In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines
Rhinsitu/mesSiO2 was prepared in one step by incorporating rhodium units onto the silica during the sol–gel process. It was revealed as an excellent active and selective catalyst for the hydrogenation of aromatic, heteroaromatic, aliphatic nitriles, and aliphatic nitriles bearing aromatic or heteroa...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2025-02-01
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| Series: | Green Processing and Synthesis |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/gps-2024-0193 |
| _version_ | 1826802763198103552 |
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| author | Ajjou Abdelaziz Nait Robichaud André Rahman Ateeq |
| author_facet | Ajjou Abdelaziz Nait Robichaud André Rahman Ateeq |
| author_sort | Ajjou Abdelaziz Nait |
| collection | DOAJ |
| description | Rhinsitu/mesSiO2 was prepared in one step by incorporating rhodium units onto the silica during the sol–gel process. It was revealed as an excellent active and selective catalyst for the hydrogenation of aromatic, heteroaromatic, aliphatic nitriles, and aliphatic nitriles bearing aromatic or heteroaromatic rings to primary amines. |
| first_indexed | 2025-03-17T01:27:56Z |
| format | Article |
| id | doaj.art-02169f6c70554d5e859db3d0db27a32e |
| institution | Directory Open Access Journal |
| issn | 2191-9550 |
| language | English |
| last_indexed | 2025-03-17T01:27:56Z |
| publishDate | 2025-02-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Green Processing and Synthesis |
| spelling | doaj.art-02169f6c70554d5e859db3d0db27a32e2025-02-17T08:45:10ZengDe GruyterGreen Processing and Synthesis2191-95502025-02-011411879510.1515/gps-2024-0193In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary aminesAjjou Abdelaziz Nait0Robichaud André1Rahman Ateeq2Department of Chemistry and Biochemistry, Université de Moncton, Moncton, New-Brunswick, E1A 3E9, CanadaHealth Canada, 1001, Saint-Laurent Ouest Blvd, Longueuil, J4K 1C7, Québec, CanadaDepartment of Physics, Chemistry & Material Science, Faculty of Agriculture, Engineering & Natural Science, University of Namibia, Pionierspark, Post Box-13301, Windhoek, NamibiaRhinsitu/mesSiO2 was prepared in one step by incorporating rhodium units onto the silica during the sol–gel process. It was revealed as an excellent active and selective catalyst for the hydrogenation of aromatic, heteroaromatic, aliphatic nitriles, and aliphatic nitriles bearing aromatic or heteroaromatic rings to primary amines.https://doi.org/10.1515/gps-2024-0193rhodium-supported catalystnitrileshydrogenationprimary aminesmesoporous silica |
| spellingShingle | Ajjou Abdelaziz Nait Robichaud André Rahman Ateeq In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines Green Processing and Synthesis rhodium-supported catalyst nitriles hydrogenation primary amines mesoporous silica |
| title | In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines |
| title_full | In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines |
| title_fullStr | In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines |
| title_full_unstemmed | In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines |
| title_short | In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines |
| title_sort | in situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines |
| topic | rhodium-supported catalyst nitriles hydrogenation primary amines mesoporous silica |
| url | https://doi.org/10.1515/gps-2024-0193 |
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