Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid
Abstract Polymer electrolyte membrane water electrolysis (PEMWE) is an attractive hydrogen energy production technology that offers various advantages such as compact design, high operating pressure, high current densities, and high hydrogen gas purity. However, PEMWE still faces several critical ch...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Wiley
2023-09-01
|
Series: | Battery Energy |
Subjects: | |
Online Access: | https://doi.org/10.1002/bte2.20230017 |
_version_ | 1797672397282738176 |
---|---|
author | Hyunseok Yoon Bobae Ju Dong‐Wan Kim |
author_facet | Hyunseok Yoon Bobae Ju Dong‐Wan Kim |
author_sort | Hyunseok Yoon |
collection | DOAJ |
description | Abstract Polymer electrolyte membrane water electrolysis (PEMWE) is an attractive hydrogen energy production technology that offers various advantages such as compact design, high operating pressure, high current densities, and high hydrogen gas purity. However, PEMWE still faces several critical challenges, particularly with respect to the oxygen evolution reaction (OER) at the anode. Highly active, corrosion‐resistant electrocatalytic materials are required for the acidic OER owing to its sluggish kinetics involving four‐electron transfer under harsh anodic potentials. To date, IrO2‐ or RuO2‐based noble metal electrocatalysts have been employed as commercial acidic OER electrocatalysts for PEMWE. However, they remain inadequate in terms of satisfying the industrial activity/stability‐related requirements. Above all, the two noble metals are too rare and expensive, which significantly inhibits widespread commercialization of PEMWE. Therefore, low‐cost, highly active, and highly stable OER electrocatalysts that can operate in acidic media must be urgently developed. This review paper presents various state‐of‐the‐art strategies employed to address the aforementioned issues by classifying them according to objectives such as improving activity, enhancing stability, and reducing cost. Then, finally, we summarize major tasks and strategies to overcome them and put forward a few issues in this field. |
first_indexed | 2024-03-11T21:29:27Z |
format | Article |
id | doaj.art-00fbe8919b3d4684a87c0cfcdc7337fa |
institution | Directory Open Access Journal |
issn | 2768-1696 |
language | English |
last_indexed | 2024-03-11T21:29:27Z |
publishDate | 2023-09-01 |
publisher | Wiley |
record_format | Article |
series | Battery Energy |
spelling | doaj.art-00fbe8919b3d4684a87c0cfcdc7337fa2023-09-27T09:47:12ZengWileyBattery Energy2768-16962023-09-0125n/an/a10.1002/bte2.20230017Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acidHyunseok Yoon0Bobae Ju1Dong‐Wan Kim2School of Civil, Environmental and Architectural Engineering Korea University Seoul South KoreaSchool of Civil, Environmental and Architectural Engineering Korea University Seoul South KoreaSchool of Civil, Environmental and Architectural Engineering Korea University Seoul South KoreaAbstract Polymer electrolyte membrane water electrolysis (PEMWE) is an attractive hydrogen energy production technology that offers various advantages such as compact design, high operating pressure, high current densities, and high hydrogen gas purity. However, PEMWE still faces several critical challenges, particularly with respect to the oxygen evolution reaction (OER) at the anode. Highly active, corrosion‐resistant electrocatalytic materials are required for the acidic OER owing to its sluggish kinetics involving four‐electron transfer under harsh anodic potentials. To date, IrO2‐ or RuO2‐based noble metal electrocatalysts have been employed as commercial acidic OER electrocatalysts for PEMWE. However, they remain inadequate in terms of satisfying the industrial activity/stability‐related requirements. Above all, the two noble metals are too rare and expensive, which significantly inhibits widespread commercialization of PEMWE. Therefore, low‐cost, highly active, and highly stable OER electrocatalysts that can operate in acidic media must be urgently developed. This review paper presents various state‐of‐the‐art strategies employed to address the aforementioned issues by classifying them according to objectives such as improving activity, enhancing stability, and reducing cost. Then, finally, we summarize major tasks and strategies to overcome them and put forward a few issues in this field.https://doi.org/10.1002/bte2.20230017acidic water electrolysisanodeelectrocatalysthydrogen productionoxygen evolution reaction |
spellingShingle | Hyunseok Yoon Bobae Ju Dong‐Wan Kim Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid Battery Energy acidic water electrolysis anode electrocatalyst hydrogen production oxygen evolution reaction |
title | Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid |
title_full | Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid |
title_fullStr | Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid |
title_full_unstemmed | Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid |
title_short | Perspectives on the development of highly active, stable, and cost‐effective OER electrocatalysts in acid |
title_sort | perspectives on the development of highly active stable and cost effective oer electrocatalysts in acid |
topic | acidic water electrolysis anode electrocatalyst hydrogen production oxygen evolution reaction |
url | https://doi.org/10.1002/bte2.20230017 |
work_keys_str_mv | AT hyunseokyoon perspectivesonthedevelopmentofhighlyactivestableandcosteffectiveoerelectrocatalystsinacid AT bobaeju perspectivesonthedevelopmentofhighlyactivestableandcosteffectiveoerelectrocatalystsinacid AT dongwankim perspectivesonthedevelopmentofhighlyactivestableandcosteffectiveoerelectrocatalystsinacid |