[meso-5,10,15,20-Tetrakis(5-bromothiophen-2-yl)porphyrinato-κ4N,N′,N′′,N′′′]nickel(II)

[meso-5,10,15,20-Tetrakis(5-bromothiophen-2-yl)porphyrinato-κ4N,N′,N′′,N′′′]nickel(II)

The NiII atom in the title porphyrin complex, [Ni(C36H16Br4N4S4)], is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N4 donor set and the pyrrole rings being in the range 17.0 (3)&am...

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Bibliographic Details
Main Authors: R. Prasath, P. Bhavana, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812011671

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