(E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol
The synthesis of (E)-2-((4R,5R)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, 1H NMR, 13C NMR, MS, elemental analysis and optical rotation.
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2010-04-01
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| Series: | Molbank |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1422-8599/2010/2/M676/ |
| _version_ | 1824044635389952000 |
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| author | Carlos R. Carreras Celina E. García Víctor S. Martín Carlos E. Tonn David Díaz Díaz Juan Pedro Ceñal |
| author_facet | Carlos R. Carreras Celina E. García Víctor S. Martín Carlos E. Tonn David Díaz Díaz Juan Pedro Ceñal |
| author_sort | Carlos R. Carreras |
| collection | DOAJ |
| description | The synthesis of (E)-2-((4R,5R)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, 1H NMR, 13C NMR, MS, elemental analysis and optical rotation. |
| first_indexed | 2024-12-23T00:14:19Z |
| format | Article |
| id | doaj.art-01f6849a29e54b17b09c3e88b06a4326 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-23T00:14:19Z |
| publishDate | 2010-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-01f6849a29e54b17b09c3e88b06a43262022-12-21T18:07:27ZengMDPI AGMolbank1422-85992010-04-0120102M67610.3390/M676(E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diolCarlos R. CarrerasCelina E. GarcíaVíctor S. MartínCarlos E. TonnDavid Díaz DíazJuan Pedro CeñalThe synthesis of (E)-2-((4R,5R)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, 1H NMR, 13C NMR, MS, elemental analysis and optical rotation.http://www.mdpi.com/1422-8599/2010/2/M676/reductionDIBAL-Hsubstituted butenolidesallylic diols |
| spellingShingle | Carlos R. Carreras Celina E. García Víctor S. Martín Carlos E. Tonn David Díaz Díaz Juan Pedro Ceñal (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol Molbank reduction DIBAL-H substituted butenolides allylic diols |
| title | (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol |
| title_full | (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol |
| title_fullStr | (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol |
| title_full_unstemmed | (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol |
| title_short | (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol |
| title_sort | e 2 4r 5r 5 benzyloxy methyl 2 2 dimethyl 1 3 dioxolan 4 yl but 2 ene 1 4 diol |
| topic | reduction DIBAL-H substituted butenolides allylic diols |
| url | http://www.mdpi.com/1422-8599/2010/2/M676/ |
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