Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material

A comparative study was done on the adsorption of methyl orange dye (MO) using non-activated and activated corn leaves with hydrochloric acid as an adsorbent material. Scanning electron microscopy (SEM) and Fourier Transform Infrared spectroscopy (FTIR) were utilized to specify the properties of ads...

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Main Authors: Omar Hisham Fadhil, Mohammed Y. Eisa
Format: Article
Language:English
Published: University of Baghdad 2019-04-01
Series:Journal of Engineering
Subjects:
Online Access:http://joe.uobaghdad.edu.iq/index.php/main/article/view/816
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author Omar Hisham Fadhil
Mohammed Y. Eisa
author_facet Omar Hisham Fadhil
Mohammed Y. Eisa
author_sort Omar Hisham Fadhil
collection DOAJ
description A comparative study was done on the adsorption of methyl orange dye (MO) using non-activated and activated corn leaves with hydrochloric acid as an adsorbent material. Scanning electron microscopy (SEM) and Fourier Transform Infrared spectroscopy (FTIR) were utilized to specify the properties of adsorbent material. The effect of several variables (pH, initial dye concentration, temperature, amount of adsorbent and contact time) on the removal efficiency was studied and the results indicated that the adsorption efficiency increases with the increase in the concentration of dye, adsorbent dosage and contact time, while inversely proportional to the increase in pH and temperature for both the treated and untreated corn leaves. The equilibrium data is best fitted to Freundlich isotherm for untreated adsorbent, while Langmuir isotherm show best agreement with the data when the treated adsorbent is used. The rate of adsorption was found to follow the pseudo first order kinetic model (PFO) when non-activated adsorbent is used, while the pseudo second order model (PSO) is fitted to the adsorption data using activated adsorbent.
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spelling doaj.art-0211b63aaa0540d190211d46ae76c3872023-09-02T23:03:23ZengUniversity of BaghdadJournal of Engineering1726-40732520-33392019-04-0125410.31026/j.eng.2019.04.05Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent MaterialOmar Hisham Fadhil0Mohammed Y. Eisa1Biochemical Engineering Department, Al-Khwarizmi College of Engineering, University of BaghdadBiochemical Engineering Department, Al-Khwarizmi College of Engineering, University of BaghdadA comparative study was done on the adsorption of methyl orange dye (MO) using non-activated and activated corn leaves with hydrochloric acid as an adsorbent material. Scanning electron microscopy (SEM) and Fourier Transform Infrared spectroscopy (FTIR) were utilized to specify the properties of adsorbent material. The effect of several variables (pH, initial dye concentration, temperature, amount of adsorbent and contact time) on the removal efficiency was studied and the results indicated that the adsorption efficiency increases with the increase in the concentration of dye, adsorbent dosage and contact time, while inversely proportional to the increase in pH and temperature for both the treated and untreated corn leaves. The equilibrium data is best fitted to Freundlich isotherm for untreated adsorbent, while Langmuir isotherm show best agreement with the data when the treated adsorbent is used. The rate of adsorption was found to follow the pseudo first order kinetic model (PFO) when non-activated adsorbent is used, while the pseudo second order model (PSO) is fitted to the adsorption data using activated adsorbent.http://joe.uobaghdad.edu.iq/index.php/main/article/view/816adsorption, methyl orange dye, corn leaves, adsorption isotherm, adsorption kinetics
spellingShingle Omar Hisham Fadhil
Mohammed Y. Eisa
Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material
Journal of Engineering
adsorption, methyl orange dye, corn leaves, adsorption isotherm, adsorption kinetics
title Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material
title_full Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material
title_fullStr Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material
title_full_unstemmed Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material
title_short Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material
title_sort removal of methyl orange from aqueous solutions by adsorption using corn leaves as adsorbent material
topic adsorption, methyl orange dye, corn leaves, adsorption isotherm, adsorption kinetics
url http://joe.uobaghdad.edu.iq/index.php/main/article/view/816
work_keys_str_mv AT omarhishamfadhil removalofmethylorangefromaqueoussolutionsbyadsorptionusingcornleavesasadsorbentmaterial
AT mohammedyeisa removalofmethylorangefromaqueoussolutionsbyadsorptionusingcornleavesasadsorbentmaterial