The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes
The usefulness of percent volume buried (%V<sub>bur</sub>) as a readily quantifiable property is investigated with regard to [Cu(NN)(PP)]<sup>+</sup> complexes of interest for lighting purposes. Photoluminescence quantum yields (PLQYs) and single crystal X-ray structures of 1...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-06-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/25/11/2647 |
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| author | Murat Alkan-Zambada Edwin C. Constable Catherine E. Housecroft |
| author_facet | Murat Alkan-Zambada Edwin C. Constable Catherine E. Housecroft |
| author_sort | Murat Alkan-Zambada |
| collection | DOAJ |
| description | The usefulness of percent volume buried (%V<sub>bur</sub>) as a readily quantifiable property is investigated with regard to [Cu(NN)(PP)]<sup>+</sup> complexes of interest for lighting purposes. Photoluminescence quantum yields (PLQYs) and single crystal X-ray structures of 100 reported compounds were assembled, %V<sub>bur</sub> of the ligand systems were calculated and analyzed for correlations. We found that increased shielding of the central Cu(I) cation relying on shared contributions of both (NN) and (PP) ligand systems led to increased PLQYs. These findings are of relevance for future characterizations of Cu(I)-based complexes and their photophysical behavior in the solid-state. |
| first_indexed | 2024-03-10T19:19:29Z |
| format | Article |
| id | doaj.art-014608fc972944c6ba52fee5caff849c |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T19:19:29Z |
| publishDate | 2020-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-014608fc972944c6ba52fee5caff849c2023-11-20T03:04:49ZengMDPI AGMolecules1420-30492020-06-012511264710.3390/molecules25112647The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting PurposesMurat Alkan-Zambada0Edwin C. Constable1Catherine E. Housecroft2Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI, BCH 3305, 1015 Lausanne, SwitzerlandDepartment of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, SwitzerlandDepartment of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, SwitzerlandThe usefulness of percent volume buried (%V<sub>bur</sub>) as a readily quantifiable property is investigated with regard to [Cu(NN)(PP)]<sup>+</sup> complexes of interest for lighting purposes. Photoluminescence quantum yields (PLQYs) and single crystal X-ray structures of 100 reported compounds were assembled, %V<sub>bur</sub> of the ligand systems were calculated and analyzed for correlations. We found that increased shielding of the central Cu(I) cation relying on shared contributions of both (NN) and (PP) ligand systems led to increased PLQYs. These findings are of relevance for future characterizations of Cu(I)-based complexes and their photophysical behavior in the solid-state.https://www.mdpi.com/1420-3049/25/11/2647copper(I)photoluminescence quantum yieldcrystal structurepercent volume buried (%V<sub>bur</sub>)empirical correlations |
| spellingShingle | Murat Alkan-Zambada Edwin C. Constable Catherine E. Housecroft The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes Molecules copper(I) photoluminescence quantum yield crystal structure percent volume buried (%V<sub>bur</sub>) empirical correlations |
| title | The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes |
| title_full | The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes |
| title_fullStr | The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes |
| title_full_unstemmed | The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes |
| title_short | The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes |
| title_sort | role of percent volume buried in the characterization of copper i complexes for lighting purposes |
| topic | copper(I) photoluminescence quantum yield crystal structure percent volume buried (%V<sub>bur</sub>) empirical correlations |
| url | https://www.mdpi.com/1420-3049/25/11/2647 |
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