SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT
It has been established the possibility for phenol allylation on natural zeolites and them analogs. Here is demonstrated the synthesis of allyl phenol, which has wide industrial applications. The offered method in comparison with the traditional methods has more advantages – higher selectivity, smal...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2011-12-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/dwnl.php?id=CSCC6201104V04S01A0014 |
| _version_ | 1818422509922418688 |
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| author | Gagik Torosyan Dezy Hovhannisyan |
| author_facet | Gagik Torosyan Dezy Hovhannisyan |
| author_sort | Gagik Torosyan |
| collection | DOAJ |
| description | It has been established the possibility for phenol allylation on natural zeolites and them analogs. Here is demonstrated the synthesis of allyl phenol, which has wide industrial applications. The offered method in comparison with the traditional methods has more advantages – higher selectivity, smaller material and power resources consumption. It has been obtained the mixture of allylating phenols (30%) in general with allyl phenyl ether (1) with 80% yields. At 600 K is obtained allylphenyl ether, at 700 K beginning the formation of allyl phenols, which is the result of direct C-allylation of the aromatic ring. It has been investigated the possibility of Claisen rearrangement in the same conditions. All of that are established by gas-liquid chromatography and liquid chromatography data. |
| first_indexed | 2024-12-14T13:27:24Z |
| format | Article |
| id | doaj.art-01ebde98d49f49de9853f6aae8943342 |
| institution | Directory Open Access Journal |
| issn | 1582-540X |
| language | English |
| last_indexed | 2024-12-14T13:27:24Z |
| publishDate | 2011-12-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-01ebde98d49f49de9853f6aae89433422022-12-21T22:59:47ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2011-12-01124425428SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENTGagik TorosyanDezy HovhannisyanIt has been established the possibility for phenol allylation on natural zeolites and them analogs. Here is demonstrated the synthesis of allyl phenol, which has wide industrial applications. The offered method in comparison with the traditional methods has more advantages – higher selectivity, smaller material and power resources consumption. It has been obtained the mixture of allylating phenols (30%) in general with allyl phenyl ether (1) with 80% yields. At 600 K is obtained allylphenyl ether, at 700 K beginning the formation of allyl phenols, which is the result of direct C-allylation of the aromatic ring. It has been investigated the possibility of Claisen rearrangement in the same conditions. All of that are established by gas-liquid chromatography and liquid chromatography data.http://pubs.ub.ro/dwnl.php?id=CSCC6201104V04S01A0014allyl alcoholallylationClaisen rearrangementnatural zeolitephenol |
| spellingShingle | Gagik Torosyan Dezy Hovhannisyan SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry allyl alcohol allylation Claisen rearrangement natural zeolite phenol |
| title | SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT |
| title_full | SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT |
| title_fullStr | SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT |
| title_full_unstemmed | SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT |
| title_short | SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT |
| title_sort | synthesis of allyl phenyl ether and claisen rearrangement |
| topic | allyl alcohol allylation Claisen rearrangement natural zeolite phenol |
| url | http://pubs.ub.ro/dwnl.php?id=CSCC6201104V04S01A0014 |
| work_keys_str_mv | AT gagiktorosyan synthesisofallylphenyletherandclaisenrearrangement AT dezyhovhannisyan synthesisofallylphenyletherandclaisenrearrangement |