Homocoupling of aryl halides in flow: Space integration of lithiation and FeCl3 promoted homocoupling

Homocoupling of aryl halides in flow: Space integration of lithiation and FeCl3 promoted homocoupling

The use of FeCl3 resulted in a fast homocoupling of aryllithiums, and this enabled its integration with the halogen–lithium exchange reaction of aryl halides in a flow microreactor. This system allows the homocoupling of two aryl halides bearing electrophilic functional groups, such as CN and NO2, i...

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Bibliographic Details
Main Authors: Aiichiro Nagaki, Yuki Uesugi, Yutaka Tomida, Jun-ichi Yoshida
Format: Article
Language:English
Published: Beilstein-Institut 2011-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
homocoupling
iron salts
microreactor
organolithiums
Online Access:https://doi.org/10.3762/bjoc.7.122

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