Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid

Abstract Polymer electrolyte membrane water electrolysis (PEMWE) is an attractive hydrogen energy production technology that offers various advantages such as compact design, high operating pressure, high current densities, and high hydrogen gas purity. However, PEMWE still faces several critical ch...

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Main Authors: Hyunseok Yoon, Bobae Ju, Dong‐Wan Kim
Format: Article
Language:English
Published: Wiley 2023-09-01
Series:Battery Energy
Subjects:
Online Access:https://doi.org/10.1002/bte2.20230017
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author Hyunseok Yoon
Bobae Ju
Dong‐Wan Kim
author_facet Hyunseok Yoon
Bobae Ju
Dong‐Wan Kim
author_sort Hyunseok Yoon
collection DOAJ
description Abstract Polymer electrolyte membrane water electrolysis (PEMWE) is an attractive hydrogen energy production technology that offers various advantages such as compact design, high operating pressure, high current densities, and high hydrogen gas purity. However, PEMWE still faces several critical challenges, particularly with respect to the oxygen evolution reaction (OER) at the anode. Highly active, corrosion‐resistant electrocatalytic materials are required for the acidic OER owing to its sluggish kinetics involving four‐electron transfer under harsh anodic potentials. To date, IrO2‐ or RuO2‐based noble metal electrocatalysts have been employed as commercial acidic OER electrocatalysts for PEMWE. However, they remain inadequate in terms of satisfying the industrial activity/stability‐related requirements. Above all, the two noble metals are too rare and expensive, which significantly inhibits widespread commercialization of PEMWE. Therefore, low‐cost, highly active, and highly stable OER electrocatalysts that can operate in acidic media must be urgently developed. This review paper presents various state‐of‐the‐art strategies employed to address the aforementioned issues by classifying them according to objectives such as improving activity, enhancing stability, and reducing cost. Then, finally, we summarize major tasks and strategies to overcome them and put forward a few issues in this field.
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spelling doaj.art-00fbe8919b3d4684a87c0cfcdc7337fa2023-09-27T09:47:12ZengWileyBattery Energy2768-16962023-09-0125n/an/a10.1002/bte2.20230017Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acidHyunseok Yoon0Bobae Ju1Dong‐Wan Kim2School of Civil, Environmental and Architectural Engineering Korea University Seoul South KoreaSchool of Civil, Environmental and Architectural Engineering Korea University Seoul South KoreaSchool of Civil, Environmental and Architectural Engineering Korea University Seoul South KoreaAbstract Polymer electrolyte membrane water electrolysis (PEMWE) is an attractive hydrogen energy production technology that offers various advantages such as compact design, high operating pressure, high current densities, and high hydrogen gas purity. However, PEMWE still faces several critical challenges, particularly with respect to the oxygen evolution reaction (OER) at the anode. Highly active, corrosion‐resistant electrocatalytic materials are required for the acidic OER owing to its sluggish kinetics involving four‐electron transfer under harsh anodic potentials. To date, IrO2‐ or RuO2‐based noble metal electrocatalysts have been employed as commercial acidic OER electrocatalysts for PEMWE. However, they remain inadequate in terms of satisfying the industrial activity/stability‐related requirements. Above all, the two noble metals are too rare and expensive, which significantly inhibits widespread commercialization of PEMWE. Therefore, low‐cost, highly active, and highly stable OER electrocatalysts that can operate in acidic media must be urgently developed. This review paper presents various state‐of‐the‐art strategies employed to address the aforementioned issues by classifying them according to objectives such as improving activity, enhancing stability, and reducing cost. Then, finally, we summarize major tasks and strategies to overcome them and put forward a few issues in this field.https://doi.org/10.1002/bte2.20230017acidic water electrolysisanodeelectrocatalysthydrogen productionoxygen evolution reaction
spellingShingle Hyunseok Yoon
Bobae Ju
Dong‐Wan Kim
Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
Battery Energy
acidic water electrolysis
anode
electrocatalyst
hydrogen production
oxygen evolution reaction
title Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
title_full Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
title_fullStr Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
title_full_unstemmed Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
title_short Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
title_sort perspectives on the development of highly active stable and cost effective oer electrocatalysts in acid
topic acidic water electrolysis
anode
electrocatalyst
hydrogen production
oxygen evolution reaction
url https://doi.org/10.1002/bte2.20230017
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AT bobaeju perspectivesonthedevelopmentofhighlyactivestableandcosteffectiveoerelectrocatalystsinacid
AT dongwankim perspectivesonthedevelopmentofhighlyactivestableandcosteffectiveoerelectrocatalystsinacid