2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium
The title compound, C5H5Cl5N5P3, crystallizes as a zwitterion in which the pyridine N atom is protonated. An S(6) ring motif is formed via an intramolecular C—H...N hydrogen bond. The triazatriphosphinine ring adopts an envelope conformation, with one N atom displaced by 0.145&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200013X |
| _version_ | 1818960396515540992 |
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| author | Safaa A. Ahmed Rosenani A. Haque Zulikha H. Zetty Hoong-Kun Fun Wan-Sin Loh |
| author_facet | Safaa A. Ahmed Rosenani A. Haque Zulikha H. Zetty Hoong-Kun Fun Wan-Sin Loh |
| author_sort | Safaa A. Ahmed |
| collection | DOAJ |
| description | The title compound, C5H5Cl5N5P3, crystallizes as a zwitterion in which the pyridine N atom is protonated. An S(6) ring motif is formed via an intramolecular C—H...N hydrogen bond. The triazatriphosphinine ring adopts an envelope conformation, with one N atom displaced by 0.145 (1) Å from the other atoms. In the crystal, N—H...N and C—H...N hydrogen bonds link the molecules into centrosymmetric dimers containing one R22(7) ring motif and two R22(8) ring motifs. |
| first_indexed | 2024-12-20T11:56:52Z |
| format | Article |
| id | doaj.art-01db96bff7de4738a2d65efd35cc294a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:56:52Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-01db96bff7de4738a2d65efd35cc294a2022-12-21T19:41:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682o306o30610.1107/S160053681200013X2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridiniumSafaa A. AhmedRosenani A. HaqueZulikha H. ZettyHoong-Kun FunWan-Sin LohThe title compound, C5H5Cl5N5P3, crystallizes as a zwitterion in which the pyridine N atom is protonated. An S(6) ring motif is formed via an intramolecular C—H...N hydrogen bond. The triazatriphosphinine ring adopts an envelope conformation, with one N atom displaced by 0.145 (1) Å from the other atoms. In the crystal, N—H...N and C—H...N hydrogen bonds link the molecules into centrosymmetric dimers containing one R22(7) ring motif and two R22(8) ring motifs.http://scripts.iucr.org/cgi-bin/paper?S160053681200013X |
| spellingShingle | Safaa A. Ahmed Rosenani A. Haque Zulikha H. Zetty Hoong-Kun Fun Wan-Sin Loh 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium Acta Crystallographica Section E |
| title | 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium |
| title_full | 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium |
| title_fullStr | 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium |
| title_full_unstemmed | 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium |
| title_short | 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium |
| title_sort | 2 2 4 4 6 6 pentachloro 1 3 5 2 amp 955 5 4 amp 955 5 6 amp 955 5 triazatriphosphinin 2 yl azanidyl pyridinium |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681200013X |
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