Study on direct-chain diacid modified phenolic resin for Al-alloy casting

Resin coated sand (RCS) with phenolic resin matrix can hardly be collapsed when it is used in Al-alloy casting. Adding collapsing agent and reducing the concentration of resin are solutions adopted by workers, but these methods tend to reduce the initial strength of RCS. Synthesis of modified phenol...

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Main Authors: Yundong JI, Jirong LUO, Moyin LI
Format: Article
Language:English
Published: Foundry Journal Agency 2005-02-01
Series:China Foundry
Subjects:
Online Access:http://www.foundryworld.com/uploadfile/20094857966281.pdf
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author Yundong JI
Jirong LUO
Moyin LI
author_facet Yundong JI
Jirong LUO
Moyin LI
author_sort Yundong JI
collection DOAJ
description Resin coated sand (RCS) with phenolic resin matrix can hardly be collapsed when it is used in Al-alloy casting. Adding collapsing agent and reducing the concentration of resin are solutions adopted by workers, but these methods tend to reduce the initial strength of RCS. Synthesis of modified phenolic resin with direct-chain diacid DAn (/JS=6, where n means carbon amount) was studied here. The effects of the addition of modifying agent on molecular weight, gel time and softening point were investigated. Optimal addition of DAn (10% phenol) was obtained by testing the initial and retained flexural strengths of the modified resin. FT-IR spectra showed that carbonyl shifts to higher wave number. With the use of TG, SEM and strength loss curves, the relation between initial and retained strengths was analysed. Tests on the heated deformation curve, before and after resin modification, show that PF-DA10 has the characteristic of higher initial and retained strengths together.
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spelling doaj.art-01837e6e9331477ca7507f101e5dee102022-12-21T18:34:32ZengFoundry Journal AgencyChina Foundry1672-64212005-02-01212833Study on direct-chain diacid modified phenolic resin for Al-alloy castingYundong JIJirong LUOMoyin LIResin coated sand (RCS) with phenolic resin matrix can hardly be collapsed when it is used in Al-alloy casting. Adding collapsing agent and reducing the concentration of resin are solutions adopted by workers, but these methods tend to reduce the initial strength of RCS. Synthesis of modified phenolic resin with direct-chain diacid DAn (/JS=6, where n means carbon amount) was studied here. The effects of the addition of modifying agent on molecular weight, gel time and softening point were investigated. Optimal addition of DAn (10% phenol) was obtained by testing the initial and retained flexural strengths of the modified resin. FT-IR spectra showed that carbonyl shifts to higher wave number. With the use of TG, SEM and strength loss curves, the relation between initial and retained strengths was analysed. Tests on the heated deformation curve, before and after resin modification, show that PF-DA10 has the characteristic of higher initial and retained strengths together.http://www.foundryworld.com/uploadfile/20094857966281.pdfdirect-chain diacidPF resinmodifyAl-alloy castingRCS
spellingShingle Yundong JI
Jirong LUO
Moyin LI
Study on direct-chain diacid modified phenolic resin for Al-alloy casting
China Foundry
direct-chain diacid
PF resin
modify
Al-alloy casting
RCS
title Study on direct-chain diacid modified phenolic resin for Al-alloy casting
title_full Study on direct-chain diacid modified phenolic resin for Al-alloy casting
title_fullStr Study on direct-chain diacid modified phenolic resin for Al-alloy casting
title_full_unstemmed Study on direct-chain diacid modified phenolic resin for Al-alloy casting
title_short Study on direct-chain diacid modified phenolic resin for Al-alloy casting
title_sort study on direct chain diacid modified phenolic resin for al alloy casting
topic direct-chain diacid
PF resin
modify
Al-alloy casting
RCS
url http://www.foundryworld.com/uploadfile/20094857966281.pdf
work_keys_str_mv AT yundongji studyondirectchaindiacidmodifiedphenolicresinforalalloycasting
AT jirongluo studyondirectchaindiacidmodifiedphenolicresinforalalloycasting
AT moyinli studyondirectchaindiacidmodifiedphenolicresinforalalloycasting