A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol
A novel gold catalyst supported by In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> with a solid solution structure shows a methanol selectivity of 70.1% and a methanol space–time yield (STY) of 0.59 g<sub>MeOH</sub> h<sup>−1</sup> g<sub>c...
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MDPI AG
2020-11-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/11/1360 |
| _version_ | 1797547107223076864 |
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| author | Zhe Lu Kaihang Sun Jing Wang Zhitao Zhang Changjun Liu |
| author_facet | Zhe Lu Kaihang Sun Jing Wang Zhitao Zhang Changjun Liu |
| author_sort | Zhe Lu |
| collection | DOAJ |
| description | A novel gold catalyst supported by In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> with a solid solution structure shows a methanol selectivity of 70.1% and a methanol space–time yield (STY) of 0.59 g<sub>MeOH</sub> h<sup>−1</sup> g<sub>cat</sub><sup>−1</sup> for CO<sub>2</sub> hydrogenation to methanol at 573 K and 5 MPa. The ZrO<sub>2</sub> stabilizes the structure of In<sub>2</sub>O<sub>3</sub>, increases oxygen vacancies, and enhances CO<sub>2</sub> adsorption, causing the improved activity. |
| first_indexed | 2024-03-10T14:38:31Z |
| format | Article |
| id | doaj.art-0123dfb64fba4c869adcce3082f0687d |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T14:38:31Z |
| publishDate | 2020-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-0123dfb64fba4c869adcce3082f0687d2023-11-20T21:56:07ZengMDPI AGCatalysts2073-43442020-11-011011136010.3390/catal10111360A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to MethanolZhe Lu0Kaihang Sun1Jing Wang2Zhitao Zhang3Changjun Liu4School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, ChinaSchool of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, ChinaSchool of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, ChinaSchool of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, ChinaSchool of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, ChinaA novel gold catalyst supported by In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> with a solid solution structure shows a methanol selectivity of 70.1% and a methanol space–time yield (STY) of 0.59 g<sub>MeOH</sub> h<sup>−1</sup> g<sub>cat</sub><sup>−1</sup> for CO<sub>2</sub> hydrogenation to methanol at 573 K and 5 MPa. The ZrO<sub>2</sub> stabilizes the structure of In<sub>2</sub>O<sub>3</sub>, increases oxygen vacancies, and enhances CO<sub>2</sub> adsorption, causing the improved activity.https://www.mdpi.com/2073-4344/10/11/1360CO<sub>2</sub> hydrogenationindium oxideAu/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub>methanolsolid solution |
| spellingShingle | Zhe Lu Kaihang Sun Jing Wang Zhitao Zhang Changjun Liu A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol Catalysts CO<sub>2</sub> hydrogenation indium oxide Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> methanol solid solution |
| title | A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol |
| title_full | A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol |
| title_fullStr | A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol |
| title_full_unstemmed | A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol |
| title_short | A Highly Active Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> Catalyst for Selective Hydrogenation of CO<sub>2</sub> to Methanol |
| title_sort | highly active au in sub 2 sub o sub 3 sub zro sub 2 sub catalyst for selective hydrogenation of co sub 2 sub to methanol |
| topic | CO<sub>2</sub> hydrogenation indium oxide Au/In<sub>2</sub>O<sub>3</sub>-ZrO<sub>2</sub> methanol solid solution |
| url | https://www.mdpi.com/2073-4344/10/11/1360 |
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