A Surface-Enhanced Raman Spectroscopic Sensor Pen

Surface-enhanced Raman spectroscopy (SERS) is widely used as a detection method in scientific research fields. However, the method for creating SERS substrates often requires expensive equipment and involves a complex process. Additionally, preserving and effectively utilizing SERS substrates in the...

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Main Authors: Zejiang Song, Zhijie Li, Weishen Zhan, Wanli Zhao, Hsiang-Chen Chui, Rui Li
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Inventions
Subjects:
Online Access:https://www.mdpi.com/2411-5134/8/6/156
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author Zejiang Song
Zhijie Li
Weishen Zhan
Wanli Zhao
Hsiang-Chen Chui
Rui Li
author_facet Zejiang Song
Zhijie Li
Weishen Zhan
Wanli Zhao
Hsiang-Chen Chui
Rui Li
author_sort Zejiang Song
collection DOAJ
description Surface-enhanced Raman spectroscopy (SERS) is widely used as a detection method in scientific research fields. However, the method for creating SERS substrates often requires expensive equipment and involves a complex process. Additionally, preserving and effectively utilizing SERS substrates in the long term poses a challenging problem. In order to address these issues, we propose a new method for creating SERS substrates on various types of paper using a combination of a ballpoint pen and 3D printing. This method ensures a high enhancement factor and maximizes the utilization of the substrate. We achieved an enhancement factor of up to 8.2 × 10<sup>8</sup> for detecting R6G molecules, with a relative standard deviation of 11.13% for the Raman peak at 612 cm<sup>−1</sup> of R6G, demonstrating excellent SERS sensitivity and spectral reproducibility. Furthermore, we successfully detected thiram at a concentration as low as 10<sup>−8</sup>, which is lower than both the Chinese national standard and European standard.
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spelling doaj.art-010a43fa926d42d595b0d818e8d15e2a2023-12-22T14:16:33ZengMDPI AGInventions2411-51342023-12-018615610.3390/inventions8060156A Surface-Enhanced Raman Spectroscopic Sensor PenZejiang Song0Zhijie Li1Weishen Zhan2Wanli Zhao3Hsiang-Chen Chui4Rui Li5School of Optoelectronic Engineering and Instrumentation Science, Dalian University of Technology, Dalian 116024, ChinaSchool of Physics, Dalian University of Technology, Dalian 116000, ChinaSchool of Physics, Dalian University of Technology, Dalian 116000, ChinaScience and Technology on Electro-Optical Information Security Control Laboratory, Tianjin 300308, ChinaSchool of Optoelectronic Engineering and Instrumentation Science, Dalian University of Technology, Dalian 116024, ChinaSchool of Physics, Dalian University of Technology, Dalian 116000, ChinaSurface-enhanced Raman spectroscopy (SERS) is widely used as a detection method in scientific research fields. However, the method for creating SERS substrates often requires expensive equipment and involves a complex process. Additionally, preserving and effectively utilizing SERS substrates in the long term poses a challenging problem. In order to address these issues, we propose a new method for creating SERS substrates on various types of paper using a combination of a ballpoint pen and 3D printing. This method ensures a high enhancement factor and maximizes the utilization of the substrate. We achieved an enhancement factor of up to 8.2 × 10<sup>8</sup> for detecting R6G molecules, with a relative standard deviation of 11.13% for the Raman peak at 612 cm<sup>−1</sup> of R6G, demonstrating excellent SERS sensitivity and spectral reproducibility. Furthermore, we successfully detected thiram at a concentration as low as 10<sup>−8</sup>, which is lower than both the Chinese national standard and European standard.https://www.mdpi.com/2411-5134/8/6/156surface-enhancement Raman scatteringchemical sensorsnanoparticlesthree-dimensional printing
spellingShingle Zejiang Song
Zhijie Li
Weishen Zhan
Wanli Zhao
Hsiang-Chen Chui
Rui Li
A Surface-Enhanced Raman Spectroscopic Sensor Pen
Inventions
surface-enhancement Raman scattering
chemical sensors
nanoparticles
three-dimensional printing
title A Surface-Enhanced Raman Spectroscopic Sensor Pen
title_full A Surface-Enhanced Raman Spectroscopic Sensor Pen
title_fullStr A Surface-Enhanced Raman Spectroscopic Sensor Pen
title_full_unstemmed A Surface-Enhanced Raman Spectroscopic Sensor Pen
title_short A Surface-Enhanced Raman Spectroscopic Sensor Pen
title_sort surface enhanced raman spectroscopic sensor pen
topic surface-enhancement Raman scattering
chemical sensors
nanoparticles
three-dimensional printing
url https://www.mdpi.com/2411-5134/8/6/156
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