A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands
The asymmetric unit of the title complex, [Ag4W2S8(C25H22P2)3]·2C3H7NO, tris[μ2-bis(diphenylphosphino)methane]-3:6κ2P:P′;4:5κ2P:P′;5:6κ2P:P′-μ5-sulfido-2:3:4:5:6κ5S-&a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810034197 |
| _version_ | 1818791653346902016 |
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| author | Cun-Lin Zhang Qiong-Hua Jin Ke-Yi Hu Rong Wang Li-Li Song |
| author_facet | Cun-Lin Zhang Qiong-Hua Jin Ke-Yi Hu Rong Wang Li-Li Song |
| author_sort | Cun-Lin Zhang |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Ag4W2S8(C25H22P2)3]·2C3H7NO, tris[μ2-bis(diphenylphosphino)methane]-3:6κ2P:P′;4:5κ2P:P′;5:6κ2P:P′-μ5-sulfido-2:3:4:5:6κ5S-μ3-sulfido-1:3:4κ3S-tetra-μ2-sulfido-1:3κ2S;1:4κ2S;2:5κ2S;2:6κ2S-disulfido-1κS,2κS-tetrasilver(I)ditungsten(VI) N,N-dimethylformamide disolvate, contains two [WS4]2− anions, four silver cations, three bidentate–bridging bis(diphenylphosphino)methane (dppm) ligands and two N,N-dimethylformamide (DMF) solvent molecules. The coordination geometry of each Ag atom is distorted tetrahedral. Two Ag ions are coordinated by μ2-S and μ5-S atoms, and by two P atoms from two dppm ligands, while the other two Ag atoms are coordinated by μ2-S, μ3-S and μ5-S atoms, and by one P atom from a dppm ligand. |
| first_indexed | 2024-12-18T15:14:46Z |
| format | Article |
| id | doaj.art-014ca31837d9454bad370714a4dd7c1f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:14:46Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-014ca31837d9454bad370714a4dd7c1f2022-12-21T21:03:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1185m118610.1107/S1600536810034197A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligandsCun-Lin ZhangQiong-Hua JinKe-Yi HuRong WangLi-Li SongThe asymmetric unit of the title complex, [Ag4W2S8(C25H22P2)3]·2C3H7NO, tris[μ2-bis(diphenylphosphino)methane]-3:6κ2P:P′;4:5κ2P:P′;5:6κ2P:P′-μ5-sulfido-2:3:4:5:6κ5S-μ3-sulfido-1:3:4κ3S-tetra-μ2-sulfido-1:3κ2S;1:4κ2S;2:5κ2S;2:6κ2S-disulfido-1κS,2κS-tetrasilver(I)ditungsten(VI) N,N-dimethylformamide disolvate, contains two [WS4]2− anions, four silver cations, three bidentate–bridging bis(diphenylphosphino)methane (dppm) ligands and two N,N-dimethylformamide (DMF) solvent molecules. The coordination geometry of each Ag atom is distorted tetrahedral. Two Ag ions are coordinated by μ2-S and μ5-S atoms, and by two P atoms from two dppm ligands, while the other two Ag atoms are coordinated by μ2-S, μ3-S and μ5-S atoms, and by one P atom from a dppm ligand.http://scripts.iucr.org/cgi-bin/paper?S1600536810034197 |
| spellingShingle | Cun-Lin Zhang Qiong-Hua Jin Ke-Yi Hu Rong Wang Li-Li Song A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands Acta Crystallographica Section E |
| title | A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands |
| title_full | A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands |
| title_fullStr | A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands |
| title_full_unstemmed | A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands |
| title_short | A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands |
| title_sort | tetrasilver i ditungsten vi cluster with sulfide and bis diphenylphosphino methane ligands |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810034197 |
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