http://www.sciencedirect.com/science/article/pii/S2773207X2300026X
Description
Summary:In this work, silver nanoparticles (AgNPs) were synthesized via two different routes. The first route was based on the Creighton method (chemical reduction), used aniline as a passivating agent and NaBH4 as a reducing agent, and led to a green nanoparticle solution with an average particle size of 23 ​± ​11 ​nm and a plasmonic resonance with a maximum at 376 ​nm. The second route was the hydrothermal method, in which aniline was used to reduce the metal salt and stabilize the nanoparticles; this provided a pink solution of nanoparticles with an average particle size of 11 ​± ​5 ​nm, and a plasmon resonance with a maximum at 550 ​nm. Aniline was polymerized by using hematin as the catalyst, and FT-IR, RAMAN, and NMR spectroscopy were used to characterize the structure. In addition, the PANI/AgNP composite was synthesized, and it exhibited a higher conductivity of 0.28 ​S/cm relative to that of PANI (0.05 ​S/cm).
ISSN:2773-207X